Mineralogical Properties, Functionalization of Graphite and Development Demand of New Material Industry
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摘要:
基于石墨的成分、结构和化学键特性,阐述了石墨独特的理化性能、功能化加工技术及新型石墨功能化产物和应用。重点讨论了膨胀石墨、石墨纳米片和石墨烯的制备工艺技术的研究进展,以及石墨功能化产物在密封材料、吸附材料、储能材料、气体传感器及功能涂料等方面的应用研究现状。针对目前石墨功能材料产业发展现状,亟需制定石墨新型功能材料的相应评价标准,提升高端石墨材料的应用技术,对石墨战略非金属矿产资源的发展具有重要意义。
Abstract:According to the composition, structure and chemical bond characteristic of graphite, the unique physical and chemical properties, functional processing technology, new functional products and applications of graphite were described. In this paper, the research progress of the preparation technology of expanded graphite, graphite nano-flakes and graphene, and the application of graphite functionalized products in sealing materials, adsorption materials, batteries and energy storage materials, gas sensors and functional coatings were discussed. In view of the current situation of the development of graphite functional materials industry, it is urgent to formulate the corresponding evaluation standards of new graphite functional materials and improve the application technology of high-end graphite materials, which is of great significance to the development of graphite strategic non-metallic mineral resources.
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Key words:
- graphite /
- functional properties /
- new materials /
- development needs
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[1] 孙红娟, 彭同江.石墨氧化-还原法制备石墨烯材料[M].北京:科学出版社.2015.
[2] 潘兆橹, 万朴.应用矿物学[M].武汉:武汉工业大学出版社.1993.
[3] Guojiang Z, Xiaotong F, Guangchao L. Preparation of sulfur-free exfoliated graphite in the graphite HClO4-CH3COOH systems[J]. Adv Materials research, 2015, 1094:61-67. doi: 10.4028/www.scientific.net/AMR.1094.61
[4] Jihui-Li, Huifang-Da, Qian-Liu, et al. Preparation of sulfur-free expanded graphite with 320μm mesh of flake graphite[J]. Materials Letters, 2006, 60(29-30):3927-3930. doi: 10.1016/j.matlet.2006.06.066
[5] 鲜海洋, 彭同江, 孙红娟.氧化程度对微细鳞片可膨胀石墨结构及膨胀性的影响[J].无机化学学报, 2014, 30(11):2537-2543. http://d.old.wanfangdata.com.cn/Periodical/wjhxxb201411012
[6] Jihui-Li H-D, Qian-Liu S-L. Preparation of sulfur-free expanded graphite with 320μm mesh of flake graphite[J]. Materials Letters, 2006, 60(29-30):3927-3930. doi: 10.1016/j.matlet.2006.06.066
[7] Zhang F, Zhao Q, Yan X, et al. Rapid preparation of expanded graphite by microwave irradiation for the extraction of triazine herbicides in milk samples[J]. Food Chemistry, 2016, 197:943-949. doi: 10.1016/j.foodchem.2015.11.056
[8] 罗立群, 刘斌, 王召, 等.低温可膨胀石墨的制备及插层过程特性[J].化工进展, 2017, 36(10):3778-3785. http://d.old.wanfangdata.com.cn/Periodical/hgjz201710034
[9] 杨永清, 王佳德, 陈二龙.可膨胀石墨电化学法制备及其研究[J].纤维复合材料, 1998(2):22-23, 48. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=QK199800464965
[10] 陈庚.新型电化学氧化法制备可膨胀石墨[J].炭素技术, 2019, 38(2):12-15. http://d.old.wanfangdata.com.cn/Periodical/tsjs201902003
[11] 杨晓燕, 关明, 夏云生, 等.电化学法制膨胀石墨的改进[J].精细化工, 2000, 17(1):72-74. http://d.old.wanfangdata.com.cn/Periodical/jxhg2000Z1025
[12] 薛美玲, 于永良, 任志华, 等.电化学法制造膨胀石墨的再改进[J].精细化工, 2002, 19(10):567-570. doi: 10.3321/j.issn:1003-5214.2002.10.004
[13] Liu T, Zhang R, Zhang X, et al. One-step room-temperature preparation of expanded graphite[J]. Carbon, 2017, 119:544-547. doi: 10.1016/j.carbon.2017.04.076
[14] 肖勇, 马卫东, 孙志勇, 等.石墨烯制备与应用研究进展[J].功能材料与器件学报, 2017(5):125-131. http://d.old.wanfangdata.com.cn/Periodical/fhclxb201402002
[15] KS N, AK G, SV M, et al. Electric field effect in atomically thin carbon films[J]. Science (New York, NY), 2004, 306(5696):666. doi: 10.1126/science.1102896
[16] 熊晓桐, 黄蓓青, 魏先福, 等.石墨烯的制备方法[J].包装工程, 2017, 38(13):20-24.
[17] 迟彩霞, 乔秀丽, 赵东江, 等.氧化-还原法制备石墨烯[J].化学世界, 2016, 57(4):251-256. http://d.old.wanfangdata.com.cn/Periodical/wjhxxb201212004
[18] 杨勇辉, 孙红娟, 彭同江.石墨烯的氧化还原法制备及结构表征[J].无机化学学报, 2010, 26(11):2083-2090. http://d.old.wanfangdata.com.cn/Periodical/wjhxxb201011027
[19] Tang M, Fei Q, Man C, et al. Synergistic effects of ammonium polyphosphate and red phosphorus with expandable graphite on flammability and thermal properties of HDPE/EVA blends[J]. Polymers for Advanced Technologies, 2016, 27(1):52-60. doi: 10.1002/pat.3596
[20] Yang X, Man C, Xin N, et al. Influences of coupling agent on thermal properties, flammability and mechanical properties of polypropylene/thermoplastic polyurethanes composites filled with expanded graphite[J]. Journal of Thermal Analysis & Calorimetry, 2014, 115(1):689-695. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=d5e89bb5741959d23c0eb1d9dab5654e
[21] Huang J, Tang Q, Liao W, et al. Green preparation of expandable graphite and its application in flame-resistance polymer elastomer[J]. Industrial & Engineering Chemistry Research, 2017, 56(18):5253-5261. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=33ced8c9ddcd3cf4ee6eabaf806fa5be
[22] Vahabi H, Saeb M R, Formela K, et al. Flame retardant epoxy/halloysite nanotubes nanocomposite coatings:Exploring low-concentration threshold for flammability compared to expandable graphite as superior fire retardant[J]. Progress in Organic Coatings, 2018, 119:8-14. doi: 10.1016/j.porgcoat.2018.02.005
[23] 邵志恒, 庄勋港, 许一婷, 等.改性环氧树脂超薄膨胀型防火涂料[J].消防科学与技术, 2017, 36(11):1574-1577. doi: 10.3969/j.issn.1009-0029.2017.11.029
[24] 刘波, 孙红娟, 彭同江, 等.膨胀微晶石墨的制备及对Pb~(2+)的吸附行为[J].矿产保护与利用, 2018, 217(5):73-78, 84. http://www.cnki.com.cn/Article/CJFDTotal-KCBH201805013.htm
[25] Li S, Tian S, Feng Y, et al. A comparative investigation on absorption performances of three expanded graphite-based complex materials for toluene[J]. Journal of Hazardous Materials, 2010, 183(1):506-511.
[26] Wu Y, Liu X, Xia D, et al. Synthesis of few-layer N-doped graphene from expandable graphite with melamine and its application in supercapacitors[J]. Chinese Chemical Letters, 2019. DOI:10.1016/j.cclet.2019.04.055.
[27] 陈莹莹, 宓一鸣, 阮勤超, 等.石墨烯的制备及应用的研究进展[J].硅酸盐通报, 2015, 34(3):755-763. http://d.old.wanfangdata.com.cn/Periodical/gsytb201503030
[28] 王旭红, 惠洋, 顾渊铠, 等.石墨烯改性碳纤维基Pt-Sn直接燃料乙醇电池阳极催化剂[J].硅酸盐学报, 2017, 45(4):483-489. http://d.old.wanfangdata.com.cn/Periodical/gsyxb201704004
[29] Xiong B, Zhou Y, O'Hayre R, et al. Facile single-step ammonia heat-treatment and quenching process for the synthesis of improved Pt/N-graphene catalysts[J]. Applied Surface Science, 2013, 266(2):433-439. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=839fe9fbbd54740e854b61287fbb1af9
[30] Ray S. Applications of graphene and graphene-oxide based nanomaterials[J]. Mrs Bulletin, 2016, 41(2):165. http://d.old.wanfangdata.com.cn/Conference/8706236
[31] 李津, 刘晓来, 赵东林.二氧化锰改性石墨烯电极材料的电化学性能[J].电池工业, 2011, 16(3):164-167. doi: 10.3969/j.issn.1008-7923.2011.03.010
[32] Xue H, Yu D Y W, Qing J, et al. Pyrite FeS2 Microspheres wrapped by reduced graphene oxide as high-performance lithium-ion battery anodes[J]. Journal of Materials Chemistry A, 2015, 3(15):7945-7949. doi: 10.1039/C5TA00988J
[33] 汪建德, 彭同江, 鲜海洋, 等.三维还原氧化石墨烯/聚苯胺复合材料的制备及其超级电容性能[J].物理化学学报, 2015, 31(1):90-98. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=wlhxxb201501015
[34] 汪建德, 彭同江, 孙红娟, 等.水热反应温度对三维还原氧化石墨烯的形貌、结构和超级电容性能的影响[J].物理化学学报, 2014, 30(11):2077-2084. doi: 10.3866/PKU.WHXB201409152
[35] 范军领.石墨烯传感器的研究进展[J].材料导报, 2012, 26(7):31-35. doi: 10.3969/j.issn.1005-023X.2012.07.007
[36] Hao Wan Y G, Jiadi Sun, Tao Liang, et al. High sensitive reduced graphene oxide-based room temperature ionic liquid electrochemical gas sensor with carbon-gold nanocomposites amplification[J]. Sensors and Actuators B:Chemical, 2019, 299:126952. doi: 10.1016/j.snb.2019.126952
[37] 何文龙, 王立, 戴艺强, 等.基于石墨烯的水性导电涂料的制备及其电磁屏蔽性能的研究[J].中国涂料, 2017, 32:2. http://d.old.wanfangdata.com.cn/Periodical/zhonggtl201702004
[38] 薛鹏, 倪维良, 胡秀东, 等.原位改性石墨烯在防腐涂料中的应用[J].涂料工业, 2017, 47(3):72-75. http://d.old.wanfangdata.com.cn/Periodical/tlgy201703013
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