-
摘要:
研究目的 中国地下水污染调查和修复日益受到科学界的重视，了解和掌握地下水污染修复方法和技术有助于对污染场地进行科学修复。
研究方法 本文在系统分析国内外地下水污染修复案例的基础上，对中国地下水污染修复现场实施的技术方法进行总结。
研究结果 结合中国区域经济发展特征和地下水污染调查评价成果认为，复杂的水文地质条件制约，污染物受地下水流速、流向和渗透系数的非均一性影响，使修复后的场地出现拖尾和反弹；污染物与含水层岩性制约，污染物与低渗透性岩土的附和解吸，常生成二次污染；场地详细调查和评价需求，修复工程的设计需由场地详细调查进行指导，场地地下水质量评价、地下水污染健康风险评估、污染程度评价为修复工程开展和完成提供科学依据。
结论 中国地下水污染修复面临着方法与技术方法相协调的机遇和挑战，地下水污染修复需以含水层岩性和水文地质条件为依托。
-
关键词:
- 地下水污染 /
- 修复方法 /
- 修复技术 /
- 场地 /
- 水资源与环境地质调查工程
Abstract:This paper is the result of the water resources and environmental geological survey engineering.
Objective The investigation and remediation of groundwater pollution in China has been paid more attention by the scientific community. Understanding and mastering the methods and technologies of groundwater pollution remediation is helpful for the scientific remediation of polluted sites.
Methods Based on the systematic analysis of groundwater pollution remediation cases at home and abroad, this paper summarizes the technical methods implemented on the groundwater pollution remediation site in China.
Results Combining the characteristics of China's regional economic development and the results of groundwater pollution investigation and evaluation, it is believed that the complex hydrogeological conditions are restricted, and the pollutants are affected by the heterogeneity of groundwater velocity, flow direction and permeability coefficient, which makes the restored site appear tailing. and rebound; pollutants are restricted by the lithology of aquifers, and the adhesion and desorption of pollutants and low-permeability rock and soil often generate secondary pollution; Groundwater quality assessment, groundwater pollution health risk assessment, and pollution degree assessment provide a scientific basis for the development and completion of restoration projects.
Conclusions Groundwater pollution remediation in China faces opportunities and challenges in the coordination of methods and technical methods. Groundwater pollution remediation needs to rely on aquifer lithology and hydrogeological conditions.
-
-
图 2 污染物在含水系统中的迁移转化路径(据Foster, 1987)
Figure 2.
图 3 地下水重质非水相污染模式图(据Stroo et al., 2015)
Figure 3.
图 6 地下水污染可渗透性反应墙技术示意图(USEPA, 1998)
Figure 6.
图 7 PRB结构示意图（a, 连续墙式PRB；b, 隔水墙漏斗门式PRB）(USEPA, 1998)
Figure 7.
表 1 不同PRB结构类型的优缺点与使用条件(宋权威等, 2019)
Table 1. Advantages, disadvantages and usage conditions of different PRB structure types (Song et al., 2019)
下载: 导出CSV
-
Bass D H, Hastings N A, Brown R A. 2000. Performance of air sparging systems: A review of case studies[J]. J. Hazard. Mater., 72(2/3): 101-119.
Baker R S, Nielsen S G, Heron G, Ploug N. 2016. How effective is thermal remediation of DNAPL source zones in reducing groundwater concentrations?[J]. Groundwater Monitoring & Remediation, 36(1): 38-53.
Beijing Municipal Ecology and Environment Bureau. 2019. Construction Land Soil Pollution Risk Control and Remediation List of Beijing[R]. Beijing: Beijing Municipal Ecology and Environment Bureau.
Ben Neriah A, Paster A. 2016. Effect of temporal changes in air injection rate on air sparging performance groundwater remediation[J]. Groundwater, 54(6): 851-860. doi: 10.1111/gwat.12428
Chao H, Hsieh L, Hai N T. 2018. Increase in volatilization of organic compounds using air sparging through addition in alcohol in a soil-water system[J]. Journal of Hazardous Materials, 344: 942-949. doi: 10.1016/j.jhazmat.2017.11.053
Chapelle F H. 2001. Ground-water Microbiology and Geochemistry[M]. New York: Wiley.
Chen Honghan, Chen Hongwei, He Jiangtao, Liu Fei, Shen Zhaoli, Han Bing, Sun Jing. 2006. Health-based risk assessment of contaminated sites: Principles and methods[J]. Earth Science Frontiers, 13(1): 216-223(in Chinese with English abstract).
Chen Mengfang, Han Lu, Luo Fei. 2017. Methodology for Risk Assessment of Soil and Groundwater in Contaminated Sites [M]. Beijing: Science Press.
Chen Sili, Yi Zhongyuan, Wang Ji, Pan Chaoyi, Chang Sha, Guo Qingwei, Zhou Junguang, Sun Lan. 2020. Case study on remediation of diesel contaminated soil and groundwater by eluent-extraction technology[J]. Environmental Engineering, 38(1): 178-182(in Chinese with English abstract).
Chen Zhongru, Zhang Chengbo, Li Hongyi, Zhang Yongding, Qiu Jinan, Lin Tao. 2012. On the structure and design of permeable reactive barrier[J]. Journal of Safety and Environment, 12(4): 56-61(in Chinese with English abstract).
China Geological Survey. [2016-05-17]. National Groundwater Quality and Pollution Survey (2005-2015)[DB/OL]. https://www.cgs.gov.cn/ddztt/jqthd/lhfjkwzz/dqhxdccg/201607/t20160705_337538.html.
Chu Tong, Yang Yuesuo, Lu Ying, Wu Yuhui, Chen Yu, Du Xinqiang. 2018. Thermal enhanced air sparging for oil contamination remediation in shallow groundwater of cold regions[J]. CIESC Journal, 69(8): 3701-3710(in Chinese with English abstract).
Compounds I C O R, Wickramanayake G B, Gavaskar A R, Chen A. 2000. Chemical Oxidation and Reactive Barriers: Remediation of Chlorinated and Recalcitrant Compounds[M]. Columbus: Battelle Press.
Dadrasnia A, Shahsavari N, Emenike C U. 2013. Remediation of Contaminated Sites[M]. Hydrocarbon.
Decree of the state council of the People's Republic of China. 2011. National Groundwater Pollution Control Plan(2011-2020)[R]. Beijing: Decree of the state council of the People's Republic of China.
Decree of the state council of the People's Republic of China. 2015. Action Plan for Prevention and Control of Water Pollution[R]. Beijing: Decree of the state council of the People's Republic of China.
Department of Ecology and Environment of Hebei Province. 2019. Construction Land Soil Pollution Risk Control and Remediation List of Hebei [R]. Shijiazhuang: Department of Ecology and Environment of Hebei Province.
Edwards D A, Little J W, Lanik W, Hajali P A. 2002. Calibration of a model for volatile organic compound mass removal by multiphase extraction[J]. Journal of Environmental Engineering (New York, N.Y. ), 128(5): 472-475.
Faisal A A H, Sulaymon A H, Khaliefa Q M. 2018. A review of permeable reactive barrier as passive sustainable technology for groundwater remediation[J]. International Journal of Environmental Science and Technology, 15(5): 1123-1138. doi: 10.1007/s13762-017-1466-0
Fei Yuhong, Zhang Zhaoji, Guo Chunyan, Wang Chunxiao, Lei Ting, Liu Jin. 2014. Research on the method for evaluation and influence factors identification of regional groundwater quality: A case study of the North China Plain[J]. Acta Geoscientica Sinica, 35(2): 131-138(in Chinese with English abstract).
Foster S S D. 1987. Fundamental Concepts in Aquifer Vulnerability, Pollution Risk and Protection Strategy[M]. The Netherlands, Netherlands Organization for Applied Scientific Research: Delft, .
Gillham R W, O'Hannesin S F. 1994. Enhanced degradation of halogenated aliphatics by zero-valent iron[J]. Ground Water, 32(6): 958-967. doi: 10.1111/j.1745-6584.1994.tb00935.x
Gu Xu, Du Peng, Shan Huimei, Ma Teng, Cheng Shenggao. 2014. Application of hydraulic capture technique in groundwater pollution restoration[J]. Safety and Environmental Engineering, 21(4): 52-58(in Chinese with English abstract).
Guo Lili, Kang Shaoguo, Wang Qi, Xiong Jing, Li Shupeng, Kong Jiaoyan. 2020. Permeable reactive barrier for chromium contaminated groundwater remediation: An overview[J]. Environmental Engineering, 38(6): 9-15(in Chinese with English abstract).
Han Yu, Liu Yuxian, Ding Guantao, Liu Yuxiang, Cao Guangming, Zhang Ruipeng, Sun Zhongjin, Tang Xiaoshan. 2019. Technologies of VOCs pollution remediation in groundwater[J]. Acta Geologica Sinica, 93(S1): 284-290(in Chinese with English abstract). doi: 10.1111/1755-6724.14094
Hicknell B N, Mumford K G, Kueper B H. 2018. Laboratory study of creosote removal from sand at elevated temperatures[J]. Journal of Contaminant Hydrology, 219: 40-49. doi: 10.1016/j.jconhyd.2018.10.006
Hou Guohua, Liu Fei, Liu Mingzhu, Kong Xiangke, Li Shengpin, Chen Liang, Colberg P J S, Jin Song, Chen Honghan. 2014. Performance of a permeable reactive barrier for in situ removal of ammonium in groundwater[J]. Water Science and Technology-Water Supply, 14(4): 585-592. doi: 10.2166/ws.2014.012
Huang Yongbing. 2018. Remediation of Arsenic Contaminated Groundwater by Manganese Ores and PRB Engineering Technology[D]. Wuhan: Huazhong Agricultural University(in Chinese with English abstract).
Johnson R L, Johnson P C, Mcwhorter D B, Hinchee R E, Goodman I. 1993. An overview of in situ air sparging[J]. Ground Water Monitoring & Remediation, 13(4): 127-135.
Li Chunping, Chen Mengfang, Luo Yongming, Song Jing, Wu Chunfa, Luo Fei, Wei Jing. 2011. Contaminants of concern and adverse environmental impact for key industries[J]. The Administration and Technique of Environmental Monitoring, 23(3): 7-13(in Chinese with English abstract).
Li Haixue, Han Shuangbao, Wu Xi, Wang Sai, Liu Weipo, Ma Tao, Zhang Mengnan, Wei Yutao, Yuan Fuqiang, Yuan Lei, Li Fucheng, Wu Bin, Wang Yushan, Zhao Minmin, Yang Hanwen, Wei Shibo, 2021. Distribution, characteristics and influencing factors of fresh groundwater resources in the Loess Plateau, China[J]. China Geology, 4(3): 509-526.
Li M T, Hao L L, Sheng L X, Xu J B. 2008. Identification and degradation characterization of hexachlorobutadiene degrading strain Serratia marcescens HL1[J]. Bioresource Technology, 99(15): 6878-6884. doi: 10.1016/j.biortech.2008.01.048
Li Shengpin, Huang Guoxin, Kong Xiangke, Yang Yingzhao, Liu Fei, Hou Guohua, Chen Honghan. 2014. Ammonium removal from groundwater using a zeolite permeable reactive barrier: A pilot-scale demonstration[J]. Water Science and Technology, 70(9): 1540-1547. doi: 10.2166/wst.2014.411
Li Yasong, Zhang Zhaoji, Fei Yuhong, Qian Yong, Wang Zhao, Chen Jingsheng, Zhang Fenge. 2014. Groundwater quality and contamination characteristics in the Hutuo River plain area, Hebei Province[J]. Acta Geoscientica Sinica, 35(2): 169-176(in Chinese with English abstract).
Li Zhenghong, Zhang Cuiyun, Zhang Sheng, Yin Miying, Ma Linna, Guo Xiuhong. 2007. Review on groundwater microbiology[J]. South-to-North Water Diversion and Water Science & Technology, 5(5): 60-63(in Chinese with English abstract).
Liu Weijiang, Chen Jian, Liu Rui, Liu Xin, Niu Haobo, Su Chunli. 2018. Investigation and evaluation of groundwater pollution around a chemical plant in Tancheng Country[J]. Safety and Environmental Engineering, 25(6): 67-75(in Chinese with English abstract).
Liu Weijiang, Fei Yuhong, Jing Liuxin, Wang Dong, Zhao Yongsheng. 2016. Technology Methods and Cases of Ground Water Pollution Prevention and Control in Typical Areas of North China Plain [M]. Beijing: China Environmental Science Press.
Liu Yong, Wang Chengjun, Liu Hua, Ma Hongzhou, Zhang Qionghua, Feng Tao, Sun Dalin. 2015. Spatial distribution and ecological risk assessment of heavy metals in soil around a lead and zinc smelter [J]. Chinese Journal of Environmental Engineering, 9(1): 477-484(in Chinese with English abstract).
Lowry G V, Reinhard M. 1999. Hydrodehalogenation of 1- to 3-carbon halogenated organic compounds in water using a palladium catalyst and hydrogen gas[J]. Environmental Science & Technology, 33(11): 1905-1910.
Mani Tripathi S, Chaurasia S. 2018. Bioremediation of groundwater: An overview[J]. International Journal of Applied Engineering Research, 13: 16825-16832.
Meng Liang, Guo Lin, Yang Jie, Luo Qishi. 2014. Research on the pilot scale in situ remediation of groundwater polluted by chlorinated hydrocarbons in a contaminated site[J]. Industrial Water Treatment, 34(8): 18-21(in Chinese with English abstract).
Miao Jinjie, Jin Jihong, Du Dong, Liu Hongwei, Bai Yaonan, Zhang Jing, Guo Xu. 2020. Valuation of groundwater environmental quality and causes of problems in the capital sub-center and key regions[J]. Geological Survey and Research, 43(3): 224-229, 286(in Chinese with English abstract).
Ministry of Ecology and Environment of the People's Republic of China, Ministry of Natural Resources of the People's Republic of China, Ministry of Housing and Urban-Rural Development of the People's Republic of China, Ministry of Water Resources of the People's Republic of China, Ministry of Agriculture and Rural Affairs of the People's Republic of China. 2019. Groundwater Pollution Prevention Implementation of The Programme[R]. Beijing: Ministry of Ecology and Environment of the People's Republic of China.
Ministry of Environmental Protection of the People's Republic of China, Ministry of Land and Resources of the People's Republic of China, Ministry of Housing and Urban-Rural Development of the People's Republic of China, Ministry of Water Resources of the People's Republic of China. 2013. Groundwater Pollution Prevention and Control Programme in North China Plain[R]. Beijing: Ministry of Environmental Protection of the People's Republic of China.
Ministry of Water Resources of the People's Republic of China. [2021-07-09]. 2020 China Water Resources Bulletin [DB/OL]. http://www.mwr.gov.cn/sj/tjgb/szygb/202107/t20210709_1528208.html.
Montgomery J H. 2000. Groundwater Chemicals Desk Reference, Fourth Edition[M]. CRC Press.
Neriah A B, Paster A. 2019. Enhancing groundwater remediation in air sparging by changing the pulse duration[J]. Groundwater Monitoring & Remediation, 39(1): 43-53.
O'Hannesin S F U O, Gillham R W. 1998. Long-term performance of an in situ "iron wall" for remediation of VOCs[J]. Ground Water, 36(1): 164-170. doi: 10.1111/j.1745-6584.1998.tb01077.x
Pu Min. 2017. Reviews on groundwater contaminants control and remediation technology: Rump and treat[J]. Environmental Engineering, 35(4): 6-10(in Chinese with English abstract).
Pu Shengyan, Hou Guoqing, Lu Xue, Li Bowen. 2020. Review on application of calcium peroxide controlled-release technology in groundwater pollution remediation[J]. Industrial Water Treatment, 40(8): 1-6(in Chinese with English abstract).
Qi Shengqi, Luo Jian, O'Connor D, Wang Yidong, Hou Deyi. 2020. A numerical model to optimize LNAPL remediation by multi-phase extraction[J]. The Science of the Total Environment, 718: 137309. doi: 10.1016/j.scitotenv.2020.137309
Qiao Wenjing, Luo Fer, Lomheim L, Mack E E, Ye Shujun, Wu Jichun, Edwards E A. 2018. Natural attenuation and anaerobic benzene detoxification processes at a chlorobenzene-contaminated industrial site inferred from field investigations and microcosm studies[J]. Environmental Science & Technology, 52(1): 22-31.
Qu Zhihui, Wang Hongtao, Yang Yong, Yuan Sili, Sang Zhiwei, Zhang Yuhu. 2016. Research on effect in remediation of chlorobenzene contaminated groundwater by circulation well[J]. Chemical Engineer, 30(11): 29-32(in Chinese with English abstract).
Sale T, Applegate D. 1997. Mobile NAPL recovery: Conceptual, field, and mathematical considerations[J]. Ground Water, 35(3): 418-426. doi: 10.1111/j.1745-6584.1997.tb00101.x
Shang Lei, Dong Mingfang, Tian Xizhao, Shan Qiang, Bai Zhenyu. 2017. The engineering application of joint repair technology for Cr6+ in a sewage treatment site in Tangshan[J]. Environmental Engineering, 35(S1): 281-284(in Chinese with English abstract).
Song Quanwei, Zhao Xingda, Chen Changzhao, Zhang Kunfeng, Chen Hongkun, Liu Yuling. 2019. Study on PRB remediation of groundwater polluted by oil pollutants[J]. Environmental Protection of Oil & Gas Fields, 29(1): 1-4(in Chinese with English abstract).
Song Xinglong. 2015. Laboratory Simulation Study of Air Sparging for Remediation of Groundwater Pollution[D]. Chuangchun: Jilin University(in Chinese with English abstract).
Song Yinan, Hou Deyi, Zhao Yongsheng, Zhu Jin, Zhang Qi, Qin Chuanyu, Wang Wenfeng. 2020. Remediation strategies for contaminated groundwater at chemical industrial sites in the Beijing-Tianjin-Hebei Region[J]. Research of Environmental Sciences, 33(6): 1345-1356(in Chinese with English abstract).
Stroo H F, Ward C H. 2015. In Situ Remediation of Chlorinated Solvent Plumes[M]. Beijing: Geological Publishing House.
Tianjin Ecology and Environment Bureau. 2019. Construction Land Soil Pollution Risk Control and Remediation List of Tianjin[R]. Tianjin: Tianjin Ecology and Environment Bureau.
Travis M M, James M M, Charles J N. 2006. Performance of DNAPL source depletion technologies at 59 chlorinated solvent-impacted sites[J]. Ground Water Monitoring & Remediation, 26(1): 73-84.
USACE. 1999. Engineering and extraction[R]. Washington DC: United States Army Corps of Engineers.
USEPA. 1998. Permeable Reactive Barrier Technologies for Contaminant Remediation[R]. Washington DC: USEPA.
USEPA. 2004. EPA 542-R-04-010, In Situ Thermal Treatment of Chlorinated Solvents. Fundamentals and Field Applications[S]. Washington, DC, USA.
Wang Di, Wei Wenxia, Wang Linling, Wang Haijian, Li Jiabin. 2018. Remediation of chromium (Ⅵ) contaminated groundwater by in-situ injection of nanoscale zero valent iron[J]. Chinese Journal of Environmental Engineering, 12(2): 521-526(in Chinese with English abstract).
Wang Hefei, Song Xinglong, Zhao Yongsheng, Wang Xiaoman, Wang Qian, Qin Chuanyu, Sun Jiaqiang. 2014. Laboratory study for air flow during air sparging[J]. China Environmental Science, 34(11): 2813-2816(in Chinese with English abstract).
Wang Jialiang. 2019. Application of extraction processing technology in groundwater pollution restoration project[J]. Shanghai Construction Science & Technology, (1): 67-69(in Chinese).
Wang Jinhuai, Gu Chunjie. 2017. Engineering application of multiphase extraction and in-situ chemical oxidation combined technology in organic contaminated sites[J]. Shanghai Chemical Industry, 42(12): 20-24(in Chinese with English abstract).
Wang Lei, Long Tao, Zhang Feng, Zhu Xin, Tian Meng, Lin Yusuo. 2014. Advancement in development of multi-phase extraction (MPE) technology for remediation of soil and groundwater[J]. Journal of Ecology and Rural Environment, 30(2): 137-145(in Chinese with English abstract).
Wang Peng, Chen Wenying, Pu Shengyan. 2021. Research progress of enhanced in situ bioremediation technology for groundwater circulation well [J]. Safety and Environmental Engineering, 28(3): 137-146(in Chinese with English abstract).
Wang Song, Chen Jiachang, Dai Zhenyu, Zhang Qiyi, Li Yunlong, Zhang Baogang. 2021. A research on microbial remediation of ti contaminated groundwater[J]. Earth and Environment, 46(3): 282-287(in Chinese with English abstract).
Wang Y. 2007. Groundwater Contamination[M]. Beijing: Higher Education Press.
Wen Dongguang, Lin Liangjun, Sun Jichao, Zhang Zhaoji, Jiang Yuehua, Ye Nianjun, Fei Yuhong, Qian Yong, Gong Jianshi, Zhou Xun, Zhang Yuxi. 2012. Groundwater quality and contamination assessment in the main plains of eastern China[J]. Earth Science——Journal of China University of Geosciences, 37(2): 220-228(in Chinese with English abstract).
Xi Beidou, Li Juan, Wang Yang, Tang Jun, Hong Hui. 2019. Strengthening the innovation capability of groundwater science and technology to support the coordinated development of Beijing-Tianjin-Hebei Region: Status quo, problems and goals[J]. Research of Environmental Sciences, 32(1): 1-9(in Chinese with English abstract).
Yang Mei, Fei Yuhong. 2008. Research summary on groundwater pollution remediation technology[J]. Site Investigation Science and Technology, (4): 12-16(in Chinese with English abstract).
Yang Xiaomin, Beckmann D, Fiorenza S, Niedermeier C. 2005. Field study of pulsed air sparging for remediation of petroleum hydrocarbon contaminated soil and groundwater[J]. Environmental Science & Technology, 39(18): 7279-7286.
Zhang Huiling, Zhang Wen, Zhang Qingquan, Liu Cuicui, Ma Tianhai, Guo Hongyan. 2016. Research and application of composite slow-release functional materials for in situ remediation of nitrate-contaminated groundwater[J]. Journal of Nanjing University (Natural Sciences), 52(1): 115-124(in Chinese with English abstract).
Zhang Jing, Zhang Feng, Ma Lie. 2016. Combined application of multiple remediation technologies by multi-phase extraction and in-situ chemical oxidation[J]. Environmental Protection Science, 42(3): 154-158(in Chinese with English abstract).
Zhang Shuai, Wang Xusheng, Jiang Yonghai, Yang Yu. 2020. Theoretical equation of recovery ratio for treatment on groundwater contamination with paired wells of extraction-injection[J]. Journal of Hydraulic Engineering, 51(5): 589-596(in Chinese with English abstract).
Zhang Wei, Han Zhantao, Xu Guangming. 2012. Problems and countermeasures of using nanoscale zero-valent iron in groundwater contamination remediation[J]. South-to-North Water Diversion and Water Science & Technology, 10(4): 34-38(in Chinese with English abstract).
Zhang Ying. 2004. Study on Organic Chemicals Removal Using Air Sparging [D]. Tianjin: Tianjin University.
Zhang Zhaoji. 2015. Method for Regional Groundwater Contamination Survey and Evaluation[M]. Beijing: Science Press.
Zhang Zhaoji, Fei Yuhong, Guo Chunyan, Qian Yong, Li Yasong. 2012. Regional groundwater contamination assessment in the north china plain[J]. Journal of Jilin University (Earth Science Edition), 42(5): 1456-1461(in Chinese with English abstract).
Zhao Xuesong. 2020. Application of improved grey cluster method in shallow groundwater quality comprehensive evaluation [J]. Water Resources & Hydropower of Northeast China, 38(8): 56-57, 60(in Chinese with English abstract)
Zhao Yongsheng. 2007. Groundwater pollution control and remediation[J]. Journal of Jilin University (Earth Science Edition), (2): 303-310(in Chinese with English abstract).
Zhao Yongsheng, Yang Yuanyuan, Gao Penglong, Kang Xuehe, Wang Haoying, Chang Yuehua. 2019. Migration characteristics of steam and its remediation to chlorobenzene contaminated soil[J]. Journal of Jilin University (Earth Science Edition), 49(5): 1431-1437(in Chinese with English abstract).
Zhou Xiaoni, Wang Zhenxing, Miao Qingzhuang, Zhang Bing. 2020. Study the shallow groundwater chemical characteristics in the typical area of Zhanghe catchment basin[J]. Geological Survey and Research, 43(3): 265-270(in Chinese with English abstract).
北京市生态环境局. 2019. 北京市建设用地土壤污染风险管控和修复名录[R]. 北京: 北京市生态环境局.
陈鸿汉, 谌宏伟, 何江涛, 刘菲, 沈照理, 韩冰, 孙静. 2006. 污染场地健康风险评价的理论和方法[J]. 地学前缘, (1): 216-223. doi: 10.3321/j.issn:1005-2321.2006.01.029
陈梦舫, 韩璐, 罗飞. 2017. 污染场地土壤与地下水风险评估方法学[M]. 北京: 科学出版社.
陈思莉, 易仲源, 王骥, 潘超逸, 常莎, 虢清伟, 周俊光, 孙兰. 2020. 淋洗-抽提技术修复柴油污染土壤及地下水案例分析[J]. 环境工程, 38(1): 178-182. https://www.cnki.com.cn/Article/CJFDTOTAL-HJGC202001029.htm
陈仲如, 张澄博, 李洪艺, 张永定, 邱锦安, 林涛. 2012. 可渗透反应墙的结构与设计研究[J]. 安全与环境学报, 12(4): 56-61. doi: 10.3969/j.issn.1009-6094.2012.04.013
初彤, 杨悦锁, 路莹, 武宇辉, 陈煜, 杜新强. 2018. 寒区石油污染场地浅层地下水原位增温强化空气扰动修复[J]. 化工学报, 69(8): 3701-3710. https://www.cnki.com.cn/Article/CJFDTOTAL-HGSZ201808046.htm
费宇红, 张兆吉, 郭春艳, 王春晓, 雷廷, 刘瑾. 2014. 区域地下水质量评价及影响因素识别方法研究——以华北平原为例[J]. 地球学报, 35(2): 131-138. https://www.cnki.com.cn/Article/CJFDTOTAL-DQXB201402002.htm
顾栩, 杜鹏, 单慧媚, 马腾, 程胜高. 2014. 水力截获技术在地下水污染修复中的应用——以某危险废物填埋场为例[J]. 安全与环境工程, 21(4): 52-58. doi: 10.3969/j.issn.1671-1556.2014.04.011
郭丽莉, 康绍果, 王祺, 熊静, 李书鹏, 孔娇艳. 2020. 渗透式反应墙技术修复铬污染地下水的研究进展[J]. 环境工程, 38(6): 9-15. https://www.cnki.com.cn/Article/CJFDTOTAL-HJGC202006002.htm
韩昱, 刘玉仙, 丁冠涛, 刘玉想, 曹光明, 张瑞鹏, 孙中瑾, 汤晓珊. 2019. 地下水VOCs污染修复技术探讨[J]. 地质学报, 93(S1): 284-290. https://www.cnki.com.cn/Article/CJFDTOTAL-DZXE2019S1036.htm
河北省生态环境厅. 2019. 河北省建设用地土壤污染风险管控和修复名录[R]. 石家庄: 河北省生态环境厅.
环境保护部, 国土资源部, 住房和城乡建设部, 水利部. 2013. 华北平原地下水污染防治工作方案[R]. 北京: 环境保护部.
黄永炳. 2018. 锰矿修复砷污染地下水及其PRB工程技术研究[D]. 华中农业大学.
李春平, 陈梦舫, 骆永明, 宋静, 吴春发, 罗飞, 韦婧. 2011. 重点行业的关注污染物与环境危害简析[J]. 环境监测管理与技术, 23(3): 7-13. doi: 10.3969/j.issn.1006-2009.2011.03.003
李亚松, 张兆吉, 费宇红. 2014. 河北省滹沱河冲积平原地下水质量及污染特征研究[J]. 地球学报, 35(2): 169-176. https://www.cnki.com.cn/Article/CJFDTOTAL-DQXB201402008.htm
李政红, 张翠云, 张胜, 殷密英, 马琳娜, 郭秀红. 2007. 地下水微生物学研究进展综述[J]. 南水北调与水利科技, 5(5): 60-63. doi: 10.3969/j.issn.1672-1683.2007.05.018
刘伟江, 陈坚, 刘锐, 刘欣, 牛浩博, 苏春利. 2018. 郯城某化工厂周边地下水污染现状调查与评价[J]. 安全与环境工程, 25(6): 67-75. https://www.cnki.com.cn/Article/CJFDTOTAL-KTAQ201806011.htm
刘伟江, 费宇红, 井柳新, 王东, 赵勇胜. 2016. 华北平原典型地区地下水污染防控技术方法及案例[M]. 北京: 中国环境出版社.
刘勇, 王成军, 刘华, 马红周, 张琼华, 冯涛, 孙大林. 2015. 铅锌冶炼厂周边重金属的空间分布及生态风险评价[J]. 环境工程学报, 9(1): 477-484. https://www.cnki.com.cn/Article/CJFDTOTAL-HJJZ201501079.htm
孟梁, 郭琳, 杨洁, 罗启仕. 2014. 原位修复氯代烃污染场地地下水的现场中试研究[J]. 工业水处理, 34(8): 18-21. https://www.cnki.com.cn/Article/CJFDTOTAL-GYSC201408006.htm
苗晋杰, 靳继红, 杜东, 刘宏伟, 白耀楠, 张竞, 郭旭. 2020. 首都副中心及重点区域地下水环境质量评价与问题成因[J]. 地质调查与研究, 43(3): 224-229, 286. doi: 10.3969/j.issn.1672-4135.2020.03.005
蒲敏. 2017. 污染场地地下水抽出处理技术研究[J]. 环境工程, 35(4): 6-10. https://www.cnki.com.cn/Article/CJFDTOTAL-HJGC201704002.htm
蒲生彦, 侯国庆, 吕雪, 李博文. 2020. 过氧化钙缓释技术在地下水污染修复中的应用研究[J]. 工业水处理, 40(8): 1-6. https://www.cnki.com.cn/Article/CJFDTOTAL-GYSC202008001.htm
屈智慧, 王洪涛, 杨勇, 袁思莉, 桑志伟, 张玉虎. 2016. 循环井技术修复地下水氯苯污染的效果研究[J]. 化学工程师, 30(11): 29-32. https://www.cnki.com.cn/Article/CJFDTOTAL-HXGC201611010.htm
商磊, 董明芳, 田西昭, 单强, 白振宇. 2017. 唐山某电镀厂污水污染场地Cr(Ⅵ)的联合修复技术工程实例[J]. 环境工程, 35(增刊): 281-284. https://cpfd.cnki.com.cn/Article/CPFDTOTAL-GYJZ201708003063.htm
生态环境部, 自然资源部, 住房城乡建设部, 水利部, 农业农村部. 2019. 地下水污染防治实施方案[R]. 北京: 生态环境部.
宋权威, 赵兴达, 陈昌照, 张坤峰, 陈宏坤, 刘玉龙. 2019. 渗透反应格栅修复地下水石油类污染研究[J]. 油气田环境保护, 29(1): 1-4. doi: 10.3969/j.issn.1005-3158.2019.01.001
宋兴龙. 2015. 地下水污染原位空气扰动修复技术模拟实验研究[D]. 长春: 吉林大学.
宋易南, 侯德义, 赵勇胜, 朱瑾, 张琪, 秦传玉, 王文峰. 2020. 京津冀化工场地地下水污染修复治理对策研究[J]. 环境科学研究, 33(6): 1345-1356. https://www.cnki.com.cn/Article/CJFDTOTAL-HJKX202006006.htm
天津市生态环境局. 2019. 天津市建设用地土壤污染风险管控和修复名录[R]. 天津: 天津市生态环境局.
王棣, 魏文侠, 王琳玲, 王海见, 李佳斌. 2018. 纳米铁原位注入技术对六价铬污染地下水的修复[J]. 环境工程学报, 12(2): 521-526. https://www.cnki.com.cn/Article/CJFDTOTAL-HJJZ201802024.htm
王贺飞, 宋兴龙, 赵勇胜, 王晓曼, 王倩, 秦传玉, 孙家强. 2014. 地下水曝气技术气流模拟实验研究[J]. 中国环境科学, 34(11): 2813-2816. https://www.cnki.com.cn/Article/CJFDTOTAL-ZGHJ201411015.htm
王家樑. 2019. 抽出处理技术在地下水污染修复工程中的应用[J]. 上海建设科技, (1): 67-69. doi: 10.3969/j.issn.1005-6637.2019.01.021
王锦淮, 顾春杰. 2017. 多相抽提+原位化学氧化联合技术在有机污染场地的工程应用[J]. 上海化工, 42(12): 20-24. doi: 10.3969/j.issn.1004-017X.2017.12.010
王磊, 龙涛, 张峰, 祝欣, 田猛, 林玉锁. 2014. 用于土壤及地下水修复的多相抽提技术研究进展[J]. 生态与农村环境学报, 30(2): 137-145. doi: 10.3969/j.issn.1673-4831.2014.02.001
王朋, 陈文英, 蒲生彦. 2021. 地下水循环井原位强化生物修复技术研究进展[J]. 安全与环境工程, 28(3): 137-146. https://www.cnki.com.cn/Article/CJFDTOTAL-KTAQ202103019.htm
王松, 陈家昌, 戴振宇, 张七一, 李云龙, 张宝刚. 2018. 铊污染地下水的微生物修复研究[J]. 地球与环境, 46(3): 282-287. https://www.cnki.com.cn/Article/CJFDTOTAL-DZDQ201803010.htm
王焰新. 2007. 地下水污染与防治[M]. 北京: 高等教育出版社.
文冬光, 林良俊, 孙继朝, 张兆吉, 姜月华, 叶念军, 费宇红, 钱永, 龚建师, 周迅, 张玉玺. 2012. 中国东部主要平原地下水质量与污染评价[J]. 地球科学(中国地质大学学报), 37(2): 220-228. https://www.cnki.com.cn/Article/CJFDTOTAL-DQKX201202005.htm
席北斗, 李娟, 汪洋, 唐军, 洪慧. 2019. 京津冀地区地下水污染防治现状、问题及科技发展对策[J]. 环境科学研究, 32(1): 1-9. https://www.cnki.com.cn/Article/CJFDTOTAL-HJKX201901001.htm
杨梅, 费宇红. 2008. 地下水污染修复技术的研究综述[J]. 勘察科学技术, (4): 12-16. doi: 10.3969/j.issn.1001-3946.2008.04.004
张会玲, 张雯, 张庆泉, 刘翠翠, 马天海, 郭红岩. 2016. 复合缓释功能材料原位修复硝酸盐污染地下水的研究和应用[J]. 南京大学学报(自然科学), 52(1): 115-124. https://www.cnki.com.cn/Article/CJFDTOTAL-NJDZ201601013.htm
张晶, 张峰, 马烈. 2016. 多相抽提和原位化学氧化联合修复技术应用——某有机复合污染场地地下水修复工程案例[J]. 环境保护科学, 42(3): 154-158. https://www.cnki.com.cn/Article/CJFDTOTAL-HJBH201603028.htm
张帅, 王旭升, 姜永海, 杨昱. 2020. 双井抽灌处理地下水污染的回收率理论公式[J]. 水利学报, 51(5): 589-596. https://www.cnki.com.cn/Article/CJFDTOTAL-SLXB202005010.htm
张威, 韩占涛, 许广明. 2012. 纳米零价铁用于地下水污染修复时存在的问题与对策[J]. 南水北调与水利科技, 10(4): 34-38. https://www.cnki.com.cn/Article/CJFDTOTAL-NSBD201204012.htm
张兆吉, 费宇红, 郭春艳, 钱永, 李亚松. 2012. 华北平原区域地下水污染评价[J]. 吉林大学学报(地球科学版), 42(5): 1456-1461. https://www.cnki.com.cn/Article/CJFDTOTAL-CCDZ201205019.htm
张兆吉. 2015. 区域地下水污染调查评价技术方法[M]. 北京: 科学出版社.
赵雪松. 2020. 改进灰色聚类法在地下浅层水质评价中的应用[J]. 东北水利水电, 38(8): 56-57, 60. https://www.cnki.com.cn/Article/CJFDTOTAL-DBSL202008023.htm
赵勇胜. 2007. 地下水污染场地污染的控制与修复[J]. 吉林大学学报(地球科学版), (2): 303-310. https://www.cnki.com.cn/Article/CJFDTOTAL-CCDZ200702017.htm
赵勇胜, 杨元元, 高鹏龙, 康学赫, 王昊颖, 常月华. 2019. 多孔介质中热蒸汽的迁移特性及其修复氯苯污染土壤的效果[J]. 吉林大学学报(地球科学版), 49(5): 1431-1437. https://www.cnki.com.cn/Article/CJFDTOTAL-CCDZ201905021.htm
张英. 2004. 地下水曝气(AS)处理有机物的研究[D]. 天津: 天津大学.
周晓妮, 王振兴, 苗青壮, 张冰. 2020. 漳河流域典型区浅层地下水水化学特征分析[J]. 地质调查与研究, 43(3): 265-270. doi: 10.3969/j.issn.1672-4135.2020.03.011
中国地质调查局. [2016-05-17]. 全国地下水质量与污染调查计划(2005-2015)[DB/OL]. https://www.cgs.gov.cn/ddztt/jqthd/lhfjkwzz/dqhxdccg/201607/t20160705_337538.html.
中华人民共和国国务院. 2011. 全国地下水污染防治规划(2011-2020年)[R]. 北京: 中华人民共和国国务院.
中华人民共和国国务院. 2015. 水污染防治行动计划[R]. 北京: 中华人民共和国国务院.
中华人民共和国水利部. [2021-07-09]. 2020年中国水资源公报[DB/OL]. http://www.mwr.gov.cn/sj/tjgb/szygb/202107/t20210709_1528208.html.
-
图(7)
表(1)
计量
- 文章访问数: 12194
- PDF下载数: 445
- 施引文献: 0