铜氨/胺体系下硫代硫酸盐浸金的电化学研究进展

蔡鑫, 崔毅琦, 何建, 贺俊傲, 童雄. 铜氨/胺体系下硫代硫酸盐浸金的电化学研究进展[J]. 矿产保护与利用, 2019, 39(5): 156-159, 166. doi: 10.13779/j.cnki.issn1001-0076.2019.04.045
引用本文: 蔡鑫, 崔毅琦, 何建, 贺俊傲, 童雄. 铜氨/胺体系下硫代硫酸盐浸金的电化学研究进展[J]. 矿产保护与利用, 2019, 39(5): 156-159, 166. doi: 10.13779/j.cnki.issn1001-0076.2019.04.045
CAI Xin, CUI Yiqi, HE Jian, HE Junao, TONG Xiong. Research Progress in Electrochemistry of Thiosulfate Gold Leaching in Copper Ammonia/Amine Systems[J]. Conservation and Utilization of Mineral Resources, 2019, 39(5): 156-159, 166. doi: 10.13779/j.cnki.issn1001-0076.2019.04.045
Citation: CAI Xin, CUI Yiqi, HE Jian, HE Junao, TONG Xiong. Research Progress in Electrochemistry of Thiosulfate Gold Leaching in Copper Ammonia/Amine Systems[J]. Conservation and Utilization of Mineral Resources, 2019, 39(5): 156-159, 166. doi: 10.13779/j.cnki.issn1001-0076.2019.04.045

铜氨/胺体系下硫代硫酸盐浸金的电化学研究进展

  • 基金项目:
    国家自然科学基金项目(51664028,51104077)
详细信息
    作者简介: 蔡鑫, 硕士研究生, 主要从事稀贵金属选冶研究
    通讯作者: 崔毅琦, 女, 博士, 副教授, 主要从事稀贵金属选冶研究
  • 中图分类号: TD953+.1

Research Progress in Electrochemistry of Thiosulfate Gold Leaching in Copper Ammonia/Amine Systems

More Information
    Corresponding author: CUI Yiqi
  • 硫代硫酸盐法浸金是一种具有应用前景的无氰浸出方法,与传统氰化法相比,具有浸出用时短、浸出速率快、低毒环保等优点。基于硫代硫酸盐浸金体系的复杂性,从电化学角度论述了铜氨/胺体系下硫代硫酸盐浸金的电化学行为及浸金过程中硫代硫酸盐、铜/铜氨络合离子、氨/胺之间的作用方式。

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  • [1]

    Muir D M, Aylmore D G. Thiosulphate as an alternative to cyanide for gold processing-issues and impediments[J]. Mineral processing and extractive metallurgy, 2004, 113(1):2-12. doi: 10.1179/037195504225004661

    [2]

    Thomas K G, Fleming C, Marchbank A R, et al. Gold recovery from refractory carbonaceous ores by pressure oxidation, thiosulphate leaching and resin-in-pulp adsorption: US 5785736[P]. 1998-07-28.

    [3]

    孟奇, 崔毅琦, 童雄, 等.从硫代硫酸盐浸金溶液中回收金的研究现状[J].矿冶, 2013(4):51-54. doi: 10.3969/j.issn.1007-967X.2013.04.017

    [4]

    Breuer P L, Jeffrey M I. An electrochemical study of gold leaching in thiosulfate solutions containing copper and ammonia[J]. Hydrometallurgy, 2002, 65(2):145-157. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=75ac3cd2fda64f13c1073ac21ad666ba

    [5]

    白成庆.硫代硫酸盐溶金机理研究[D].昆明: 昆明理工大学, 2008: 65-68.http://cdmd.cnki.com.cn/Article/CDMD-10674-2008112505.htm

    [6]

    Zhang S, Nicol M J. An electrochemical study of the dissolution of gold in thiosulfate solutions Part Ⅰ:alkaline solutions[J]. Journal of applied electrochemistry, 2003, 33(9):767-775. doi: 10.1023/A:1025502303122

    [7]

    Zelinsky A G, Novgorodtseva O N. EQCM study of the dissolution of gold in thiosulfate solutions[J]. Hydrometallurgy, 2013, 138(6):79-83. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=3923e87da53fdda78a800aa6586326de

    [8]

    Jeffrey M I, Watling K, Hope G A, et al. Identification of surface species that inhibit and passivate thiosulfate leaching of gold[J]. Minerals engineering, 2008, 21(6):443-452. doi: 10.1016/j.mineng.2008.01.006

    [9]

    Wood R, Hope G A, Watling K M, et al. A spectrochemical study of surface species formed in the gold/thiosulfate system[J]. Journal of the electrochemical society, 2006, 153(7):D105. doi: 10.1149/1.2195889

    [10]

    刘克俊, 李剑虹, 李长根, 等.用硫代硫酸盐溶液浸出和回收金[J].国外金属矿选矿, 2005(3):10-15. http://d.old.wanfangdata.com.cn/Periodical/gwjskxk200503002

    [11]

    Gamini Senanayake. Role of copper(Ⅱ), carbonate and sulphite in gold leaching and thiosulphate degradation by oxygenated alkaline non-ammoniacal solutions[J]. Minerals engnieering, 2005(18):409-426. http://www.sciencedirect.com/science/article/pii/S0892687504001748

    [12]

    聂彦合.多硫酸盐对硫代硫酸盐浸金过程的影响及调控研究[D].昆明: 昆明理工大学, 2017。http://cdmd.cnki.com.cn/Article/CDMD-10674-1017220393.htm

    [13]

    项朋志, 刘琼, 黄遥, 等.硫代硫酸盐浸金体系中铜氨影响研究[J].化学与生物工程, 2017(12):14-16. doi: 10.3969/j.issn.1672-5425.2017.12.004

    [14]

    Gamini Senanayake. Analysis of reaction kinetics speciation and mechanism of gold leaching and thiosulfate oxidation by ammoniacal copper(Ⅱ) solutions[J]. Hydrometallurgy, 2004, 75:55-75. doi: 10.1016/j.hydromet.2004.06.004

    [15]

    字富庭, 何素琼, 胡显智, 等.硫代硫酸盐浸金中硫代硫酸盐稳定性研究状况[J].矿冶, 2012, (3):33-38. http://d.old.wanfangdata.com.cn/Periodical/ky201203010

    [16]

    P L Breuer, M I Jeffrey. Copper catalysed oxidation of thiosulfate by oxygenin gold leach solutions[J]. Minerals engineering, 2003(16):21-30.

    [17]

    蒋培军, 崔毅琦, 谢贤, 等.硫代硫酸盐浸银过程中氧化剂的作用机理分析[J].矿产保护与利用, 2017(5):29-33. http://kcbh.cbpt.cnki.net/WKD/WebPublication/paperDigest.aspx?paperID=96ebd2a8-04ac-4e1a-bc46-1174628e3a31

    [18]

    姜涛, 许时, 陈荩.硫代硫酸盐浸金电化学研究(Ⅱ)金的阴极溶解行为及机理[J].中南矿冶学院学报, 1993(2):169-173. http://www.cnki.com.cn/Article/CJFDTotal-ZNGD199302006.htm

    [19]

    龚亚军.方铅矿碳酸化转化的电化学-动力学[D].北京: 中国科学院化工冶金研究, 1988.

    [20]

    魏宝明.金属腐蚀理论及应用[M].北京:化学工业出版社.1984.

    [21]

    Zhang S, Nicol M J. An electrochemical study of the dissolution of gold in thiosulfate solutions. Part Ⅱ:effect of copper[J]. Journal of applied electrochemistry, 2005(3):339-345. http://link.springer.com/article/10.1007/s10800-004-7469-9

    [22]

    张卿.某含砷难处理金矿超声强化浸金试验研究[J].矿产综合利用, 2010(4):12-15. doi: 10.3969/j.issn.1000-6532.2010.04.003

    [23]

    陈荩, 姜涛, 许时.硫代硫酸盐浸金电化学研究(Ⅰ)金的阳极溶解行为及机理[J].中南矿冶学院学报, 1993(2):169-173.

    [24]

    Zhu Guocai. Electrochemical studies on the mechanism of gold dissolution in thiosulfate solutions[J]. Transactions of nonferrous metals society of China, 1994(1):50-53. http://www.cqvip.com/QK/85276X/199401/3001303173.html

    [25]

    许姣, 胡显智, 杨朋, 等.氨性硫代硫酸盐体系中金溶解过程的腐蚀电化学行为[J].昆明理工大学学报(自然科学版), 2015(2):123-129. http://d.old.wanfangdata.com.cn/Periodical/kmlgdxxb201502018

    [26]

    沈智慧, 张覃, 唐云.用硫代硫酸盐浸出和回收金的研究进展[C]中国有色金属学会: 2013有色金属矿山环保高层论坛, 2013.

    [27]

    Baron J Y, Mirza J, Nicol E A, et al. SERS and electrochemical studies of the gold-electrolyte interface under thiosulfate based leaching conditions[J]. Electrochimica acta, 2013, 111(6):390-399. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=4198b27f79b154c69900583a71ca9023

    [28]

    Jeffrey M I. Kinetic aspects of gold and silver leaching in ammonia-thiosulfate solutions[J]. Hydrome tallurgy, 2001, 60(1):7-16. doi: 10.1016/S0304-386X(00)00151-1

    [29]

    胡显智.一种以乙二胺为添加剂的硫代硫酸盐提取金的方法: CN101824545.3[P]. 2010-09-08.

    [30]

    字富庭.铜(Ⅱ)胺(氨)配离子在硫代硫酸盐浸金中构效关系研究[D].昆明: 昆明理工大学, 2012.

    [31]

    项朋志, 刘琼, 叶国华.铜-乙二胺-硫代硫酸盐浸金体系中硫代硫酸盐消耗研究[J].黄金, 2018, 39(3):59-62. http://d.old.wanfangdata.com.cn/Periodical/huangj201803013

    [32]

    项朋志, 刘琼, 黄遥, 等.基于硫代硫酸盐铜乙二胺浸金体系铜及乙二胺影响电化学研究[J].现代矿业, 2018(1):151-154. doi: 10.3969/j.issn.1674-6082.2018.01.028

    [33]

    高鹏, 唐道文, 唐攒浪.用硫代硫酸钠从某卡林型金矿石中浸出金试验研究[J].湿法冶金, 2017(1):12-15. http://d.old.wanfangdata.com.cn/Periodical/sfyj201701003

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出版历程
收稿日期:  2018-12-25
刊出日期:  2019-10-25

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