含钴二次资源综合回收技术研究进展

郭豪杰, 段灼, 黄宇坤, 化全县, 曹亦俊. 含钴二次资源综合回收技术研究进展[J]. 矿产保护与利用, 2021, 41(5): 55-64. doi: 10.13779/j.cnki.issn1001-0076.2021.05.009
引用本文: 郭豪杰, 段灼, 黄宇坤, 化全县, 曹亦俊. 含钴二次资源综合回收技术研究进展[J]. 矿产保护与利用, 2021, 41(5): 55-64. doi: 10.13779/j.cnki.issn1001-0076.2021.05.009
GUO Haojie, DUAN Zhuo, HUANG Yukun, HUA Quanxian, CAO Yijun. Research Progress of Comprehensive Recovery Rechnology of Secondary Resources Containing Cobalt[J]. Conservation and Utilization of Mineral Resources, 2021, 41(5): 55-64. doi: 10.13779/j.cnki.issn1001-0076.2021.05.009
Citation: GUO Haojie, DUAN Zhuo, HUANG Yukun, HUA Quanxian, CAO Yijun. Research Progress of Comprehensive Recovery Rechnology of Secondary Resources Containing Cobalt[J]. Conservation and Utilization of Mineral Resources, 2021, 41(5): 55-64. doi: 10.13779/j.cnki.issn1001-0076.2021.05.009

含钴二次资源综合回收技术研究进展

  • 基金项目:
    国家自然科学基金青年项目(51904275)
详细信息
    作者简介: 郭豪杰(1997-), 男, 硕士研究生, 主要从事含钴冶金渣高效回收研究, E-mial: 843742313@qq.com
    通讯作者: 黄宇坤(1990-), 男, 博士, 副教授, 主要从事矿物综合利用研究, E-mail: huang90@zzu.edu.cn 化全县(1974-), 男, 博士, 副教授, 主要从事废弃物综合利用研究, E-mail: huaqx@zzu.edu.cn
  • 中图分类号: TD983;TD926.4+2

Research Progress of Comprehensive Recovery Rechnology of Secondary Resources Containing Cobalt

More Information
  • 我国钴资源极度匮乏,严重依赖进口,突出的供需矛盾已成为制约我国钴行业发展的关键。开发含钴二次资源的回收利用技术对于缓解供需矛盾具有重要意义。论文概述了钴矿产资源的分布和储量,介绍了钴二次资源来源及种类,并以含钴冶金渣、废合金、加氢催化剂和废电池等二次资源为主要对象,详细阐述了含钴二次资源中钴的回收利用潜力和相关技术。结果表明,目前含钴二次资源通常采用湿法浸出技术进行回收再利用,其中含钴浸出液中钴与杂质元素的高效分离是回收钴的关键环节。因此,选择性溶出提钴体系和工艺的开发是提高含钴二次资源利用率的核心。

  • 加载中
  • 图 1  全球陆地钴资源储量分布

    Figure 1. 

    图 2  中国钴资源储量分布

    Figure 2. 

    图 3  2019年全球钴消费结构

    Figure 3. 

    图 4  2020年中国钴消费结构

    Figure 4. 

    图 5  锂离子电池结构

    Figure 5. 

    图 6  含钴二次资源回收过程

    Figure 6. 

    图 7  碱性甘氨酸溶液选择性络合浸出分离锌钴技术

    Figure 7. 

    图 8  [69]回收钴、锌的工艺流程

    Figure 8. 

    表 1  钴资源分类[1]

    Table 1.  Classification of cobalt resources

    主要一次资源 主要二次资源
    镍(铜钴)硫化物矿石、红土镍(钴)矿、铜(钴)硫化物矿石、钴(砷)硫化物矿石、深海锰结核 铜冶炼产生的炉渣、锌冶炼产生的净化渣、电解锰净化渣、使用过的高温合金、硬质合金、磁性合金、催化剂、二次电池
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出版历程
收稿日期:  2021-09-10
刊出日期:  2021-10-25

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