Research on Reducing Thiosulfate Consumption During the Process of Leaching Gold and Silver by Ammonia Thiosulfate
-
摘要:
氨性硫代硫酸盐浸出金银过程中硫代硫酸盐消耗量大是阻碍该技术应用于工业生产中的主要因素之一。浸出体系中铜离子和铜氨络离子浓度是影响硫代硫酸盐消耗量的关键因素,通过控制铜离子和铜氨络离子的浓度、加入添加剂或预处理矿石均可达到降低硫代硫酸盐消耗的目的。
Abstract:The large consumption of thiosulfate in the process of leaching gold and silver by ammonia thiosulfate is one of important factors that hinders the application of this technology in industry. In the leaching system, the concentration of copper ions and copper ammine complex ions are the key factors that affect the consumption of thiosulfate. The purpose of reducing thiosulfate consumption can be achieved by regulating the concentration of copper ions and copper ammine ions, adding additives, and pre-treating ore.
-
Key words:
- ammonia /
- thiosulfate /
- leaching /
- gold /
- silver
-
[1] 鲁顺利.非氰化法提金工艺研究现状[J].云南冶金, 2011, 40(3):32-36. doi: 10.3969/j.issn.1006-0308.2011.03.007
[2] 深智慧, 张覃, 卯松, 等.贵州某微细浸染型金矿硫代硫酸盐浸出试验研究[J].矿冶工程, 2013, 33[5]:85-90. doi: 10.3969/j.issn.0253-6099.2013.05.022
[3] 韩彬, 童雄, 谢贤, 等.硫代硫酸盐浸金体系研究进展[J].矿产资源综合利用, 2015(3):11-16. http://d.old.wanfangdata.com.cn/Periodical/kczhly201503003
[4] 赵鹤飞, 杨洪英, 张勤, 等.硫代硫酸盐浸金各因素影响研究现状[J].黄金科学技术, 2018, 26(1):105-114. http://d.old.wanfangdata.com.cn/Periodical/hjkxjs201801015
[5] 宋永辉, 兰新哲.含硫试剂提金研究的几点思考[J].有色金属, 2004, 56(1):67-69. doi: 10.3969/j.issn.1671-1610.2004.01.018
[6] 王丹.基于控制硫代硫酸盐消耗的强化浸金研究[D].长沙: 中南大学, 2013.
http://d.wanfangdata.com.cn/Thesis/y2422390 [7] 童雄, 张艮林, 普传杰.氨性硫代硫酸盐浸金体系中硫代硫酸盐的消耗[J].有色金属工程, 2005, 57(2):69-77. doi: 10.3969/j.issn.2095-1744.2005.02.019
[8] Rivera I, Patio F, Roca A, et al. Kinetics of metallic silver leaching in the O2-thiosulfate system[J]. Hydrometallurgy, 2015, 156:63-70. doi: 10.1016/j.hydromet.2015.05.009
[9] Jeffrey M I, Breuer P L, Chu C K. The importance of controlling oxygen addition during the thiosulfate leaching of gold ores[J]. International Journal of Mineral Processing, 2003(1-4), 72:323-330. doi: 10.1016/S0301-7516(03)00108-X
[10] 蒋培军, 崔毅琦, 谢贤, 等.硫代硫酸盐浸银过程中氧化剂的作用机理分析[J].矿产保护与利用, 2017(5):29-33. http://kcbh.cbpt.cnki.net/WKD/WebPublication/paperDigest.aspx?paperID=96ebd2a8-04ac-4e1a-bc46-1174628e3a31
[11] 姜涛, 黄柱成, 杨永斌, 等.硫代硫酸盐消耗规律与含铜金矿的浸出[J].矿冶工程, 1996, 16(1):46-48.
[12] 沈智慧, 张覃, 卯松, 等.贵州某微细浸染型金矿硫代硫酸盐浸出试验研究[J].矿冶工程, 2013, 33(4):85-90. http://d.old.wanfangdata.com.cn/Periodical/kygc201305022
[13] 周国华, 薛玉兰, 何伯泉, 等.硫代硫酸盐浸金过程中硫代硫酸盐消耗浅探[J].矿产综合利用, 2000(5):15-18. doi: 10.3969/j.issn.1000-6532.2000.05.005
[14] 项朋志, 叶国华.云南某金矿硫代硫酸盐浸金工艺研究[J].广州化工, 2017, 45(5):58-60. doi: 10.3969/j.issn.1001-9677.2017.05.021
[15] 李月娥.用硫代硫酸盐浸出贵金属热力学分析[J].贵金属, 1984, 5(3):10-19. http://www.cnki.com.cn/Article/CJFDTotal-GJSZ198403002.htm
[16] Valentin Ibarra-Galvan, Alejandro Lo'pez-Valdivieso, Xiong Tong, et al. Role of oxygen and ammonium ions in silver leaching withthiosulfate-ammonia-cupric ions[J]. Raremetals, 2014, 33(2):225-229.
[17] 曹昌林, 胡洁雪, 龚乾.低浓度硫代硫酸盐浸金[J].中国有色金属学报, 1992, 2(4):33-36. doi: 10.3321/j.issn:1004-0609.1992.04.007
[18] 何建, 崔毅琦, 蒋培军, 等.硫代硫酸盐浸金及回收过程中氨的作用研究现状[J].矿冶, 2018, 27(1):57-60. doi: 10.3969/j.issn.1005-7854.2018.01.014
[19] M.I.Jeffreyt. Kinetic aspects of gold and silver leaching in ammonia-thiosulfate solutions[J]. Hydrometallurgy, 2001, 60(1):7-16. doi: 10.1016/S0304-386X(00)00151-1
[20] Schippers A, Jorgensen B. Oxidation of pyrite and iron sulfide by manganese dioxide in marine sediments[J]. Geoehimica Et Cosmochimica Acta, 2001, 65:915-922. doi: 10.1016/S0016-7037(00)00589-5
[21] 字富庭, 何素琼, 胡显智, 等.硫代硫酸盐浸金中硫代硫酸盐稳定性状况研究[J].矿冶, 2012, 21(3):33-38. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=ky201203010
[22] 胡洁雪, 龚乾.硫代硫酸盐提金过程中硫酸盐代替亚硫酸盐的探讨[J].化工冶金, 1991, 4:301-305. doi: 10.3321/j.issn:1009-606X.1991.04.004
[23] Feng D, VanDeventer J S J. Effect of sulfides on gold dissolution in ammoniacal thiosulfate medium[J]. Metallurgical and Materials Transactions B, 2003, 34:5-13. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=dc1cc9fb22e3b4647abb472ff988c732
[24] Xia C, Yen W T, Deschenes G.Improvement of thiosulfate stability in gold leaching[J]. Minerals&metallurgical processing, 2003, 20:68-72. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=38860c03189845b2d51f9ddf493a290b
[25] Feng D, VanDeventer J S J. Thiosulphate leaching of gold in the presence of ethylenediaminetetraacetic acid(EDTA)[J]. Minerals Engineering, 2010, 23:143-150. doi: 10.1016/j.mineng.2009.11.009
[26] M Aazami, G T Lapidus, Amir Azadeh. The effect of solution parameters on the thiosulfate leaching ofzarshouran refractory gold ore[J]. Mineral processing, 2014, 131:43-50. doi: 10.1016/j.minpro.2014.08.001
[27] Feng D, Van Deventer J S J. Thiosulphate leaching of gold in the presence of carboxymethyl cellulose (CMC)[J]. Minerals Engineering, 2011, 24:115-121. doi: 10.1016/j.mineng.2010.10.007
[28] Yong-bin YANG, Xi ZHANG, Bin XU, et al. Effect of arsenopyrite on thiosulfate leaching of gold[J]. Transactions of nonferrous metals society of China, 2015, 25:3454-3460. doi: 10.1016/S1003-6326(15)63982-6
[29] 李汝雄, 王建基, 邝生鲁.用金的阳极溶解方法研究氯化钠在硫代硫酸盐浸金过程中的作用[J].黄金, 2001, 22(2):28-30. doi: 10.3969/j.issn.1001-1277.2001.02.009
[30] Feng D, VanDeventer J S J. Thiosulphate leaching of gold in the presence of orthophosphate and polyphosphate[J]. Hydrometallurgy, 2011, 106:38-45. doi: 10.1016/j.hydromet.2010.11.016
[31] Bin Xu, Yongbin Yang, Tao Jiang, et al. Improved thiosulfate leaching of a refractory gold concentrate calcinewith additives[J]. Hydrometallurgy, 2015, 152:214-222. doi: 10.1016/j.hydromet.2014.12.016
[32] Feng D, Van Deventer J S J. The role of amino acids in the thiosulphate leaching of gold[J]. Minerals engineering, 2011, 24:1022-1024. doi: 10.1016/j.mineng.2011.04.017
[33] 李峰, 丁德鑫, 胡南, 等.难处理含金硫精矿的焙烧氧化-硫代硫酸盐浸出[J].中国有色金属学报, 2014, 24(3):831-837. http://d.old.wanfangdata.com.cn/Periodical/zgysjsxb201403035
[34] 姜涛, 许时, 陈荩, 等.含铜金矿自催化硫代硫酸盐浸金新工艺及化学原理[J].有色金属, 1992, 44(3):30-33. doi: 10.3321/j.issn:1004-0609.1992.03.006
[35] 邓文, 伍荣霞, 刘志成, 等.焙烧预氧化-硫代硫酸盐浸出某难处理金精矿[J].矿冶工程, 2017, 37(3):114-117. doi: 10.3969/j.issn.0253-6099.2017.03.030
[36] 陈立乐, 王景伟, 白建峰, 等.硫代硫酸盐法浸出废旧IC芯片中金的试验研究[J].化工进展, 2015, 34(3):884-890. http://d.old.wanfangdata.com.cn/Periodical/hgjz2015030052
计量
- 文章访问数: 1466
- PDF下载数: 55
- 施引文献: 0