石墨的矿物学属性、功能化与石墨新材料的应用

孙红娟, 侯波, 彭同江. 石墨的矿物学属性、功能化与石墨新材料的应用[J]. 矿产保护与利用, 2019, 39(6): 8-13. doi: 10.13779/j.cnki.issn1001-0076.2019.06.002
引用本文: 孙红娟, 侯波, 彭同江. 石墨的矿物学属性、功能化与石墨新材料的应用[J]. 矿产保护与利用, 2019, 39(6): 8-13. doi: 10.13779/j.cnki.issn1001-0076.2019.06.002
SUN Hongjuan, Hou Bo, PENG Tongjiang. Mineralogical Properties, Functionalization of Graphite and Development Demand of New Material Industry[J]. Conservation and Utilization of Mineral Resources, 2019, 39(6): 8-13. doi: 10.13779/j.cnki.issn1001-0076.2019.06.002
Citation: SUN Hongjuan, Hou Bo, PENG Tongjiang. Mineralogical Properties, Functionalization of Graphite and Development Demand of New Material Industry[J]. Conservation and Utilization of Mineral Resources, 2019, 39(6): 8-13. doi: 10.13779/j.cnki.issn1001-0076.2019.06.002

石墨的矿物学属性、功能化与石墨新材料的应用

  • 基金项目:
    国家自然科学基金(41772036)
详细信息
    作者简介: 孙红娟, 教授, 博导, 研究领域:矿物学与矿物材料, E-mail:sunhongjuan@swust.edu.cn
  • 中图分类号: TD975+.2;TB321

Mineralogical Properties, Functionalization of Graphite and Development Demand of New Material Industry

  • 基于石墨的成分、结构和化学键特性,阐述了石墨独特的理化性能、功能化加工技术及新型石墨功能化产物和应用。重点讨论了膨胀石墨、石墨纳米片和石墨烯的制备工艺技术的研究进展,以及石墨功能化产物在密封材料、吸附材料、储能材料、气体传感器及功能涂料等方面的应用研究现状。针对目前石墨功能材料产业发展现状,亟需制定石墨新型功能材料的相应评价标准,提升高端石墨材料的应用技术,对石墨战略非金属矿产资源的发展具有重要意义。

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  • 图 1  石墨晶体结构(左2H型,右3R型)

    Figure 1. 

    图 2  膨胀石墨SEM图

    Figure 2. 

    图 3  氧化石墨烯结构

    Figure 3. 

  • [1]

    孙红娟, 彭同江.石墨氧化-还原法制备石墨烯材料[M].北京:科学出版社.2015.

    [2]

    潘兆橹, 万朴.应用矿物学[M].武汉:武汉工业大学出版社.1993.

    [3]

    Guojiang Z, Xiaotong F, Guangchao L. Preparation of sulfur-free exfoliated graphite in the graphite HClO4-CH3COOH systems[J]. Adv Materials research, 2015, 1094:61-67. doi: 10.4028/www.scientific.net/AMR.1094.61

    [4]

    Jihui-Li, Huifang-Da, Qian-Liu, et al. Preparation of sulfur-free expanded graphite with 320μm mesh of flake graphite[J]. Materials Letters, 2006, 60(29-30):3927-3930. doi: 10.1016/j.matlet.2006.06.066

    [5]

    鲜海洋, 彭同江, 孙红娟.氧化程度对微细鳞片可膨胀石墨结构及膨胀性的影响[J].无机化学学报, 2014, 30(11):2537-2543. http://d.old.wanfangdata.com.cn/Periodical/wjhxxb201411012

    [6]

    Jihui-Li H-D, Qian-Liu S-L. Preparation of sulfur-free expanded graphite with 320μm mesh of flake graphite[J]. Materials Letters, 2006, 60(29-30):3927-3930. doi: 10.1016/j.matlet.2006.06.066

    [7]

    Zhang F, Zhao Q, Yan X, et al. Rapid preparation of expanded graphite by microwave irradiation for the extraction of triazine herbicides in milk samples[J]. Food Chemistry, 2016, 197:943-949. doi: 10.1016/j.foodchem.2015.11.056

    [8]

    罗立群, 刘斌, 王召, 等.低温可膨胀石墨的制备及插层过程特性[J].化工进展, 2017, 36(10):3778-3785. http://d.old.wanfangdata.com.cn/Periodical/hgjz201710034

    [9]

    杨永清, 王佳德, 陈二龙.可膨胀石墨电化学法制备及其研究[J].纤维复合材料, 1998(2):22-23, 48. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=QK199800464965

    [10]

    陈庚.新型电化学氧化法制备可膨胀石墨[J].炭素技术, 2019, 38(2):12-15. http://d.old.wanfangdata.com.cn/Periodical/tsjs201902003

    [11]

    杨晓燕, 关明, 夏云生, 等.电化学法制膨胀石墨的改进[J].精细化工, 2000, 17(1):72-74. http://d.old.wanfangdata.com.cn/Periodical/jxhg2000Z1025

    [12]

    薛美玲, 于永良, 任志华, 等.电化学法制造膨胀石墨的再改进[J].精细化工, 2002, 19(10):567-570. doi: 10.3321/j.issn:1003-5214.2002.10.004

    [13]

    Liu T, Zhang R, Zhang X, et al. One-step room-temperature preparation of expanded graphite[J]. Carbon, 2017, 119:544-547. doi: 10.1016/j.carbon.2017.04.076

    [14]

    肖勇, 马卫东, 孙志勇, 等.石墨烯制备与应用研究进展[J].功能材料与器件学报, 2017(5):125-131. http://d.old.wanfangdata.com.cn/Periodical/fhclxb201402002

    [15]

    KS N, AK G, SV M, et al. Electric field effect in atomically thin carbon films[J]. Science (New York, NY), 2004, 306(5696):666. doi: 10.1126/science.1102896

    [16]

    熊晓桐, 黄蓓青, 魏先福, 等.石墨烯的制备方法[J].包装工程, 2017, 38(13):20-24.

    [17]

    迟彩霞, 乔秀丽, 赵东江, 等.氧化-还原法制备石墨烯[J].化学世界, 2016, 57(4):251-256. http://d.old.wanfangdata.com.cn/Periodical/wjhxxb201212004

    [18]

    杨勇辉, 孙红娟, 彭同江.石墨烯的氧化还原法制备及结构表征[J].无机化学学报, 2010, 26(11):2083-2090. http://d.old.wanfangdata.com.cn/Periodical/wjhxxb201011027

    [19]

    Tang M, Fei Q, Man C, et al. Synergistic effects of ammonium polyphosphate and red phosphorus with expandable graphite on flammability and thermal properties of HDPE/EVA blends[J]. Polymers for Advanced Technologies, 2016, 27(1):52-60. doi: 10.1002/pat.3596

    [20]

    Yang X, Man C, Xin N, et al. Influences of coupling agent on thermal properties, flammability and mechanical properties of polypropylene/thermoplastic polyurethanes composites filled with expanded graphite[J]. Journal of Thermal Analysis & Calorimetry, 2014, 115(1):689-695. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=d5e89bb5741959d23c0eb1d9dab5654e

    [21]

    Huang J, Tang Q, Liao W, et al. Green preparation of expandable graphite and its application in flame-resistance polymer elastomer[J]. Industrial & Engineering Chemistry Research, 2017, 56(18):5253-5261. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=33ced8c9ddcd3cf4ee6eabaf806fa5be

    [22]

    Vahabi H, Saeb M R, Formela K, et al. Flame retardant epoxy/halloysite nanotubes nanocomposite coatings:Exploring low-concentration threshold for flammability compared to expandable graphite as superior fire retardant[J]. Progress in Organic Coatings, 2018, 119:8-14. doi: 10.1016/j.porgcoat.2018.02.005

    [23]

    邵志恒, 庄勋港, 许一婷, 等.改性环氧树脂超薄膨胀型防火涂料[J].消防科学与技术, 2017, 36(11):1574-1577. doi: 10.3969/j.issn.1009-0029.2017.11.029

    [24]

    刘波, 孙红娟, 彭同江, 等.膨胀微晶石墨的制备及对Pb~(2+)的吸附行为[J].矿产保护与利用, 2018, 217(5):73-78, 84. http://www.cnki.com.cn/Article/CJFDTotal-KCBH201805013.htm

    [25]

    Li S, Tian S, Feng Y, et al. A comparative investigation on absorption performances of three expanded graphite-based complex materials for toluene[J]. Journal of Hazardous Materials, 2010, 183(1):506-511.

    [26]

    Wu Y, Liu X, Xia D, et al. Synthesis of few-layer N-doped graphene from expandable graphite with melamine and its application in supercapacitors[J]. Chinese Chemical Letters, 2019. DOI:10.1016/j.cclet.2019.04.055.

    [27]

    陈莹莹, 宓一鸣, 阮勤超, 等.石墨烯的制备及应用的研究进展[J].硅酸盐通报, 2015, 34(3):755-763. http://d.old.wanfangdata.com.cn/Periodical/gsytb201503030

    [28]

    王旭红, 惠洋, 顾渊铠, 等.石墨烯改性碳纤维基Pt-Sn直接燃料乙醇电池阳极催化剂[J].硅酸盐学报, 2017, 45(4):483-489. http://d.old.wanfangdata.com.cn/Periodical/gsyxb201704004

    [29]

    Xiong B, Zhou Y, O'Hayre R, et al. Facile single-step ammonia heat-treatment and quenching process for the synthesis of improved Pt/N-graphene catalysts[J]. Applied Surface Science, 2013, 266(2):433-439. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=839fe9fbbd54740e854b61287fbb1af9

    [30]

    Ray S. Applications of graphene and graphene-oxide based nanomaterials[J]. Mrs Bulletin, 2016, 41(2):165. http://d.old.wanfangdata.com.cn/Conference/8706236

    [31]

    李津, 刘晓来, 赵东林.二氧化锰改性石墨烯电极材料的电化学性能[J].电池工业, 2011, 16(3):164-167. doi: 10.3969/j.issn.1008-7923.2011.03.010

    [32]

    Xue H, Yu D Y W, Qing J, et al. Pyrite FeS2 Microspheres wrapped by reduced graphene oxide as high-performance lithium-ion battery anodes[J]. Journal of Materials Chemistry A, 2015, 3(15):7945-7949. doi: 10.1039/C5TA00988J

    [33]

    汪建德, 彭同江, 鲜海洋, 等.三维还原氧化石墨烯/聚苯胺复合材料的制备及其超级电容性能[J].物理化学学报, 2015, 31(1):90-98. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=wlhxxb201501015

    [34]

    汪建德, 彭同江, 孙红娟, 等.水热反应温度对三维还原氧化石墨烯的形貌、结构和超级电容性能的影响[J].物理化学学报, 2014, 30(11):2077-2084. doi: 10.3866/PKU.WHXB201409152

    [35]

    范军领.石墨烯传感器的研究进展[J].材料导报, 2012, 26(7):31-35. doi: 10.3969/j.issn.1005-023X.2012.07.007

    [36]

    Hao Wan Y G, Jiadi Sun, Tao Liang, et al. High sensitive reduced graphene oxide-based room temperature ionic liquid electrochemical gas sensor with carbon-gold nanocomposites amplification[J]. Sensors and Actuators B:Chemical, 2019, 299:126952. doi: 10.1016/j.snb.2019.126952

    [37]

    何文龙, 王立, 戴艺强, 等.基于石墨烯的水性导电涂料的制备及其电磁屏蔽性能的研究[J].中国涂料, 2017, 32:2. http://d.old.wanfangdata.com.cn/Periodical/zhonggtl201702004

    [38]

    薛鹏, 倪维良, 胡秀东, 等.原位改性石墨烯在防腐涂料中的应用[J].涂料工业, 2017, 47(3):72-75. http://d.old.wanfangdata.com.cn/Periodical/tlgy201703013

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出版历程
收稿日期:  2019-11-22
刊出日期:  2019-12-25

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