Zircon U-Pb dating and geochemistry of the syenogranite from the Bianjiadayuan Pb-Zn-Ag deposit of Inner Mongolia and its tectonic implications
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摘要:
文章对内蒙古边家大院铅锌银多金属矿床深部正长花岗岩进行了LA-ICP-MS锆石U-Pb同位素测年，并对花岗岩的主量元素、微量元素和Sr-Nd同位素组成做了分析研究。结果显示，边家大院正长花岗岩加权平均年龄为（140.31±0.34）Ma，为大兴安岭南段早白垩世岩浆活动集中期产物；研究区至少有两期岩浆活动，早期酸性岩浆侵位，约10 Ma后中基性岩浆侵位，成岩与成矿同期进行。花岗岩地球化学特征具有高SiO2、K2O，低MgO、CaO、TiO2的主量元素特征，A/CNK在0.98~1.19，属于准铝-弱过铝系列；富集Rb、Th、U、K等大离子亲石元素（LILE），亏损Sr、P、Ti等高场强元素（HFSE）；稀土总量ΣREE较大，δEu为0.12~0.14，强烈Eu负异常；（87Sr/86Sr）i和（143Nd/144Nd）i初始比值，分别介于0.7066~0.7077和0.5121~0.5122（t=140 Ma），εNd（t）为-5.0‰~-6.6‰，成岩物质来自于中元古界下地壳铁镁质源岩的部分熔融。研究表明边家大院正长花岗岩是在早白垩世受到了蒙古-鄂霍次克海“剪刀式”闭合造山后的伸展条件和岩石圈减薄作用的影响，形成于高温低压环境的A型花岗岩。高温低压环境还可能与该区域岩石圈发生拆沉作用有关。
Abstract:In this study, a series of analyses such as LA-ICP-MS zircon U-Pb isotopic dating and major elements, trace elements and Sr-Nd isotope composition investigation were performed for the syenogranite located in the deep layer of the Bianjiadayuan Pb-Zn-Ag polymetallic deposit, Inner Mongolia. Formed during the magmatic concentration period of early Cretaceous in southern Da Hinggan Mountains, the syenogranite in this deposit has age of (140.31±0.34) Ma. There were at least two periods of magmatic activity in the study area:Acid magma invaded in the early period, whereas intermediate magma and basic magma invaded about 10 Ma later. Ore-forming and rock-forming activities occurred over the same period. Geochemistry of major elements in the syenogranite is characterized by high SiO2 and K2O and low MgO, CaO and TiO2 with A/CNK ratio between 0.98 and 1.19, suggesting metaluminous-weakly peraluminous series. The syenogranite is enriched in LILE such as Rb, Th, U and K and depleted in HFSE such as Sr, P and Ti. The ΣREE values are slightly high. The δEu lies between 0.12 and 0.14, exhibiting significant negative Eu anomalies. The initial ratio of (87Sr/86Sr)i is between 0.7066 and 0.7077, while the initial ratio of (143Nd/144Nd)i is between 0.5121 and 0.5122 (t=140 Ma); εNd(t) values vary in the range of-5.0 to-6.6. Therefore, the petrogenetic materials were the products of partial melting of mafic-ultramafic source rock in middle Proterozoic lower crust. The analyses reveal that the syenogranite in the Bianjiadayuan deposit is A-type granite formed in the environment of high temperature and low pressure with the impact of the post-orogenic extension of Mongolia-Okhotsk scissor-type closed orogeny and lithospheric thinning in early Cretaceous. The high temperature and low pressure environment was probably related to the regional lithosphere demolition effect.
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图 1 大兴安岭南段区域地质-矿床分布图（据Chu et al., 2001修改）
Figure 1.
图 6 内蒙古边家大院铅锌矿正长花岗岩SiO2-全碱图解 (a, 据Middlemost, 1994)、SiO2-K2O图解 (b, 据Peccerillo, Taylor, 1976)
Figure 6.
图 7 微量元素原始地幔标准化图解 (a)、稀土元素球粒陨石标准化图解 (b)(标准值据Sun and McDonough, 1989)
Figure 7.
图 9 边家大院正长花岗岩 (87Sr/86Sr)i-1/Sr (a)、εNd(t)-1/Nd (b)、(87Sr/86Sr)i-εNd(t) (c, 据吴福元等, 1999) 相关图解
Figure 9.
图 10 不同类型花岗岩形成p-t条件 (a, 据张旗, 2014)、花岗岩类lg[CaO/(K2O+Na2O)-SiO2]图解 (b，据Brown, 1982)、Rb-(Y+Nb) 图解 (c, 据Pearce et al., 1984)、R1-R2图解 (d, 据Batchelor et al., 1985)
Figure 10.
表 1 边家大院铅锌多金属矿正长花岗岩锆石LA-ICP-MS测年结果
Table 1. LA-ICP-MS data for zircons from the syenogranite of the Bianjiadayuan lead and zinc polymetallic deposit
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表 2 边家大院铅锌矿正长花岗岩主量元素含量（%）和微量元素（10-6）含量
Table 2. Major elements (%) and trace elements (10-6) compositions of syenogranite from the Bianjiadayuan lead and zinc polymetallic deposit
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表 3 边家大院铅锌矿正长花岗岩Sr-Nd同位素分析结果
Table 3. Sr-Nd isotopic composition of syenogranite from the Bianjiadayuan lead and zinc polymetallic deposit
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