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南岭成矿带中—晚侏罗世成钨、成锡、成铅锌(铜)花岗岩的差异性研究

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秦拯纬, 付建明, 邢光福, 程顺波, 卢友月, 祝颖雪. 2022. 南岭成矿带中—晚侏罗世成钨、成锡、成铅锌(铜)花岗岩的差异性研究[J]. 中国地质, 49(2): 518-541. doi: 10.12029/gc20220212
引用本文: 秦拯纬, 付建明, 邢光福, 程顺波, 卢友月, 祝颖雪. 2022. 南岭成矿带中—晚侏罗世成钨、成锡、成铅锌(铜)花岗岩的差异性研究[J]. 中国地质, 49(2): 518-541. doi: 10.12029/gc20220212
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QIN Zhengwei, FU Jianming, XING Guangfu, CHENG Shunbo, LU Youyue, ZHU Yingxue. 2022. The petrogenetic differences of the Middle-Late Jurassic W-, Sn-, Pb-Zn-Cu-bearing granites in the Nanling Range, South China[J]. Geology in China, 49(2): 518-541. doi: 10.12029/gc20220212
Citation: QIN Zhengwei, FU Jianming, XING Guangfu, CHENG Shunbo, LU Youyue, ZHU Yingxue. 2022. The petrogenetic differences of the Middle-Late Jurassic W-, Sn-, Pb-Zn-Cu-bearing granites in the Nanling Range, South China[J]. Geology in China, 49(2): 518-541. doi: 10.12029/gc20220212
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南岭成矿带中—晚侏罗世成钨、成锡、成铅锌(铜)花岗岩的差异性研究

  • 1.

    中国地质调查局武汉地质调查中心，湖北 武汉 430205

  • 2.

    中国地质调查局花岗岩成岩成矿地质研究中心，湖北 武汉 430205

  • 3.

    弗莱堡大学，弗莱堡 79104

  • 4.

    中国地质大学，湖北 武汉 430074

  • 基金项目:
    国家自然科学基金项目(41802069)、湖北省自然科学基金项目(2019CFB634)及中国地质调查局项目(DD20221689、DD20190154)联合资助
详细信息
    作者简介: 秦拯纬，男，1987年，博士，高级工程师，从事花岗岩成岩成矿作用研究; E-mail: qzwwto1232006@126.com
    通讯作者: 付建明，男，1964年，博士，研究员，从事岩石地球化学研究; E-mail: ycfjianming@163.com

  • 中图分类号: P618.4;P618.67;P588.12+1

The petrogenetic differences of the Middle-Late Jurassic W-, Sn-, Pb-Zn-Cu-bearing granites in the Nanling Range, South China

  • 1.

    Wuhan Center of Geological Survey, China Geological Survey, Wuhan 430205, Hubei, China

  • 2.

    Research Center of Granitic Diagenesis and Mineralization, China Geological Survey, Wuhan 430205, Hubei, China

  • 3.

    Freiburg University, Freiburg 79104, Germany

  • 4.

    China University of Geosciences, Wuhan 430074, Hubei, China

  • Fund Project: Supported by NSF of China (No. 41802069)、NSF of Hubei Province (No. 2019CFB634)、China Geological Survey (No. DD20221689, No. DD20190154)
More Information
    Author Bio: QIN Zhengwei, male, born in 1987, doctor, senior engineer, engaged in granite petrogenesis and mineralization; E-mail: qzwwto1232006@126.com .
    Corresponding author: FU Jianming, male, born in 1964, doctor, professor, engaged in petrogeochemistry; E-mail: ycfjianming@163.com

    摘要
  • 研究目的

    南岭地区以发育强烈的中—晚侏罗世岩浆作用与相关金属成矿作用为主要特色，这些金属矿床尤以钨、锡、铅锌铜最具代表性。对这3类成矿花岗岩开展系统的对比研究，深入分析成矿差异原因，对指导区域找矿具有重要意义。

     研究方法

    本文通过搜集已发表的主量元素、微量元素、年代学、Sr-Nd-Hf同位素和矿物化学数据，并结合项目组长期野外地质调查进展，对3类成矿花岗岩进行了差异性研究。

     研究结果

    通过对比发现成钨、成锡、成铅锌铜3类花岗岩在时空分布格局、野外地质特征、矿物组成、源区性质、包体成因类型、岩浆分异程度、形成温度和氧逸度等方面具有明显的差异。

     结论

    笔者认为花岗岩的岩石地球化学成分、源区物质组成、岩浆分异程度以及岩浆演化过程中物化条件(如氧逸度)的综合差异是导致南岭花岗岩形成3类不同金属矿床的主要原因。在此基础上，进一步完善了南岭成矿带成钨、成锡、成铅锌铜花岗岩的综合判别标志，指导区域找矿勘查。

    This paper is the result of minerial exploration engineering.

     Objective

    The Nanling Range in southern China is characterized by extensive granitic magmatic activity and significant metal deposits during the Middle-Late Jurassic, with W, Sn and Pb-Zn-Cu as the most representative metallogenic categories. In this regard, a systematic comparison study on the three types of ore-bearing granites and a thorough analysis on the origin of mineralization differences would have great implications for regional prospecting.

     Methods

    In this contribution, the whole rock major and trace element concentrations as well as geochronological, Sr-Nd-Hf isotopical and mineral chemical data of these ore-bearing granites have been collected and reviewed to summarize their petrogenetic differences.

     Results

    In combination with our major progress in the long-term geological survey, we suggest that differences do exist among W-, Sn- and Pb-Zn-Cu-bearing granites in many aspects, including the spatial-temporal distribution of the metallic deposits and related granitic plutons, geological characteristics, mineral compositions, source nature, enclave origin, differentiation degree, formation temperatures and the oxygen fugacity as well.

     Conclusions

    It is concluded that the chemical component of granitic rocks, source materials, magmatic differentiation degree and physical-chemical environment during magma evolution are closely associated with the mineralization types (W, Sn, Pb-Zn-Cu) and control the processes of ore formation. Based on the above, the integrated classification criteria for the W-, Sn- and Pb-Zn-Cu-bearing granites from the Nanling Range has been improved, which would be helpful for ore prospecting in the region.
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  • 图 1  南岭花岗岩及钨锡铅锌铜矿床分布图(据陈骏等，2014)

    Figure 1. 

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    图 2  南岭中—晚侏罗世成锡、成钨、成铅锌(铜)花岗岩侵位年龄直方图

    Figure 2. 

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    图 3  不同类型成矿花岗岩野外特征

    Figure 3. 

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    图 4  成锡成钨成铅锌(铜)花岗岩地球化学分类图解

    Figure 4. 

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    图 5  成钨、成锡、成铅锌(铜)花岗岩的微量(a)和稀土元素(b)标准化图

    Figure 5. 

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    图 6  成锡成钨成铅锌(铜)花岗岩LREE/HREE-SiO2图(a), LREE/HREE-(Zr+Nb+Y+Ce)图(b), (Cr+Ni) -SiO2图(c)及(Cr+Ni) -(Zr+Nb+Y+Ce)图解(d, 图例与数据来源同图 4)

    Figure 6. 

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    图 7  成锡成钨成铅锌(铜)花岗岩FeOT/MgO-(Zr+Nb+Y+Ce)(a, Whalen et al., 1987) 及ACF图解(b, Hine et al., 1978)

    Figure 7. 

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    图 8  成锡(a-b)、成钨(c-d)、成铅锌(铜)花岗岩(e-f)εNd(t)和T2DM (Nd)直方图

    Figure 8. 

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    图 9  成锡(a，b)、成钨(c，d)、成铅锌(铜)花岗岩(e，f)的锆石εHf(t)和T2DM (Hf)直方图

    Figure 9. 

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    图 10  成锡(a)、成钨(b)、成铅锌(铜)花岗岩(c)锆饱和温度直方图

    Figure 10. 

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    图 11  云母Mg-(AlⅥ+Fe3++Ti)-(Fe2++Mn)分类图(a, Foster, 1960), 黑云母的Fe3+-Fe2+-Mg图解(b, HM=Fe2O3-Fe3O4的氧缓冲线, NNO=Ni-NiO的氧缓冲线, FMQ=Fe2SiO4-SiO2-Fe3O4的氧缓冲线, Wones and Eugster, 1965)，侵入岩黑云母的FeOT/(FeOT+MgO)-MgO图解(c, 周作侠, 1986)及黑云母Al2O3-MgO图解(d, 底图修改自Abdel-Rahman, 1994)黑云母数据吴光英(2005)、Wang et al. (2013)、南京大学地质调查项目报告(2013—2015)、张佳茹等(2014)、王辉等(2015)、Li et al. (2017)

    Figure 11. 

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    图 12  成锡、成钨、成铅锌(铜)花岗岩中黑云母Ti-Mg/(Mg+Fe3++Fe2+)温度图解

    Figure 12. 

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    图 13  成锡、成钨、成铅锌(铜)花岗岩CaO/(Na2O+K2O)-Rb/Sr(a)及Nb/Ta-Zr/Hf图解(b)

    Figure 13. 

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    图 14  成锡(a，b)、成钨(c，d)、成铅锌(铜)花岗岩(e，f)的锆石Ce4+/Ce3+与黑云母氧逸度ΔNNO直方图

    Figure 14. 

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    图 15  南岭成锡、成钨、成铅锌(铜)花岗岩的εNd(t)-T演化线

    Figure 15. 

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    图 16  南岭成锡、成钨、成铅锌(铜)花岗岩AMF-CMF(a) 及Rb/Ba-Rb/Sr(b)源区判别图

    Figure 16. 

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    表 1  南岭地区代表性成锡、成钨花岗岩锆饱和温度

    Table 1.  Zircon saturation temperatures of the representative Sn- and W-bearing granites from Nanling

    下载: 导出CSV

    表 2  南岭地区代表性成锡、成钨、成铅锌(铜)花岗岩氧逸度

    Table 2.  Oxygen fugacity of the representative W-, Sn- and Pb-Zn-Cu-bearing granites from Nanling

    下载: 导出CSV

    表 3  南岭地区成锡、成钨、成铅锌(铜)花岗岩综合判别标志

    Table 3.  The integrated classification criteria for the W-, Sn- and Pb-Zn-Cu-bearing granites from Nanling

    下载: 导出CSV
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