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热带地区碳酸盐岩上覆红色风化壳的成因机理及元素演化

张连凯, 季宏兵, 刘秀明, 魏晓, 罗刚, 王世杰, NGUYENDại Trung, NGUYENQuoc Dinh. 2021. 热带地区碳酸盐岩上覆红色风化壳的成因机理及元素演化[J]. 中国地质, 48(2): 651-660. doi: 10.12029/gc20210221
引用本文: 张连凯, 季宏兵, 刘秀明, 魏晓, 罗刚, 王世杰, NGUYENDại Trung, NGUYENQuoc Dinh. 2021. 热带地区碳酸盐岩上覆红色风化壳的成因机理及元素演化[J]. 中国地质, 48(2): 651-660. doi: 10.12029/gc20210221
ZHANG Liankai, JI Hongbing, LIU Xiuming, WEI Xiao, LUO Gang, WANG Shijie, NGUYEN Dại Trung, NGUYEN Quoc Dinh. 2021. Genetic mechanism and elemental evolution of weathering laterite crust overlying carbonate rocks in tropical areas[J]. Geology in China, 48(2): 651-660. doi: 10.12029/gc20210221
Citation: ZHANG Liankai, JI Hongbing, LIU Xiuming, WEI Xiao, LUO Gang, WANG Shijie, NGUYEN Dại Trung, NGUYEN Quoc Dinh. 2021. Genetic mechanism and elemental evolution of weathering laterite crust overlying carbonate rocks in tropical areas[J]. Geology in China, 48(2): 651-660. doi: 10.12029/gc20210221

热带地区碳酸盐岩上覆红色风化壳的成因机理及元素演化

  • 基金项目:
    国家自然科学基金项目(41473122)、国家重点基础研发计划项目(2013CB956700)、国家重点研发计划项目(2017YFC0406104)及中国地质调查局地质调查项目(DD20190502)联合资助
详细信息
    作者简介: 张连凯, 男, 1981年生, 博士, 主要从事岩溶环境地质研究; E-mail: zhangliankai@karst.ac.cn
    通讯作者: 季宏兵, 男, 1966年生, 教授, 博士生导师, 主要从事环境地球化学研究与教学工作; E-mail: hongbing_ji@163.com
  • 中图分类号: P548

Genetic mechanism and elemental evolution of weathering laterite crust overlying carbonate rocks in tropical areas

  • Fund Project: Supported by National Natural Science Foundation of China (41473122), National Basic Research Program (2013CB956700), National Key Research and Development Program (2017YFC0406104), and China Geological Survey (DD20190502)
More Information
    Author Bio: ZHANG Liankai, male, born in 1981, doctor, associate researcher, engaged in the study of karst environment and geology; E-mail: zhangliankai@karst.ac.cn .
    Corresponding author: JI Hongbing, male, born in 1966, professor, engaged in the study and education of environmental geochemistry; E-mail: ji.hongbing@hotmail.com
  • 开展热带岩溶地区红色风化壳元素地球化学演化规律研究,有助于丰富碳酸盐岩风化成土理论的认识。在越南北部选取典型的碳酸盐岩风化剖面,分析热带气候条件下碳酸盐岩上覆红色风化壳中主量元素的物质来源和演化特征。结果表明:无论Ti/Zr的元素比值分析,Hf-Zr、Nb-Ta及Sm-Nd的元素对协变分析,还是上地壳元素平均值(UCC)标准化分析,两个剖面的上覆风化壳均显示原地残积的特征,即两个剖面是碳酸盐岩的原位风化产物。碳酸盐岩风化成土过程中,CaO、MgO淋失明显,Al2O3和Fe2O3发生富集,显示两个剖面均经历较强的风化过程,但是白云岩和灰岩剖面有一定的分异特征。越南北部白云岩风化剖面从基岩到上部土层显示出稳定的Ti-Fe元素共富集特征,而灰岩剖面中Fe的增长速率明显超过Ti。白云岩上覆风化壳经历了强烈的风化作用,其脱硅作用弱于灰岩风化剖面,而富集铝的作用强于灰岩。迁移系数的演化规律说明两个剖面中长石成分(钾长石、钠长石等)或次生矿物(伊利石等)在风化成土过程中逐渐分解,同时Al、Fe、Si等稳定元素的在风化剖面中不断富集。

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  • 图 1  SC和TG采样位置及剖面结构示意图

    Figure 1. 

    图 2  CaO和MgO在白云岩和石灰岩风化剖面地球化学特征

    Figure 2. 

    图 3  难溶性元素在白云岩和石灰岩风化剖面中的地球化学特征

    Figure 3. 

    图 4  白云岩和石灰岩剖面主量元素上地壳元素平均值(UCC)标准化蜘蛛图

    Figure 4. 

    图 5  Ti/Zr与Ti的百分含量散点图

    Figure 5. 

    图 6  白云岩和灰岩风化剖面Hf-Zr、Nb-Ta及Sm-Nd变化图

    Figure 6. 

    图 7  白云岩剖面和灰岩剖面不同元素的质量含量散点图及风化趋势

    Figure 7. 

    图 8  白云岩和灰岩风化剖面主量元素以Ti为参比的质量迁移系数

    Figure 8. 

    表 1  碳酸盐岩红色风化壳主量元素含量(%)

    Table 1.  Contents (%) of major elements/compounds in weathering crust over carbonate rocks

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出版历程
收稿日期:  2018-09-13
修回日期:  2019-08-08
刊出日期:  2021-04-25

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