Geochemistry and zircon LA-ICP-MS U-Pb age of volcanic rocks in Longjiang Formation of Longjiang basin
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摘要:
在龙江盆地地区，龙江组由中—中酸性火山岩、火山碎屑岩和火山碎屑沉积岩组成。岩石地球化学显示为钙碱性岛弧火山岩系列，火山熔岩主体具有高SiO2、Na2O、Al2O3、Sr，低MgO、Y、Yb，和高场强元素Ta、Nb明显亏损等特征，与典型埃达克岩地球化学特征吻合，Sr和Sr/Y值显示为俯冲型埃达克岩。地球化学相关图解等表明岩浆在早期演化过程阶段可能发生了陆壳混染，经历了斜长石、辉石、铁钛氧化物和磷灰石的分离结晶作用。锆石LAICP-MS U-Pb谐和年龄为（125.9±1.5）Ma，与在该组中发现的化石资料完全一致，代表了火山岩的形成年龄。从东北地区火山岩的定年结果及其空间展布来看，龙江组火山岩的形成既与环太平洋构造体系有关，又与蒙古—鄂霍茨克构造带相联系。
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关键词:
- 龙江盆地 /
- 龙江组 /
- 埃达克岩 /
- 锆石LA-ICP-MS U-Pb年龄
Abstract:The Longjiang Formation in Longjiang basin is composed of intermediate-acidic volcanic rocks, pyroclastic rocks and tuffaceous sedimentary rocks. The petrochemical compositions of most volcanic rocks belong to the calc-alkaline island arc series. These volcanic rocks are characterized by high SiO2, Na2O, Al2O3 and Sr content, low MgO, Y and Yb content and clear depletion of high field strength elements (Ta, Nb), similar to the characteristics of the classical adakite. These Sr values and Sr/Y ratios are also similar or close to features of most subduction-type adakites. Geochemical characteristics indicate that the magma experienced crust contamination and fractional crystallization of clinipyroxene, plagioclase, Ti-Fe-oxides and apatite during the early evolution process. The zircon LA-ICP-MS U-Pb age is 125.9±1.5Ma, consistent with the fossils data, representing volcanics formation age. Combined with the spatial variation of ages of the Mesozoic volcanic rocks in Northeast China, the authors hold that the formation of the volcanic rocks was related to the Circum-Pacific tectonic system as well as the Mongolia-Okhotsk structural belt.
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Key words:
- Longjiang basin /
- Longjiang Formation /
- adakite /
- zircon LA-ICP-MS U-Pb dating
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图 7 稀土元素配分曲线（a）和微量元素原始地幔标准化蛛网图（b）(球粒陨石标准化值据Boynton，1984；原始地幔标准化值据McDonough and Sun，1995)
Figure 7.
表 1 龙江盆地安山岩LA-ICP-MS锆石U-Pb测试结果
Table 1. Zircon U-Pb isotope LA-ICP-MS analyses of the volcanic rocks of Longjiang Formation
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表 2 龙江组火山岩主量元素（%）、稀土及微量元素（10-6）分析结果
Table 2. Major (wt%) and trace elements (10-6) compositions of the volcanic rocks of Longjiang Formation
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表 3 龙江组火山岩与典型埃达克岩成分对比
Table 3. A comparison of adakite with the volcanic rocks from Longjiang Formation
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