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摘要:
锰的用途非常广泛,世界上90%~95%的锰应用于冶金工业,其余应用于电池工业、陶瓷工业、化学工业等。根据成矿作用过程中的含矿岩系特征,将世界锰矿划分为海相沉积型、火山(热液)-沉积型、变质型、热液型和表生型5类,以海相沉积型、变质型和表生型为主。截至2019年,世界锰的储量达8.12亿t,但分布极不均匀,主要集中在南非、巴西、乌克兰、澳大利亚、加蓬、中国、印度、加纳等国,而优质锰矿石主要分布在南非、澳大利亚、加蓬、加纳。时间上,将锰的成矿作用分为7期,其中元古宙和新生代是主要的成矿期。空间上,锰矿床主要分布在南非德兰士瓦群、乌克兰尼科波尔盆地、澳大利亚格鲁特岛和皮尔巴拉克拉通、中国泛扬子区、西非克拉通等。目前,锰的生产主要集中在南非的卡拉哈里和波斯特马斯堡锰矿田、澳大利亚的格鲁特岛、加蓬的莫安达锰矿、加纳的恩苏塔锰矿等地。
Abstract:Manganese is widely used, 90%~95% of the world's manganese is used in the metallurgical industry, the rest in the battery industry, ceramic industry, chemical industry and so on. According to the characteristics of ore-bearing rocks in the process of mineralization, the world manganese deposits are divided into five types, including marine sedimentary type, volcanic (hydrothermal)-sedimentary type, metamorphic type, hydrothermal type and supergene type, with marine sedimentary type, metamorphic type and supergene type as the main ones. By the end of 2019, the worldwide manganese reserves had reached up to 812 million tons, but their distribution is extremely uneven, mainly concentrated in South Africa, Brazil, Ukraine, Australia, Gabon, China, India, Ghana and so on, while the high quality manganese ores are mainly distributed in South Africa, Australia, Gabon and Ghana. The mineralization epoch of manganese can be divided into 7 periods, of which Proterozoic and Cenozoic are of great importance. Manganese deposits are spatially concentrated in the Transvaal Supergroup of South Africa, the Nikopol ore Basin in Ukraine, the Groote Eylandt and Pilbara Craton of Australia, the Pan-Yangtze area of China, the West African Craton. At present, manganese ore production is mainly concentrated in Kalahari and Postmasburg ore fields in South Africa, Groote Island in Australia, Moanda mine in Gabon and Nsuta mine in Ghana.
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Key words:
- manganese /
- type /
- distribution /
- development
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Ahmet S, Vasyl M Z, Bigle S. 2020. Major, trace and rare earth element (REE) geochemistry of the Oligocene stratiform manganese oxide-hydroxide deposits in the Nikopol, Ukraine[J]. Ore Geology Reviews, 126:1-15 http://www.sciencedirect.com/science/article/pii/S0169136820306284
Beauvais A, Ruffet G, Hénocque O, Colin F. 2008. Chemical and physical erosion rhythms of the West African Cenozoic morphogenesis:The 39Ar-40Ar dating of supergene K-Mn oxides[J]. Journal of Geophysical Research, 113:1-15. http://dx.doi.org/10.1029/2008jf000996
Beukes N J, Burger A M, Gutzmer J. 1995. Fault controlled hydrothermal alteration of Paleoproterozoic manganese ore in Wessels mine, Kalahari manganese field[J]. South Africa Journal Geology, 98(4):430-451. http://sajg.geoscienceworld.org/content/98/4/430
Biondi J C, Lopez M. 2017. Urucum Neoproterozoic-Cambrian manganese deposits (MS, Brazil):Biogenic participation in the ore genesis, geology, geochemistry, and depositional environment[J]. Ore Geology Reviews, 91:335-386. doi: 10.1016/j.oregeorev.2017.09.018
Blake T S, Rothery E, Muhling J R, Drake-Brockman J A P, Sprigg L C, Ho S E, Rasmussen B, Fletcher I R. 2011. Two episodes of regional-scale Precambrian hydrothermal alteration in the eastern Pilbara, western Australia[J]. Precambrian Research, 188(1/4):73-103. http://www.sciencedirect.com/science/article/pii/S0301926811000738
Brusnitsyn A I, Zhukov I G. 2012. Manganese deposits of the Devonian magnitogorsk paleovolcanic belt (southern Urals, Russia)[J]. Ore Geology Reviews, 47:42-58. doi: 10.1016/j.oregeorev.2012.01.003
Chang Honglun, Kong Fanhui, Song Xiaodong, Zhao Jin, Li Jianfeng, Du Jun, Wang Congyin. 2014. Dolostone controls in Postmasburg manganese field of South Africa[J]. Acta Sedimentologica Sinica, 32(5):832-839(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-DZLP201403011.htm
Chen Yuchuan, Wang Denghong, Xu Zhigang. 2015. Important Mineral and Regional Metallogenic Regularity in China[M]. Beijing:Geological Publishing House(in Chinese).
Chetty D, Gutzmer J. 2012. REE redistribution during hydrothermal alteration of ores of the Kalahari manganese deposit[J]. Ore Geology Reviews, 47:126-135. doi: 10.1016/j.oregeorev.2011.06.001
Cong Yuan, Dong Qingjie, Xiao Keyan, Chen Jianping, Gao Yongbao, Yin Jiangning. 2018. Characteristics and predicted potential of Mn resources in China[J]. Earth Science Frontiers, 25(3):118-137(in Chinese with English abstract). http://www.researchgate.net/publication/327766360_Characteristics_and_predicted_potential_of_Mn_resources_in_China
De Putter T, Liégeois J, Dewaele S, Cailteux J, Boyce A, Mees F. 2018. Paleoproterozoic manganese and base metals deposits at Kisenge-Kamata (Katanga D R. Congo)[J]. Ore Geology Reviews, 96:181-200. doi: 10.1016/j.oregeorev.2018.04.015
Deng Wenbing, Zhang Yanwen, Kong Linghu, Shang Lei. 2019. Current status of manganese ore resources in China and selecting for national physical geological data of manganese ore deposits[J]. China Mining Magazine, 28(9):175-182(in Chinese with English abstract).
Du Q, Yi H, Hui B, Li S, Xia G, Yang W, Wu X. 2013. Recognition, genesis and evolution of manganese ore deposits in southeastern China[J]. Ore Geology Reviews, 55:99-109. doi: 10.1016/j.oregeorev.2013.05.001
Dzigbodi-Adjimah K. 2004. The mineralogy and petrography of the ferruginous manganese rocks at Mankwadzi, Ghana[J]. Journal of African Earth Sciences, 38(3):293-315. doi: 10.1016/j.jafrearsci.2003.08.001
Fairey B J, Timmerman M J, Sudo M, Tsikos H. 2019. The role of hydrothermal activity in the formation of karst-hosted manganese deposits of the Postmasburg mn field, Northern Cape Province, South Africa[J]. Minerals, 9(7):408-436. doi: 10.3390/min9070408
Fu Yong, Xu Zhigang, Pei Haoxiang, Jiang Ran. 2004. Study on metallogenic regularity of manganese ore deposits in China[J]. Acta Geologica Sinica, 88(12):2192-2207(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-DZXE201412004.htm
Ghosh R, Chakraborty D, Halder M, Baidya T K. 2015. Manganese mineralization in Archean greenstone belt, Joda-Noamundi sector, Noamundi basin, east Indian shield[J]. Ore Geology Reviews, 70:96-109. doi: 10.1016/j.oregeorev.2015.04.007
Gunn A G, Dorbor J K, Mankelow J M, Lusty P A J, Deady E A, Shaw R A, Goodenough K M. 2018. A review of the mineral potential of Liberia[J]. Ore Geology Reviews, 101:413-431. doi: 10.1016/j.oregeorev.2018.07.021
Gutzmer J, Beukes N.J.1995. Fault controlled metasomatic alteration of early Proterozoic sedimentary manganese ores in the Kalahari manganese field, South Africa[J]. Economic Geology, 90:823-844. doi: 10.2113/gsecongeo.90.4.823
Gutzmer J, Du Plooy A P, Beukes N J. 2012. Timing of supergene enrichment of low-grade sedimentary manganese ores in the Kalahari manganese field, South Africa[J]. Ore Geology Reviews, 47:136-153. doi: 10.1016/j.oregeorev.2012.04.003
He Hui. 2017. A present situation of Mn-ore resources and its investigation[J]. China's Manganese Industry, 35(1):23-24(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTotal-ZGMM201701007.htm
Hein K A A, Tshibubudze A. 2016. Manganese deposits of the Oudalan province in the northeast of Burkina Faso, and Ansongo Inlier in eastern Mali[J]. Ore Geology Reviews, 78:645-651. doi: 10.1016/j.oregeorev.2015.11.008
Hong Shikun. 2011. Status of China Mn-ore in resources exploitation and the sustainable development[J]. China's Manganese Industry, 29(3):13-16(in Chinese with English abstract). http://search.cnki.net/down/default.aspx?filename=ZGMM201103007&dbcode=CJFD&year=2011&dflag=pdfdown
Hu Dewen, Feng Dandan. 2011. An analysis of the constraints on Chinese manganese industry[J]. China Mining Magazine, 20(6):1-8(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-ZGKA201106002.htm
Klein C, Ladeira E.A. 2004. Geochemistry and mineralogy of Neoproterozoic Banded Iron Formations and some selected, siliceous manganese formations from the Urucum district, Mato Grosso do Sul, Brazil[J]. Economic Geology, 99(6):1233-1244. doi: 10.2113/gsecongeo.99.6.1233
Kuleshov V N. 2003. Isotopic composition (δ13C, δ18O) and origin of manganese carbonate ores from the early Oligocene deposits, the eastern paratethys[J]. Geochemistry, 63(4):329-363. doi: 10.1078/0009-2819-00029
Kuleshov V N. 2011. Manganese deposits:communication 2. Major epochs and phases of manganese accumulation in the Earth's history[J]. Lithology and Mineral Resources, 46:546-565. doi: 10.1134/S0024490211060095
Laznika P.1992. Manganese deposits in the global lithogenetic system:Quantitative approach[J]. Ore Geology Reviews, 7(4):279-356. doi: 10.1016/0169-1368(92)90013-B
Li Guiliang. 2018. Status quo of manganese ore in China[J]. China's Manganese Industry, 36(3):5-7(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTotal-ZGMM201803003.htm
Luo Huabao. 2002. The direction of prospecting for high quality manganese ore resources in China[J]. Geology and Exploration, 38(4):8-11(in Chinese with English abstract).
Maghfouri S, Rastad E, Mousivand F, Choulet F, Ye L. 2017. Geological and geochemical constraints on the Cheshmeh-Frezi volcanogenic stratiform manganese deposit, southwest Sabzevar basin, Iran[J]. Ore Geology Reviews, 89:96-113. doi: 10.1016/j.oregeorev.2017.06.015
Markwitz V, Hein K A A, Jessell M W, Miller J. 2016. Metallogenic portfolio of the West Africa craton[J]. Ore Geology Reviews, 78:558-563. doi: 10.1016/j.oregeorev.2015.10.024
Markwitz V, Hein K A A, Miller J. 2016. Compilation of West African mineral deposits:Spatial distribution and mineral endowment[J]. Precambrian Research, 274:61-81. doi: 10.1016/j.precamres.2015.05.028
Moore J M, Polteau S, Armstrong R A, Corfu F, Tsikos H. 2012. The age and correlation of the Postmasburg Group, southern Africa:Constraints from detrital zircon grains[J]. Journal of African Earth Sciences, 64:9-19. doi: 10.1016/j.jafrearsci.2011.11.001
Nayak B, Das S K, Bhattacharyya K K. 2011. Detrital and authigenic(?) baddeleyite (ZrO2) in ferromanganese nodules of central Indian ocean basin[J]. Geoscience Frontiers, 2:571-576. doi: 10.1016/j.gsf.2011.08.001
Ostwald J. 1988. Mineralogy of the Groote Eylandt manganese oxides:A review[J]. Ore Geology Reviews, 4(1):3-45. http://www.sciencedirect.com/science/article/pii/0169136888900030
Pickard A. 2003. SHRIMP U-Pb zircon ages for the Paleoproterozoic Kuruman Iron Formation, Northern Cape Province, South Africa:Evidence for simultaneous BIF deposition on Kaapvaal and Pilbara Cratons[J]. Precambrian Research, 125(3/4):275-315. http://www.sciencedirect.com/science/article/pii/S030192680300113X
Pracejus B, Bolton B R, Frakes L A. 1988. Nature and development of supergene manganese deposits, Groote Eylandt, northern Territory, Australia[J]. Ore Geology Reviews, 4(1):71-98. http://www.sciencedirect.com/science/article/pii/0169136888900054
Roy S. 2006. Sedimentary manganese metallogenesis in response to the evolution of the earth system[J]. Earth Science Reviews, 77:273-305. doi: 10.1016/j.earscirev.2006.03.004
Salama W, Aref M E, Gaupp R. 2012. Mineralogical and geochemical investigations of the middle Eocene ironstones, El Bahariya Depression, western Desert, Egypt[J]. Gondwana Research, 22:717-736. doi: 10.1016/j.gr.2011.11.011
Sethumadhav M S, Gunnell Y, Ahmed M M, Chinnaiah. 2010. Late Archean manganese mineralization and younger supergene maganese ores in the Anmod-Bisgod region, western Dharwar Craton, southern India:Geological characterization, palaeoenvironmental history, and geomorphological setting[J]. Ore Geology Reviews, 38:70-89. doi: 10.1016/j.oregeorev.2010.06.001
Sharkov A A. 2000. Manganese raw mineral base of russia and problem of its utilization[J]. Razved Okhr Nedr, 11:15-19.
Sheppard S, Krapez B, Zi J W, Rasmussen B, Fletcher I R. 2017. Young ores in old rocks:Proterozoic iron mineralisation in Mesoarchean Banded Iron Formation, northern Pilbara Craton, Australia[J]. Ore Geology Reviews, 89:40-69. doi: 10.1016/j.oregeorev.2017.06.003
U.S.Geological Survey. 2011. Mineral Commodity Summaries[R].
U.S.Geological Survey. 2012. Mineral Commodity Summaries[R].
U.S.Geological Survey. 2013. Mineral Commodity Summaries[R].
U.S.Geological Survey. 2014. Mineral Commodity Summaries[R].
U.S.Geological Survey. 2015. Mineral Commodity Summaries[R].
U.S.Geological Survey. 2016. Mineral Commodity Summaries[R].
U.S.Geological Survey. 2017. Mineral Commodity Summaries[R].
U.S.Geological Survey. 2018. Mineral Commodity Summaries[R].
U.S.Geological Survey. 2019. Mineral Commodity Summaries[R].
U.S.Geological Survey. 2020. Mineral Commodity Summaries[R].
Vafeas N A, Blignaut L C, Viljoen K S. 2019. Arsenic-bearing manganese ore of the Mukulu enrichment in the Kalahari manganese Field, South Africa:A new discrimination scheme for Kalahari manganese ore[J]. Ore Geology Reviews, 115:103146. doi: 10.1016/j.oregeorev.2019.103146
Wang Jian, Duan Taizhong, Xie Yuan, Wang Zhengjiang, Hao Ming, Liu Wei. 2012. The tectonic evolution and its oil and gas prospect of southeast margin of Yangtze Block[J]. Geological Bulletin of China, 31(11):1739-1749(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-ZQYD201211002.htm
Xiang J, Chen J, Bagas L, Li S, Wei H, Chen B. 2020. Southern China's manganese resource assessment:An overview of resource status, mineral system, and prediction model[J]. Ore Geology Reviews, 116:103261. doi: 10.1016/j.oregeorev.2019.103261
Xie Jin. 2017. Analysis on Investment Prospect of One Belt And One Road Manganese Ore Resources[D]. Beijing: China University of Geosciences (Beijing) (in Chinese).
Xu Shiqi, Xue Chunji, Feng Jing, Feng Changrong. 2019. Study on metallogenic regularity of manganese deposits of Xinjiang[J]. Xiangjiang Geology, 37(2):201-206(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTotal-XJDI201902012.htm
Yan Wangsheng, Gao Hailiang. 2009. The resource of Mn ore and its development of Mn-Mining[J]. China's Manganese Industry, 27(3):6-11(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-ZGMM200903002.htm
Yin Jiangning, Xiao Keyan. 2014. Resources potential analysis and metallogenic prospect of Mn resources in China[J]. Geology in China, 41(5):1424-1436(in Chinese with English abstract). http://www.researchgate.net/publication/288973332_Resources_potential_analysis_and_metallogenic_prospect_of_Mn_resources_in_China
Zang Zhongjiang, Sui Yanhui. 2019. An analysis of the present situation and utilization of manganese ore resources in Russian Federation[J]. China's Manganese Industry, 37(4):1-7(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTotal-ZGMM201904001.htm
Zhang Jingsheng, Zhou Guanghua. 2006. A review of manganese ore resources in China and its processing technology progress[J]. China's Manganese Industry, 24(1):1-5(in Chinese with English abstract). http://en.cnki.com.cn/Article_en/CJFDTOTAL-ZGMM200601000.htm
Zhang Jiuling. 1982. Geological characteristics and prospecting direction for domestic and foreign manganese mine[J]. Geology and Prospecting, 18(2):26-40(in Chinese).
Zhou Liuxia. 2000. Mining conditions and problems about China's Mn mines and some proposals[J]. China Mining Magazine, 9(49):51-54(in Chinese with English abstract). http://www.cnki.com.cn/Article/CJFDTotal-ZGMM200001002.htm
常洪伦, 孔繁辉, 宋晓东, 赵晋, 李建锋, 杜俊, 王聪颖. 2014.南非Postmasburg锰矿田白云岩的控矿作用[J].沉积学报, 32(5):832-839. https://www.cnki.com.cn/Article/CJFDTOTAL-CJXB201405005.htm
陈毓川, 王登红, 徐志刚. 2015.中国重要矿产和区域成矿规律[M].北京:地质出版社.
丛源, 董庆吉, 肖克炎, 陈建平, 高永宝, 阴江宁.2018.中国锰矿资源特征及潜力预测[J].地学前缘, 25(3):118-137. https://www.cnki.com.cn/Article/CJFDTOTAL-DXQY201803013.htm
邓文兵, 张彦文, 孔令湖, 尚磊. 2019.中国锰矿资源现状与国家级锰矿床实物地质资料筛选[J].中国矿业, 28(9):175-182. https://www.cnki.com.cn/Article/CJFDTOTAL-ZGKA201909032.htm
付勇, 徐志刚, 裴浩翔, 姜冉. 2014.中国锰矿成矿规律初探[J].地质学报, 88(12):2192-2207. https://www.cnki.com.cn/Article/CJFDTOTAL-DZXE201412004.htm
何辉. 2017.锰矿资源现状与锰矿勘查研究[J].中国锰业, 35(1):23-24. https://www.cnki.com.cn/Article/CJFDTOTAL-ZGMM200402001.htm
洪世琨.2011.我国锰矿资源开采现状与可持续发展的研究[J].中国锰业, 29(3):13-16. doi: 10.3969/j.issn.1002-4336.2011.03.004
胡德文, 冯丹丹. 2011.我国锰矿产业问题分析[J].中国矿业, 20(6):1-8. doi: 10.3969/j.issn.1004-4051.2011.06.001
黎贵亮. 2018.中国锰矿山现状[J].中国锰业, 36(3):5-7. https://www.cnki.com.cn/Article/CJFDTOTAL-ZGMM201803003.htm
骆华宝. 2002.我国优质锰矿的勘查方向[J].地质与勘探, 38(4):8-11. doi: 10.3969/j.issn.0495-5331.2002.04.002
王剑, 段太忠, 谢渊, 汪正江, 郝明, 刘伟. 2012.扬子地块东南缘大地构造演化及其油气地质意义[J].地质通报, 31(11):1739-1749. doi: 10.3969/j.issn.1671-2552.2012.11.001
谢进. 2017.一带一路锰矿资源投资前景分析[D].北京: 中国地质大学(北京).
徐仕琪, 薛春纪, 冯京, 冯昌荣. 2019.新疆锰矿成矿规律研究[J].新疆地质, 37(2):201-206. doi: 10.3969/j.issn.1000-8845.2019.02.010
严旺生, 高海亮.2009.世界锰矿资源及锰矿业发展[J].中国锰业, 27(3):6-11. doi: 10.3969/j.issn.1002-4336.2009.03.002
阴江宁, 肖克炎. 2014.中国锰矿资源潜力分析及成矿预测[J].中国地质, 41(5):1424-1436. doi: 10.3969/j.issn.1000-3657.2014.05.002 http://geochina.cgs.gov.cn/geochina/ch/reader/view_abstract.aspx?file_no=20140502&flag=1
臧忠江, 隋延辉. 2019.俄罗斯锰矿资源现状与利用情况[J].中国锰业, 37(4):1-7. https://www.cnki.com.cn/Article/CJFDTOTAL-ZGMM201904001.htm
张泾生, 周光华. 2006.我国锰矿资源及选矿进展评述[J].中国锰业, 24(1):1-5. doi: 10.3969/j.issn.1002-4336.2006.01.001
张九龄. 1982.国内外锰矿主要类型地质特征及找矿方向[J].地质与勘探, 18(2):26-40. https://www.cnki.com.cn/Article/CJFDTOTAL-DZKT198202004.htm
周柳霞. 2000.我国锰矿山的开采现状问题与建议[J].中国矿业, 9(49):51-54. https://www.cnki.com.cn/Article/CJFDTOTAL-ZGKA2000S1009.htm
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