Ore geochemical characteristics and metallogenic epoch of typical graphite deposits in Jiamusi Massif, Heilongjiang Province
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摘要:
佳木斯地块位于东北亚早前寒武纪陆块，区内变质岩系发育，是重要的晶质石墨富集地带。文章通过对佳木斯地块典型的萝北云山和鸡西柳毛石墨矿床含矿岩石进行SHRIMP锆石U-Pb年龄测定，结果表明：变质锆石和碎屑锆石207Pb/206Pb年龄分别为（1855±5）~（1979±13）Ma和（476±9）~（575±12）Ma。通过地球化学特征分析，萝北云山石墨矿和鸡西柳毛石墨矿含矿岩石富集Rb、Ba等大离子亲石元素和Zr、Hf、Th、U、Nb、Ta等高场强元素，含矿岩石Rb/Sr平均值均高于陆壳值0.24，表明循环沉积作用较弱；Sr/Ba比值较低，表明岩浆来源于陆壳重熔，显示以陆源物质为主；V/Cr平均值为4.58，V/（Ni+V）平均值为0.90，显示弱还原环境；两处典型矿床轻稀土元素含量均高于重稀土元素，萝北云山矿床负Eu异常明显，显示陆棚浅海沉积特征，鸡西柳毛矿床正Ce异常明显，显示海源物质为主的浅海沉积特征。研究区混合花岗岩脉的稀土元素配分曲线具有正Eu异常，显示出外来岩浆热液交代岩石特征。因此，佳木斯地块典型石墨矿床含矿岩石在古元古代晚期经受区域性高温高压变质作用，后经过早古生代强烈的泛亚构造作用，在构造岩浆侵入背景下进一步增生形成巨晶鳞片状石墨。
Abstract:Jiamusi massif is located in the northeast Asia early Precambrian landmass, where metamorphic rocks well developed and constituted an important crystalline graphite enrichment zone. The SHRIMP U-Pb dating results of ore rocks from typical Luobei Yunshan and Jixi Liumao graphite deposits in Jiamusi massif show that 207Pb/206Pb age is (1855±5)-(1979±13) Ma and (476±9)-(575±12) Ma respectively for metamorphic recrystallization zircon and authigenic zircon. The geochemical characteristic analysis indicates that the ore rock is enriched in large ion lithophile elements such as Rb, Ba and high field strength elements such as Zr, Hf, Th, U, Nb and Ta, and Rb/Sr ratio of ore rock is higher than continental crust Value 0.24, suggesting weak cyclic sedimentation; Sr/Ba ratio is lower, implying that magma was derived from the continental crust remelting; terrigenous material is dominant; the average V/Cr ratio is 4.58, average V/(Ni+V)ratio is 0.90, suggesting a weak reduction environment; the light rare earth element values are higher than those of heavy rare earth elements in the two typical deposits; negative europium anomalies are obvious for Luobei Yunshan mineral deposit, implying shelf shallow sea sedimentary characteristics; cerium is abnormal in Jixi Liumao deposit, indicating that the source material was dominated by shallow sea sedimentary materials. Mixed granite dike of rare earth elements in the study area exhibits a positive europium anomaly distribution curve, suggesting the characteristics of foreign magmatic hydrothermal metasomatic rock. Ore rocks of typical graphite deposit in Jiamusi massif were subjected to regional metamorphism of high temperature and high pressure in Paleoproterozoic period, and later experienced the pan-Asian structural activity under the background of tectonic magmatic intrusion in early Paleozoic period, which caused further proliferation and formation of giant crystal flaky graphite.
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Key words:
- Jiamusi massif /
- graphite deposit /
- Mashan Group /
- geochemistry /
- chronology
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表 2 萝北云山石墨矿和鸡西柳毛石墨矿岩石化学分析结果
Table 2. Petrochemical analyses of Luobei Yunshan graphite deposit and Jixi Liumao graphite deposit
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表 3 萝北云山石墨矿和鸡西柳毛石墨矿石锆石年龄
Table 3. Ore rock zircon ages of Jixi Liumao and Luobei Yunshan graphite deposits
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Boynton W V. 1984. Geochemistry of the rare earth elements:Meteorite studies[C]//Henderson P. Rare Earth Element Geochemistry.Amsterdam:Elsevier, 63-114.
http://d.wanfangdata.com.cn/ExternalResource/zgdizhi201004017%5E35 Cao Xi, Dang Zengxin, Zhang Xingzhou, Jiang Jisheng, Wang Hongde. 1992. Jianusi Composite Terrane[M]. Jilin Science and Technology Press.
Cao Shengen, Zhao Chunli. 1993. Geological characteristics of Jixi lingnan graphite mine deposit[J]. Non-Metallic Geology, (2):8-12.
Compston W, Williams IS, Kirschvink J L, Zhang Z C, Ma G G. 1992, Zircon U-Pb ages for the Early Cambrian time-scale[J]. J. Geol.Soc. (149):171-184. https://www.researchgate.net/publication/291776779_Zircon_U-Pb_ages_for_the_Early_Cambrian_time-scale
Fang Junwei, Li Xiaojun, Liu Yanlin. 2009. Large flake graphite mine geological characteristics in Luobei Sifangshan forest farm eastern.[J]. Building Materials and Decorations, 60(10):43-53.
Ge Xiaohong, Liu Junlai, Ren Shoumai. 2014. The formation and evolution of the mesozoic-cenozoic continental in eastern China[J]. Geology in China, 41(1):19-38. https://www.researchgate.net/publication/286072656_The_formation_and_evolution_of_the_Mesozoic-Cenozoic_continental_tectonics_in_eastern_China
Heilongjiang Bureau of Gology and Mineral. 1989. Regional Geology of Heilongjiang Province[M]. Beijing:Geological Publishing House, 16-19.
Jiang Jisheng. 1992. Regional metamorphism and evolution of Mashan khondalite series[J]. Acta Petrologica et Mineralogica, 11(2):97-110. https://www.researchgate.net/publication/285635463_Regional_metamorphism_and_evolution_of_Mashan_khondalite_series
Jiang Jisheng, Liu Xiang. 1992. The Early Precambrian sedimentary metamorphic type crystal graphite deposit[J]. Non-Metallic Geology, (5):18-22
Jiang Jisheng. 1992.Khondalite Series stratum subjects of MaShan group[J].Journal of Stratigraphy, 16(4):304-311.
Li Chunwen. 2003. Development and Utilization for valuable metal uranium, vanadium, titanium occurrence state of Liumao graphite mine[J]. Heilongjiang Geology, 14(2):114-121.
Li Guanghui, Huang Yongwei, Wu Runtang, Xu Dajie. 2008. Origin of carbon and concentration of uranium and vanadium from Liumao graphite formation in Jixi[J]. Global Geology, 27(1):19-22. http://en.cnki.com.cn/Article_en/CJFDTOTAL-SJDZ200801004.htm
Li Hanbin, Zhang Bing. 2014. Metamorphism and its significance of Yunshan graphite deposit in Heilongjiang[J]. China Nonmetallic Minerals Industry, (1):45-46. http://en.cnki.com.cn/Article_en/CJFDTotal-LGFK201401017.htm
Ma Jiajun, Fang Dahe. 1991. A preliminary study of the Mesozoic volcanic rocks in HeiLongjiang province china[J]. Heilongjiang Geology, 2(2):1-16.
Miao Fulin. 2006. Analysis and discussed the characteristics of Jixi graphite resources[J]. Scientific and Technological Achievements, (3):70.
Mo Rujue, Liu Shaobin, Huang Cuirong, Zhang Guangrong, Tan Guanmin, Wang Baoxian, Xian Xiangzhang. 1989. China Graphite Mine Deposit geology[M]. China Architecture & Building Press.
Ren Liudong, Wang Yanbin, Yang Chonghui, Han Juan, Xie Hhangqiang, Li Linshan. 2010. Metamorphism, migmatization and granites of the Mashan complex[J]. Acta Petrologica Sinica, 26(7):2005-2014. http://www.oalib.com/paper/1473529
Simon A wilde, Wu Fuyuan, Zhang Xingzhou. 2001. The Mashan complex:SHRIMP U-Pb zircon evidence for a Late Pan-African metamorphic event in NE China and its implication for global continental reconstructions[J]. Geochemica, 30(1):35-50. https://www.researchgate.net/publication/304111114_The_Mashan_Complex_SHRIMP_U-Pb_zircon_evidence_for_a_Late_Pan-African_metamorphic_event_in_NE_China_and_its_implication_for_global_continental_reconstructions
Song Biao, Zhang Yuhai, Wan Yusheng, Jian Ping. 2002. Mount making and procedure of the SHRIMP dating[J]. Geological Review, 48(Supp.):26-30. http://en.cnki.com.cn/Article_en/CJFDTOTAL-DZLP2002S1006.htm
Sun Xiangdong. 1994. Geological characteristics forming of graphite deposit in east of Heilongjiang Province[J]. Non-Metallic Geology, (1):15-19. https://www.researchgate.net/publication/292126141_Geochemical_characteristics_of_fluid_inclusions_in_Jinchang_gold_deposit_Heilongjiang_Province
Taylor H P, Sheppard S M F. 1986.Ingeous rocks:I.Processes of isotopic fractionation and isotopic systematic[C]//Valley J W, Taylor H P, O'Neil Taylor P N, Jones N W, Moorbath S (eds.). 1984.Isotopic Assessment of Relative Contributions from Crust and Mantle Sources to the Magma Genesis of Precambrian Granitoid Rocks.Phil. Trans. Roy. Soc. Lond. A, 310:605-625.
Tian Jing, Li Jinwen, Wang Runhe, Liu Wen, Xiang Anping, Kang Yongjian, Guo Zhijun, Dong Xunzhou. 2014. Zircon LA-ICP-MS U-Pb ages and geochemical features of intrusions in Erentaolegai area of Inner Mongolia[J]. Geology in China, 41(4):1092-1107. https://www.researchgate.net/publication/287696853_Zircon_LA-ICP-MS_U-Pb_ages_and_geochemical_features_of_intrusions_in_Erentaolegai_area_of_Inner_Mongolia
Wang Changshui, Wang Xiuhua. 2006. Early precambrian basement and metallogenetic series in eastern Hei Longjiang Province[J]. Geology and Resources, 15(4):256-264. https://www.researchgate.net/profile/M_Santosh/publication/268691988_Types_characteristics_and_metallogenesis_of_gold_deposits_in_the_Jiaodong_Peninsula_Eastern_North_China_Craton/links/54791e210cf205d1687f7d74.pdf?inViewer=true&disableCoverPage=true&origin=publication_detail
Wilde S A, Cawood P A, Wang K Y. 1997. SHRIMP U-Pb data of granires and gneisses in the Tmhangshan-Wutaishan area:Implications for the timing of crustal growth in the Noah China craton[J]. Chinese Science Bulletin, 43(supp.):144.
Xu Yanqiang, Han Zhenxin, Xu Shoumin. 2001. Formation and evolution of the centralized area of the large crystalline graphite deposit in the Jiamusi massif[J]. Heilongjiang Geology, 12(3):1-10.
Yu Enjun. 2008. Geologic features and tectonic evolution mechanism of Mashan Group in Jiamusi block[J]. JiLin Geology, 27(4):16-25. http://en.cnki.com.cn/Article_en/CJFDTotal-JLDZ200804007.htm
Yuan Li, Yao Ping. 1993. Analysis on tectonic stress field of the Liumao graphite in Jixi Heilongjiang and its significance[J].NonMetallic Geology, (5):13-17.
Zhang Benchen. 2005. Geological features and genesis of the Guangyi graphite deposit of Muling county[J]. Jilin Geology, 24(4):47-53. http://en.cnki.com.cn/Article_en/CJFDTOTAL-JLDZ200504008.htm
Zhao Ranran, Song Shouyong. 2013. Graphite mine metallogenic conditions in Heilongjiang Province[J]. Industrial Science Tribune, . 12(6):64-65.
Zhao Zhonghai, Qu Hui, Li Chenglu, Xu Guozhan, Wang zhuo, et al. 2014. Zircon U-Pb ages, geochemical characteristics and tectonic implications of the Early Paleozoic granites in Huolongmen area, Heilongjiang Province[J].Geology in China, 41(3):773-783. http://en.cnki.com.cn/Article_en/CJFDTotal-DIZI201403007.htm
Zhou Jianbo, Zhang Xingzhou, Simon A Wilde, Zheng Changqing. 2011. Confirming of the Heilongjiang-500Ma Pan-African khondalite belt and its tectonic implications[J]. Acta Petrologica Sinica, 27(4):1235-1245. https://espace.curtin.edu.au/handle/20.500.11937/45718?show=full
曹熹, 党增欣, 张兴洲, 姜继圣, 王洪德. 1992.佳木期复合地体[M].长春:吉林科学技术出版社.
曹圣恩, 赵纯礼. 1993.鸡西市岭南石墨矿床地质特征[J].建材地质, (2):8-12. http://www.cnki.com.cn/Article/CJFDTOTAL-LGFK199302001.htm
房俊伟, 李晓军, 刘彦林. 2009.萝北县四方山林场东部大鳞片石墨矿地质特征[J].建筑材料装饰, 60(10), 43-53. http://d.wanfangdata.com.cn/Periodical_jcjzzx200903021.aspx
葛肖虹, 刘俊来, 任收麦. 2014.中国东部中-新生代大陆构造的形成与演化[J].中国地质, 41(1):19-38. http://geochina.cgs.gov.cn/ch/reader/view_abstract.aspx?file_no=20140102&flag=1
黑龙江省地质矿产局. 1989.黑龙江区域地质志[M].北京:地质出版社, 16-19.
姜继圣. 1992.麻山群孔兹岩系主期区域变质作用及演化[J].岩石矿物学杂志, 11(2):97-110. http://www.cnki.com.cn/Article/CJFDTOTAL-YSKW199202000.htm
姜继圣, 刘祥. 1992.中国早前寒武纪沉积变质型晶质石墨矿床[J].建材地质, (5):18-22. http://www.cnki.com.cn/Article/CJFDTOTAL-LGFK199205002.htm
姜继圣. 1992.麻山群孔兹岩系地层新见[J].地层学杂志, 16(4):304-311. http://www.cnki.com.cn/Article/CJFDTOTAL-DCXZ199204009.htm
李春文. 2003.鸡西市柳毛石墨矿有价金属铀、钒、钛赋存状态及开发利用[J].黑龙江地质, 14(2):114-121. http://cdmd.cnki.com.cn/Article/CDMD-10220-2005154486.htm
李光辉, 黄永卫, 吴润堂, 徐大杰. 2008.鸡西柳毛石墨矿碳质来源及铀、钒的富集机制[J].世界地质, 27(1):19-22. http://www.cnki.com.cn/Article/CJFDTOTAL-SJDZ200801004.htm
李寒滨, 张冰. 2014.黑龙江云山石墨矿床变质作用及其意义[J].中国非金属矿工业导刊, (1):45-46. http://www.cnki.com.cn/Article/CJFDTOTAL-LGFK201401017.htm
马家骏, 方大赫. 1991.黑龙江省中生代火山岩初步研究[J].黑龙江地质, 2(2):1-16. http://cdmd.cnki.com.cn/Article/CDMD-11415-2009075402.htm
苗富林. 2006.鸡西市石墨资源特征分析探讨[J].科技成果纵横, (3):70. http://www.cnki.com.cn/Article/CJFDTOTAL-KJCH200603045.htm
莫如爵, 刘绍斌, 黄翠蓉, 张光荣, 谭冠民, 王宝娴, 肖祥章. 1989. 中国石墨矿床地质[M]. 中国建筑工业出版社.
任留东, 王彦斌, 杨崇辉, 韩娟, 颉颃强, 李林山. 2010.麻山杂岩的变质-混合岩化作用和花岗质岩浆活动[J].岩石学报, 26(7):2005-2014. http://www.cnki.com.cn/Article/CJFDTOTAL-YSXB201007005.htm
Simon A wilde, 吴福元, 张兴洲. 2001.中国东北麻山杂岩晚泛非期变质的锆石Shrimp年龄证据及全球大陆再造意义[J].地球化学, 30(1):35-50. http://www.cnki.com.cn/Article/CJFDTOTAL-DQHX200101005.htm
宋彪, 张玉海, 万渝生, 简平. 2002.锆石SHRIMP样品靶制作、年龄测定及有关现象讨论[J].地质论评, 48 (增刊):26-30. http://www.cnki.com.cn/Article/CJFDTOTAL-DZLP2002S1006.htm
孙向东. 1994.黑龙江省东部地区石墨矿床成矿地质特征[J].建材地质, (1):15-19. http://www.cnki.com.cn/Article/CJFDTOTAL-LGFK199401003.htm
田京, 李进文, 王润和, 刘文, 向安平, 康永建, 郭志军, 董旭舟. 2014.内蒙古额仁陶勒盖地区侵入岩LA-ICP-MS锆石U-Pb年龄及地球化学特征[J].中国地质, 41(4):1092-1107. http://geochina.cgs.gov.cn/ch/reader/view_abstract.aspx?file_no=20140405&flag=1
王长水, 王秀华. 2006.黑龙江省东部早前寒武纪基底及矿床成矿系列划分[J].地质与资源, 15(4):256-264. http://www.cnki.com.cn/Article/CJFDTOTAL-GJSD200604003.htm
徐衍强, 韩振新, 徐受民. 2001.佳木斯地块大型晶质石墨矿集区的形成和演化[J].黑龙江地质, 12(3):1-10.
于恩君. 2008.佳木斯地块麻山岩群的地质特征及构造演化机制探讨[J].吉林地质, 27(4), 16-25. http://www.cnki.com.cn/Article/CJFDTOTAL-JLDZ200804007.htm
袁犁, 姚萍. 1993.黑龙江鸡西柳毛石墨矿区构造应力场分析及其意义[J].建材地质, (5):13-17. http://www.cnki.com.cn/Article/CJFDTOTAL-LGFK199305002.htm
张本臣. 2005.穆棱县光义石墨矿地质特征及成因浅析[J].吉林地质, 24(4):47-53. http://www.cnki.com.cn/Article/CJFDTOTAL-JLDZ200504008.htm
赵然然, 宋守永. 2013.黑龙江省石墨矿成矿条件探究[J].产业与科技论坛, 12(6):64-65. http://www.cnki.com.cn/Article/CJFDTOTAL-CYYT201306034.htm
赵忠海, 曲晖, 李成禄, 徐国战, 王军. 2014.黑龙江霍龙门地区早古生代花岗岩的锆石U-Pb年龄、地球化学特征及构造意义[J].中国地质, 41(3):773-783. http://geochina.cgs.gov.cn/ch/reader/view_abstract.aspx?file_no=20140307&flag=1
周建波, 张兴洲, Simon A Wilde, 郑常青. 2011.中国东北-500Ma泛非期孔兹岩带的确定及其意义[J].岩石学报, 27(04):1235-1245. http://www.cnki.com.cn/Article/CJFDTOTAL-YSXB201104031.htm
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