Geochemical characteristics and zircon U-Pb age of the Paleoproterozic S-type granite in Wulashan region and its geological significance
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摘要:
华北克拉通北缘乌拉山地区发育有大量的古元古代花岗岩，以诺尔音S型花岗岩为代表，本文对诺尔音花岗岩进行详细研究，结果表明：诺尔音花岗岩具有高硅w（SiO2）=70.03%~75.43%、高铝（w（Al2O3）=13.04%~14.87%）、富钾（w（K2O）=5.36%~6.58%）的特征，其较低的铁镁质量比Mg# < 10和较高铝饱和指数A/CNK=1.03~1.21，属于典型的过铝质花岗岩，岩石轻稀土富集，且轻重稀土强烈分馏（LaN/YbN=22.3~300.5），配分模式表现为右倾型，具有明显的铕负异常（δEu=0.16~0.55），微量元素原始地幔标准化蛛网图显示，岩石富集K、Rb、Th、Pb，亏损Sr、Ba、Nb、Ta、P、Ti；诺尔音花岗岩与乌拉山地区古元古代孔兹岩系具有相似的主微量地球化学特征，推断其为古元古代阴山陆块与鄂尔多斯陆块碰撞背景下，孔兹岩系深熔作用的产物。LA-ICP-MS锆石U-Pb年龄为（1891±14）Ma和（1863±17）Ma，代表诺尔音S型花岗岩的结晶年龄，与区域内孔兹岩带记录的岩浆-变质事件相吻合。
Abstract:Wulashan area, located in the north part of the North China craton, has well-developed Paleoproterozoic granites, with the Nuoeryin S-type granites as the typical one. The investigation of Nuoeryin granites shows that the granites have high SiO2 (w(SiO2)=70.03%~75.43%), high Al2O3 (w(Al2O3)=13.04%~14.87%), and high K2O values (w(K2O)=5.36%~6.58%), low Mg# (< 10) and high A/CNK values, indicating that they belong to peraluminous S-type granites. They are enriched in LREE with significant differentiation between LREE and HREE (LaN/YbN=22.3-300.5), and REE patterns of the samples are of right-oblique type, with strong negative Eu anomalies(δEu=0.16-0.55). The primitive mantle-normalized trace element diagrams show enrichment of K, Rb, Th, Pb and depletion of Sr, Ba, Nb, Ta, P, Ti. The Nuoeryin granites have similar geochemical characteristics to the Paleoproterozic knondalites in Wulashan area and, and the reason is probably that Nuoeryin granites were generated by the knondalites anatexis while the Yinshan blocks and Ordos blocks experienced collision in Paleoproterzoic. The LA-ICP-MS zircon U-Pb ages of Nuoeryin granites are 1891±14 Ma and 1863±17 Ma, which represent the crystallization age of the Nuoeryin S-type granites, and the age is also contemporaneous with magmatic-metamorphic events in Khondalite belt.
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Key words:
- Wulashan /
- khondalite belt /
- Nuoerying S-type granite /
- Paleoproterozoic /
- geochemistry
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图 1 乌拉山地区在华北克拉通的分布和构造位置图（a.b，据Zhao et al. 2005）和乌拉山西部地质简图及采样位置（c，据刘涛涛等，2016）
Figure 1.
图 3 诺尔音花岗岩的TAS图解(a，据Middlemost et al., 1994)和A/CNK-A/NK图解(b，据Maniar et al., 1989)
Figure 3.
图 4 乌拉山诺尔音花岗岩的原始地幔标准化微量元素蛛网图和球粒陨石标准化稀土元素配分图（标准化值据Sun et al., 1989图例同图 3）
Figure 4.
图 7 乌拉山诺尔音花岗岩的微量元素环境判别图解（据Pearce et al., 1984）（图例同图 3）
Figure 7.
表 1 乌拉山古元古代花岗岩主量元素（%）与微量元素（10-6）分析结果
Table 1. Content of major elements (%) and trace elements (10-6) for granites in Wulashan
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表 2 正长花岗岩样品TWB12 LA-ICP-MS锆石U-Pb定年数据
Table 2. LA-ICP-MS zircon U-Pb dating data for sample TWB12
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表 3 二长花岗岩样品TW14 LA-ICP-MS锆石U-Pb定年数据
Table 3. LA-ICP-MS zircon U-Pb dating data for sample TW14
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