原位U-Th/He同位素定年技术研究进展及其低温矿床学应用前景

付山岭; 赵成海

doi:10.15898/j.cnki.11-2131/td.2017.01.002

原位U-Th/He同位素定年技术研究进展及其低温矿床学应用前景

中国科学院地球化学研究所矿床地球化学国家重点实验室, 贵州贵阳 550081

基金项目:
国家自然科学基金重点项目（41230316）；国家重点基础研究发展规划项目（2014CB440906）

详细信息

作者简介: 付山岭, 博士, 助理研究员, 从事矿床地球化学和岩石学研究。E-mail:fushanling@mail.gyig.ac.cn

中图分类号: P597.3

收稿日期: 2016-09-23

修回日期: 2016-12-13

录用日期: 2017-01-12

Progress of in situ U-Th/He Isotopic Dating Technique and Its Application to Low Temperature Deposits

State Key Laboratory of Ore Deposit Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550081, China

Received Date: 23 September 2016

Revised Date: 13 December 2016

Accepted Date: 12 January 2017

摘要

摘要: 应用传统单颗粒方法对目标矿物进行定年具有较高要求（如U、Th等母体同位素均匀分布），需要耗时的酸溶过程，同时还需进行α粒子射出效应校正。原位U-Th/He同位素定年技术是近年发展起来的一种定年技术，其主要原理是采用激光加热目标矿物，并通过与激光系统连接的稀有气体质谱（Alphachron）和电感耦合等离子体质谱（ICP-MS）分别完成⁴He和U、Th等母体同位素分析，将⁴He和U、Th分析结果代入年龄公式计算即可获得目标矿物的U-Th/He年龄。本文阐述了原位U-Th/He同位素定年技术的主要原理、实验测试流程、适用矿物等，重点对原位U-Th/He同位素定年的技术难点和低温矿床学应用前景进行了分析。相对于传统单颗粒方法，原位测试方法解决了两个关键问题：①无需进行α粒子射出效应的校正，提高了定年结果的可靠性和准确度；②能完成母体同位素分布不均匀样品的测试，扩展了U-Th/He同位素定年的应用范围。尽管原位U-Th/He同位素定年技术在侧向加热效应、剥蚀坑体积测定以及标准矿物等方面尚存在一些亟待解决的问题，但已在硅酸盐、磷酸盐、钛铁氧化物等矿物的年代学研究方面展示了良好的应用前景。随着原位U-Th/He同位素定年技术的发展和进步，尤其是硫化物的U-Th/He同位素定年的发展，将为解决低温矿床的年代学问题提供一种新的思路。
- 原位U-Th/He定年 /
- 单颗粒U-Th/He定年 /
- 原位分析 /
- 低温矿床定年
Abstract: The traditional single-grain U-Th/He isotopic dating method a uses time-consuming acid dissolution, correction for α-ejection and more requirements on target minerals (euhedral, transparent, no cracks or inclusions). in situ U-Th/He isotopic dating is a newly developed dating technique, which uses extracted ⁴He from target mineral by laser ablation system and analyzes the ⁴He and U, Th and other parent isotopes via the Noble Gas Mass Spectrum (Alphachron) coupled with laser system and Inductively Coupled Plasma-Mass Spectrometry (ICP-MS). The U-Th/He age of the deposits can be acquired by an age calculation formula using the analytical results of ⁴He, U, and Th isotopes. The principles, analytical processes, and minerals suitable for dating, technique difficulty and application prospect in low-temperature mineral deposits, are presented in this paper. In situ U-Th/He dating technique solved two key problems compared to traditional single-grain method: (1) Correction of α-ejection is unnecessary, improving the reliability and accuracy of dating results, and (2) Overcoming the bias from heterogeneous distribution of parent isotopes (U, Th), enlarging the range of U-Th/He isotopic dating. Although the in situ U-Th/He isotopic dating technique still needs to address issues such as collateral heating, precise measurement of pit volume and standard materials, it has shown itself to be a promising prospect for silicates, phosphates and Fe-Ti oxides. With the improvement of the in situ U-Th/He isotopic dating technique, particularly the U-Th/He isotopic dating of hydrothermal sulfides, this technique will provide a better way to date low-temperature mineralization.
- in situ U-Th/He dating technique /
- single-grain U-Th/He dating technique /
- in situ analytical technique /
- chronology of low-temperature ore deposits

HTML全文

图 1 矿物颗粒内U-Th分布特征及其对定年结果的影响 (据文献[46]修改)

Figure 1.

下载: 全尺寸图片幻灯片

图 2 剥蚀坑形态与剥蚀深度的关系示意图

Figure 2.

下载: 全尺寸图片幻灯片

图 3 不同矿物的U-Th/He同位素体系封闭温度

Figure 3.

下载: 全尺寸图片幻灯片

参考文献(102)

[1]	Hurley P M.Alpha ionization damage as a cause of low helium ratios[J].Transactions American Geophysical Union, 1952, 33(2):174-183. doi: 10.1029/TR033i002p00174
[2]	Hurley P M, Larsen Jr E S, Gottfried D.Comparison of radiogenic helium and lead in zircon[J].Geochimica et Cosmochimica Acta, 1956, 9(1-2):98-102. doi: 10.1016/0016-7037(56)90060-6
[3]	Cox S E, Farley K A, Hemming S R.Insights into the age of the Mono Lake Excursion and magmatic crystal residence time from (U-Th)/He and ²³⁰Th dating of volcanic allanite[J].Earth and Planetary Science Letters, 2012, 319-320:178-184. doi: 10.1016/j.epsl.2011.12.025
[4]	Blackburn T J, Stockli D F, Walker J D.Magnetite (U-Th)/He dating and its application the geochronology of intermediate to mafic volcanic rocks[J].Earth and Planetary Science Letters, 2007, 259(3-4):360-371. doi: 10.1016/j.epsl.2007.04.044
[5]	Blackburn T J, Stockli D F, Carlson R W, et al.(U-Th)/He dating of kimberlites-A case study from North-Eastern Kansas[J].Earth and Planetary Science Letters, 2008, 275(1-2):111-120. doi: 10.1016/j.epsl.2008.08.006
[6]	邱楠生, Reiners P W, 梅庆华, 等.(U-Th)/He年龄在沉积盆地构造-热演化研究中的应用--以塔里木盆地KQ1井为例[J].地球物理学报, 2009, 52(7):1825-1835. http://www.cnki.com.cn/Article/CJFDTOTAL-DQWX200907018.htm Qiu N S, Reiners P W, Mei Q H, et al.Application of the (U-Th)/He thermochronometry to the tectono-thermal evolution of sedimentary basin-A case history of Well KQ1 in the Tarim Basin[J].Chinese Journal of Geophysics, 2009, 52(7):1825-1835. http://www.cnki.com.cn/Article/CJFDTOTAL-DQWX200907018.htm
[7]	俞顺, 陈文, 吕修祥, 等.(U-Th)/He技术约束下库车盆地北缘构造热演化--以吐孜2井为例[J].地球物理学报, 2014, 57(1):62-74. http://www.cnki.com.cn/Article/CJFDTOTAL-DQWX201401007.htm Yu S, Chen W, Lü X X, et al.(U-Th)/He thermochronometry constraints on the Mesozoic-Cenozoic tectono-thermal evolution of Kuqa Basin:A case study of well TZ2[J].Chinese Journal of Geophysics, 2014, 57(1):62-74. http://www.cnki.com.cn/Article/CJFDTOTAL-DQWX201401007.htm
[8]	孙敬博, 孙腾飞, 陈文, 等.新疆东天山红云滩地区构造-热演化探讨:来自Ar-Ar和 (U-Th)/He热年代学的约束[J].岩石学报, 2015, 31(12):3732-3742. Sun J B, Sun T F, Chen W, et al.Thermo-tectono evolution history of Hongyuntan area, Eastern Tianshan, Xinjiang:Constrained from Ar-Ar and (U-Th)/He dating[J].Acta Petrologica Sinica, 2015, 31:3732-3742.
[9]	Dai J G, Wang C S, Hourigan J, et al.Multi-stage tectono-magmatic events of the Eastern Kunlun Range, Northern Tibet:Insights from U-Pb geochronology and (U-Th)/He thermochronology[J].Tectonophysics, 2013, 599:97-106. doi: 10.1016/j.tecto.2013.04.005
[10]	Wolff R, Dunkl I, Lange J M, et al.Superposition of burial and hydrothermal events:Post-Variscan thermal evolution of the Erzgebirge, Germany[J].Terra Nova, 2015, 27(4):292-299. doi: 10.1111/ter.12159
[11]	周祖翼, 许长海, Reiners P W, 等.大别山天堂寨地区晚白垩世以来剥露历史的 (U-Th)/He和裂变径迹分析证据[J].科学通报, 2003, 48(6):598-602. doi: 10.1360/03tb9127 Zhou Z Y, Xu C H, Reiners P W, et al.Evidence of (U-Th)/He & fission track analysis on denudation history after Late Cretaceous in the Tiantangzhai area of the Dabieshan Mountain[J].Chinese Science Bulletin, 2003, 48(6):598-602. doi: 10.1360/03tb9127
[12]	Qiu N S, Jiang G, Mei Q H, et al.The Paleozoic tectonothermal evolution of the Bachu Uplift of the Tarim Basin, NW China:Constraints from (U-Th)/He ages, apatite fission track and vitrinite reflectance data[J].Journal of Asian Earth Sciences, 2011, 41(6):551-563. doi: 10.1016/j.jseaes.2011.02.008
[13]	Wang E, Kirby E, Furlong K P, et al.Two-phase growth of high topography in eastern Tibet during the Cenozoic[J].Nature Geoscience, 2012, 5:640-645. doi: 10.1038/ngeo1538
[14]	Yu S, Chen W, Evans N J, et al.Cenozoic uplift, exhumation and deformation in the north Kuqa Depression, China as constrained by (U-Th)/He thermochronometry[J].Tectonophysics, 2014, 630:166-182. doi: 10.1016/j.tecto.2014.05.021
[15]	Sobczyk A, Danisik M, Aleksandrowski P, et al.Post-Variscan cooling history of the central Western Sudetes (NE Bohemian Massif, Poland) constrained by apatite fission-track and zircon (U-Th)/He thermochronology[J].Tectonophysics, 2015, 649:47-57. doi: 10.1016/j.tecto.2015.02.021
[16]	Ehlers T A, Farley K A.Apatite (U-Th)/He thermo-chronometry:Methods and applications to problems in tectonic and surface processes[J]. Earth and Planetary Science Letters, 2003, 206(1-2):1-14. doi: 10.1016/S0012-821X(02)01069-5
[17]	Ehlers T A, Farley K A, Rusmore M E.Apatite (U-Th)/He signal of large-magnitude accelerated glacial erosion, Southwest British Columbia[J].Geology, 2006, 34(9):765-768. doi: 10.1130/G22507.1
[18]	Campbell I H, Reiners P W, Allen C M, et al.He-Pb double dating of detrital zircons from the Ganges and Indus Rivers:Implications for quantifying sediments recycling and provenance studies[J].Earth and Planetary Science Letters, 2005, 237(3-4):402-432. doi: 10.1016/j.epsl.2005.06.043
[19]	Rahl J M, Ehlers T A, van der Pluijm B A.Quantifying transient erosion of orogens with detrital thermochronology from syntectonic basin deposits[J].Earth and Planetary Science Letters, 2007, 256(1-2):147-161. doi: 10.1016/j.epsl.2007.01.020
[20]	Pi T, Sole J, Taran Y.(U-Th)/He dating of fluorite:Application to the La Azul fluorspar deposit in the Taxco mining district, Mexico[J].Mineralium Deposita, 2005, 39(8):976-982. doi: 10.1007/s00126-004-0443-y
[21]	Cabral A R, Eugster O, Brauns M, et al.Direct dating of gold by radiogenic helium:Testing the method on gold from Diamantina, Minas Gerais, Brazil[J].Geology, 2013, 41(2):163-166. doi: 10.1130/G33751.1
[22]	Wolff R, Dunkl I, Kempe U, et al.The age of the latest thermal overprint of tin and polymetallic deposits in the Erzgebirge, Germany:Constraints from fluorite (U-Th-Sm)/He thermochronology[J].Economic Geology, 2015, 110(8):2025-2040. doi: 10.2113/econgeo.110.8.2025
[23]	保增宽, 袁万明, 王世成, 等.磷灰石 (U-Th)/He定年技术及应用简介[J].岩石矿物学杂志, 2005, 24(2):126-132. http://www.cnki.com.cn/Article/CJFDTOTAL-YSKW200502005.htm Bao Z K, Yuan W M, Wang S C, et al.Apatite (U-Th)/He dating and its application[J].Acta Petrologica et Mineralogica, 2005, 24(2):126-132. http://www.cnki.com.cn/Article/CJFDTOTAL-YSKW200502005.htm
[24]	陈文, 何学贤, 张彦, 等.金属矿床年龄测定新技术--(U-Th)/He同位素定年方法[J].矿床地质, 2010, 29(增刊):821-822. http://www.cnki.com.cn/Article/CJFDTOTAL-KCDZ2010S1412.htm Chen W, He X X, Zhang Y, et al.A new dating technique for metallic mineral deposit-(U-Th)/He isotopic dating[J].Mineral Deposits, 2010, 29(Supplement):821-822. http://www.cnki.com.cn/Article/CJFDTOTAL-KCDZ2010S1412.htm
[25]	蒋毅, 常宏.磷灰石 (U-Th)/He定年方法综述[J].岩石矿物学杂志, 2012, 31(5):757-766. Jiang Y, Chang H.Apatite (U-Th)/He dating:A review[J].Acta Petrologica et Mineralogica, 2012, 31(5):757-766.
[26]	Evans N J, Byrne J, Keegan J, et al.Determination of uranium and thorium in zircon, apatite, and fluorite:Application to laser (U-Th)/He thermochronology[J].Journal of Analytical Chemistry, 2005, 60(12):1159-1165. doi: 10.1007/s10809-005-0260-1
[27]	Boyce J W, Hodges K V, Olszewski W J, et al.Laser microprobe (U-Th)/He geochronology[J].Geochimica et Cosmochimica Acta, 2006, 70(12):3031-3039. doi: 10.1016/j.gca.2006.03.019
[28]	Boyce J W, Hodges K V, King D, et al.Improved confidence in (U-Th)/He thermochronology using the laser microprobe:An example from a Pleistocene leucogranite, Nanga Parbat, Pakistan[J].Geochemistry Geophysics Geosystems, 2009, 10(9):1-13.
[29]	van Soest M C, Monteleone B D, Boyce J W, et al.Advances in laser microprobe (U-Th)/He geochronology[R].American Geophysical Union (Fall Meeting), 2008.
[30]	Tripathy-Lang A, Monteleone B D, van Soest M C, et al.In situ detrital zircon (U-Th)/He thermochronology[R].American Geophysical Union (Fall Meeting), 2010.
[31]	Tripathy-Lang A, Hodges K V, Monteleone B D, et al.Laser (U-Th)/He thermochronology of detrital zircons as a tool for studying surface processes in modern catchments[J].Journal of Geophysical Research:Earth Surface, 2013, 118(3):1333-1341. doi: 10.1002/jgrf.20091
[32]	Vermeesch P, Sherlock S C, Roberts N M W, et al.A simple method for in-situ U-Th-He dating[J].Geochimica et Cosmochimica Acta, 2012, 79:140-147. doi: 10.1016/j.gca.2011.11.042
[33]	Evans N J, McInnes B I A, McDonald B, et al.An in situ technique for (U-Th-Sm)/He and U-Pb double dating[J].Journal of Analytical Atomic Spectrometry, 2015, 30:1636-1645. doi: 10.1039/C5JA00085H
[34]	Horne A M, van Soest M C, Hodges K V, et al.Integrated single crystal ablation U/Pb and (U-Th)/He dating of detrital accessory minerals-proof-of-concept studies of titanites and zircons from the Fish Canyon Tuff[J].Geochimica et Cosmochimica Acta, 2016, 178:106-123. doi: 10.1016/j.gca.2015.11.044
[35]	Farley K A.(U-Th)/He dating:Techniques, calibrations, and applications[J].Reviews in Mineralogy and Geochemistry, 2002, 47(1):819-844. doi: 10.2138/rmg.2002.47.18
[36]	吴堑红, 刘厚昌.(U-Th)/He定年--低温热年代学研究的一种新技术[J].地球科学进展, 2002, 17(1):126-131. http://www.cnki.com.cn/Article/CJFDTOTAL-DXJZ200201019.htm Wu Q H, Liu H C.(U-Th)/He dating-A new method of low-temperature thermochronometry[J].Advance in Earth Sciences, 2002, 17(1):126-131. http://www.cnki.com.cn/Article/CJFDTOTAL-DXJZ200201019.htm
[37]	Boyce J W, Hodges K V.U and Th zoning in Cerro de Mercado (Durango, Mexico) fluorapatite:Insights regarding the impact of recoil redistribution of radiogenic ⁴He on (U-Th)/He thermochronology[J].Chemical Geology, 2005, 219(1-4):261-274. doi: 10.1016/j.chemgeo.2005.02.007
[38]	Dobson K J, Stuart F M, Dempster T J, et al.U and Th zonation in Fish Canyon Tuff zircons:Implications for a zircon (U-Th)/He standard[J].Geochimica et Cosmochimica Acta, 2008, 72(19):4745-4755. doi: 10.1016/j.gca.2008.07.015
[39]	Ault A K, Flowers R M.Is apatite U-Th zonation information necessary for accurate interpretation of apatite (U-Th)/He thermochronometry data[J].Geochimica et Cosmochimica Acta, 2011, 79:60-78.
[40]	Farley K A, Shuster D L, Ketcham R A.U and Th zonation in apatite observed by laser ablation ICPMS, and implications for the (U-Th)/He system[J].Geochimica et Cosmochimica Acta, 2011, 75(16):4515-4530. doi: 10.1016/j.gca.2011.05.020
[41]	Hourigan J K, Reiners P W, Brandon M T.U-Th zonation-dependent alpha-ejection in (U-Th)/He chronometry[J].Geochimica et Cosmochimica Acta, 2005, 69(13):3349-3365. doi: 10.1016/j.gca.2005.01.024
[42]	Farley K A, Wolf R A, Fallick A E.The effects of long alpha-stopping distances on (U-Th)/He ages[J].Geochimica et Cosmochimica Acta, 1996, 60(21):4223-4229. doi: 10.1016/S0016-7037(96)00193-7
[43]	Ketcham R A, Gautheron C, Tassan-Got L.Accounting for long alpha-particle stopping distances in (U-Th-Sm)/He geochronology:Refinement of the baseline case[J].Geochimica et Cosmochimica Acta, 2011, 75(24):7779-7791. doi: 10.1016/j.gca.2011.10.011
[44]	Gautheron C, Tassan-Got L, Ketcham R R A, et al.Accounting for long alpha-particle stopping distances in (U-Th-Sm)/He geochronology:3D modeling of diffusion, zoning, implantation, and abrasion[J].Geochimica et Cosmochimica Acta, 2012, 96:44-56. doi: 10.1016/j.gca.2012.08.016
[45]	Meesters A G C A, Dunai T J.Solving the production-diffusion equation for finite diffusion domains of various shapes Part Ⅱ.Application to cases with α-ejection and nonhomogeneous distribution of the source[J].Chemical Geology, 2002, 186(3-4):57-73. https://www.researchgate.net/publication/223572432_Solving_the_production-diffusion_equation_for_finite_diffusion_domains_of_various_shapes_Part_II_Application_to_cases_with_a-ejection_and_nonhomogeneous_distribution_of_the_source
[46]	Bargnesi E A, Stockli D F, Hourigan J K, et al.Improved accuracy of zircon (U-Th)/He ages by rectifying parent nuclide zonation with practical methods[J].Chemical Geology, 2016, 426:158-169. doi: 10.1016/j.chemgeo.2016.01.017
[47]	Zeitler P K, Herczeg A L, McDougall I, et al.U-Th-He dating of apatite-A potential thermochronometer[J].Geochimica et Cosmochimica Acta, 1987, 51(10):2865-2868. doi: 10.1016/0016-7037(87)90164-5
[48]	Lippolt H J, Leitz M, Wernicke R S, et al.(Uranium+thorium)/helium dating of apatite:Experience with samples from different geochemical environments[J].Chemical Geology, 1994, 112(1-2):179-191. doi: 10.1016/0009-2541(94)90113-9
[49]	Wolf R A, Farley K A, Silver L T.Helium diffusion and low-temperature thermochronometry of apatite[J].Geochimica et Cosmochimica Acta, 1996, 60(21):4231-4240. doi: 10.1016/S0016-7037(96)00192-5
[50]	House M A, Farley K A, Stockli D F.Helium chronometry of apatite and titanite using Nd-YAG laser heating[J].Earth and Planetary Science Letters, 2000, 183(3-4):365-368. doi: 10.1016/S0012-821X(00)00286-7
[51]	Foeken J P, Stuart F M, Dobson K J, et al.A diode laser system for heating minerals for (U-Th)/He chronometry[J].Geochemistry, Geophysics, Geosystems, 2006, 7(4):1-9.
[52]	Kelly S P, Cherniak D J, Farley K A, et al.Testing the limits to high spatial resolution laser analysis of noble gases in natural and experimental samples[J].Goldschmidt Conference Abstracts, 2009:A636.
[53]	Reiners P W.Zircon (U-Th)/He thermochronometry[J].Reviews in Mineralogy and Geochemistry, 2005, 58(1):151-179. doi: 10.2138/rmg.2005.58.6
[54]	Stockli D F, Farley K A.Empirical constraints on the titanite (U-Th)/He partial retention zone from the KTB drill hole[J].Chemical Geology, 2004, 207(3-4):223-236. doi: 10.1016/j.chemgeo.2004.03.002
[55]	Aciego A, Kennedy B M, DePaolo D J, et al.U-Th/He age of phenocrystic garnet from the 79AD eruption of Mt.Vesuvius[J].Earth and Planetary Sciences Letters, 2003, 219(1-2):209-219.
[56]	Farley K A, Stockli D F.(U-Th)/He dating of phosphates:Apatite, monazite, and xenotime[J].Reviews in Mineralogy and Geochemistry, 2002, 48(1):559-577. doi: 10.2138/rmg.2002.48.15
[57]	Min K, Farley K A, Renne P R, et al.Single grain (U-Th)/He ages from phosphates in Acapulco meteorite and implications for thermal history[J].Earth and Planetary Science Letters, 2003, 209(3-4):323-336. doi: 10.1016/S0012-821X(03)00080-3
[58]	Min K, Reiners P W, Shuster D L.(U-Th)/He ages of phosphates from St.S verin LL6 chondrite[J].Geochimica et Cosmochimica Acta, 2013, 100:282-296. doi: 10.1016/j.gca.2012.09.042
[59]	Boyce J W, Hodges K V, Olszewski W J, et al.He diffusion in monazite:Implications for (U-Th)/He thermochronometry[J].Geochemistry, Geophysics, Geosystems, 2005, 6(12):1-12.
[60]	Evans N J, Wilson N S F, Cline J S, et al.Fluorite (U-Th)/He thermochronology:Constraints on the low temperature history of Yucca Mountain, Nevada[J].Applied Geochemistry, 2005, 20(6):1099-1105. doi: 10.1016/j.apgeochem.2005.02.008
[61]	Copeland P, Watson E B, Urizar S C, et al.Alpha thermochronology of carbonates[J].Geochimica et Cosmochimica Acta, 2007, 71(18):4488-4511. doi: 10.1016/j.gca.2007.07.004
[62]	Cros A, Gautheron C, Pagel M, et al.⁴He behavior in calcite filling viewed by (U-Th)/He dating, ⁴He diffusion and crystallographic studies[J].Geochimica et Cosmochimica Acta, 2014, 125:414-432. doi: 10.1016/j.gca.2013.09.038
[63]	Stockli D F, Wolfe M R, Blackburn T J, et al.He diffusion and (U-Th)/He thermochronometry of rutile[J].American Geophysical Union Fall Meeting, 2007:1548.
[64]	Meinhold G.Rutile and its applications in earth sciences[J].Earth-Science Reviews, 2010, 102(1-2):1-28. doi: 10.1016/j.earscirev.2010.06.001
[65]	Shuster D L, Vasconcelos P M, Heim J A, et al.Weathering geochronology by U-Th/He dating of goethite[J].Geochimica et Cosmochimica Acta, 2005, 69(3):659-673. doi: 10.1016/j.gca.2004.07.028
[66]	Wernicke R S, Lippolt H J.(U-Th)-He evidence of Jurassic continuous hydrothermal activity in the Schwarzwald basement, Germany[J].Chemical Geology, 1997, 138(3-4):273-285. doi: 10.1016/S0009-2541(97)00020-X
[67]	Shukolyukov Y A, Yakubovich O V, Rytsk Y A.About possibility of isotope dating of native gold by the (U-Th)/He method[J].Doklady Earth Sciences, 2010, 430(1):90-94. doi: 10.1134/S1028334X10010204
[68]	Yakubovich O V, Shukolyukov Y A, Kotov A B, et al.U-Th-He dating of native gold:First results, problems and outlooks[J].Petrology, 2014, 22(5):429-437. doi: 10.1134/S0869591114050075
[69]	LeHarzic R, Valette S, Huot N, et al.TEM Investigations of Thermal Effects on Material Structure Induced by Femtosecond and Nanosecond Laser Processing[C]//Sugioka K, Gower M C, Haglund R F, et al.Photon Processing in Microelectronics and Photonics:Proceedings of SPIE, Vol.4637.Bellingham, 2002:148-158.
[70]	Yao Y L, Chen H Q, Zhang W W.Time scale effects in laser material removal:A review[J].International Journal of Advanced Manufacturing Technology, 2005, 26(5):598-608.
[71]	van Soest M C, Monteleone B D, Boyce J W, et al.Laser depth profiling studies of helium diffusion in Durango fluorapatite[J].Geochimica et Cosmochimica Acta, 2011, 75(9):2409-2419. doi: 10.1016/j.gca.2011.02.008
[72]	Liu W L, Xia H R, Wang X Q, et al.Characterization of deuterated potassium dihydrogen phosphate single crystals grown by circulating method[J].Journal of Crystal Growth, 2006, 293(2):387-393. doi: 10.1016/j.jcrysgro.2006.05.040
[73]	Santos E A F, Silva W F, de Araújo M T, et al.Quantum efficiencies and thermo-optical properties of Er³⁺-, Nd³⁺-, and P³⁺-single doped lead-indium-phosphate glasses[J].Journal of Applied Physics, 2009, 106:1-6.
[74]	Hodapp T W, Fleming P R.Modeling topology formation during laser ablation[J].Journal of Applied Physics, 1998, 84(1):577-583. doi: 10.1063/1.368063
[75]	Usoskin A, Freyhardt H C, Krebs H U.Influence of light scattering on the development of laser-induced ridge-cone structures on target surfaces[J].Applied Physics A:Materials Science & Processing, 1999, 69:S823-S826.
[76]	Woodhead J, Hergt J, Meffre S, et al.In situ Pb-isotope analysis of pyrite by laser ablation (multi-collector and quadrupole) ICPMS[J].Chemical Geology, 2009, 262(3-4):344-354. doi: 10.1016/j.chemgeo.2009.02.003
[77]	Wolf R A, Farley K A, Kass D M.Modeling of the temperature sensitivity of the apatite (U-Th)/He thermochronometer[J].Chemical Geology, 1998, 148(1-2):105-114. doi: 10.1016/S0009-2541(98)00024-2
[78]	Reiners P W, Spell T L, Nicolescu S, et al.Zircon (U-Th)/He thermochronometry:He diffusion and comparisons with ⁴⁰Ar/³⁹Ar dating[J].Geochimica et Cosmochimica Acta, 2004, 68(8):1857-1887. doi: 10.1016/j.gca.2003.10.021
[79]	Siebel W, Hann H P, Danisik M, et al.Age constraints on faulting and fault reactivation:A multi-chronological approach[J].International Journal of Earth Science, 2010, 99(6):1187-1197. doi: 10.1007/s00531-009-0474-9
[80]	Crowhurst P, Farley K A, Ryan C, et al.Potential of rutile as a U-Th-He thermochronometer[J].Geochimica et Cosmochimica Acta, 2002(Supplement 1), 66:A158.
[81]	Stockli D F, Farley K A, Walker J D, et al.Helium diffusion and (U-Th)/He thermochronometry of monazite and rutile[J].Geochimica et Cosmochimica Acta, 2005, 69(10):A8.
[82]	Wolfe M R, Stockli D F, Shuster D L, et al.Assessment of the rutile (U-Th)/He thermochronometry on the KTB drill hole, Germany[R].American Geophysical Union (Fall Meeting), 2007.
[83]	Peterman E M, Hourigan J K, Grove M.Experimental and geologic evaluation of monazite (U-Th)/He thermochronometry:Catnip Sill, Catalina core complex, Tucson, AZ[J].Earth and Planetary Science Letters, 2014, 403:48-55. doi: 10.1016/j.epsl.2014.06.020
[84]	McInnes B I A, Evans N J, Fu F Q, et al.Thermal History Analysis of Selected Chilean, Indonesian and Iranian Porphyry Cu-Mo-Au Deposits[M]//Porter T M.Super Porphyry Copper & Gold Deposits:A Global Perspective.Adelaide:PGC Publishing, 2005:1-16.
[85]	McInnes B I A, Evans N J, Fu F Q, et al.Application of thermochronology to hydrothermal ore deposits[J].Reviews in Mineralogy and Geochemistry, 2005, 58(1):467-498. doi: 10.2138/rmg.2005.58.18
[86]	Harris A, Dunlap W J, Reiners P W, et al.Multimillion year thermal history of a porphyry copper deposit:Application of U-Pb, ⁴⁰Ar/³⁹Ar and (U-Th)/He chrono-meters, Bajo de la Alumbrera copper-gold deposit, Argentina[J].Mineralium Deposita, 2008, 43(3):295-314. doi: 10.1007/s00126-007-0151-5
[87]	Betsi T B, Lentz D, McInnes B I A, et al.Emplacement ages and exhumation rates for intrusion-hosted Cu-Mo-Sb-Au mineral systems at Freegold Mountain (Yukon, Canada):Assessment from U-Pb, Ar-Ar, and (U-Th)/He geochronometer[J].Canada Journal of Earth Sciences, 2012, 49(5):653-670. doi: 10.1139/e2012-009
[88]	Li G M, Cao M J, Qin K Z, et al.Thermal-tectonic history of the Baogutu porphyry Cu deposit, West Junggar as constrained from zircon U-Pb, biotite Ar/Ar and zircon/apatite (U-Th)/He dating[J].Journal of Asian Earth Sciences, 2014, 79(Part B):741-758.
[89]	Li J X, Qin K Z, Li G M, et al.Petrogenesis and thermal history of the Yulong porphyry copper deposit, Eastern Tibet:Insights from U-Pb and U-Th/He dating, and zircon Hf isotopes and trace element analysis[J].Mineralogy and Petrology, 2012, 105(3):201-221.
[90]	Liu X, Fan H R, Evans N J, et al.Cooling and exhumation of the mid-Jurassic porphyry copper systems in Dexing City, SE China:Insights from geo-and thermochronology[J].Mineralium Deposita, 2014, 49(7):809-819. doi: 10.1007/s00126-014-0536-1
[91]	Arehart G B, Chakurian A M, Tertbar D R, et al.Evaluation of radioisotope dating of Carlin-type deposits in the Great Basin, Western North America, and implications for deposit genesis[J].Economic Geology, 2003, 98(2):235-248.
[92]	Zeng Q T, Evans N J, McInnes B I A, et al.Geological and thermochronological studies of the Dashui gold deposit, West Qinling Orogen, Central China[J].Mineralium Deposita, 2013, 48(3):397-412. doi: 10.1007/s00126-012-0433-4
[93]	Eugster O, Hofmann B, Krahenbuhl U, et al.Noble gases in alpine gold:U/Th-He dating and excesses of radiogenic He and Ar[J].Meteoritics, 1992, 27(3):219-220.
[94]	Eugster O, Niedermann S, Thalmann C, et al.Noble gases, K, U, Th, and Pb in native gold[J]. Journal of Geophysical Research, 1995, 100(B12):24677-24689. doi: 10.1029/95JB02843
[95]	Niedermann S, Eugster O, Frei R, et al.Formation of alpine Au~30Ma ago:Further results of the develop-ment of a dating method for native Au[J].Meteoritics, 1993, 28(3):411-412.
[96]	Pettke T, Frei R, Kramers J D, et al.Isotope systematics in vein gold from Brusson, Vald'Ayas (NW Italy):2.(U+Th)/He and K/Ar in native Au and its fluid inclusions[J].Chemical Geology, 1997, 135(3-4):173-187. doi: 10.1016/S0009-2541(96)00114-3
[97]	Shukolyukov Y A, Yakubovich O V, Yakovleva S Z, et al.Geothermochronology based on noble gases:Ⅲ.Migration of radiogenic He in the crystal structure of native metals with applications to their isotopic dating[J].Petrology, 2012, 20(1):1-20. doi: 10.1134/S0869591112010043
[98]	Heim J A, Vasconcelos P M, Shuster D L, et al.Dating paleochannel iron ore by (U-Th)/He analysis of supergene goethite, Hamersley Province, Australia[J].Geology, 2006, 34(3):173-176. doi: 10.1130/G22003.1
[99]	Farley K A, Flowers R M.(U-Th)/Ne and multidomain (U-Th)/He systematics of a hydrothermal hematite from Eastern Grand Canyon[J].Earth and Planetary Science Letters, 2012, 359-360:131-140. doi: 10.1016/j.epsl.2012.10.010
[100]	Danisik M, Evans N J, Ramanaidou E R, et al.(U-Th)/He chronology of the Robe River channel iron deposits, Hamersley Province, Western Australia[J].Chemical Geology, 2013, 354:150-162. doi: 10.1016/j.chemgeo.2013.06.012
[101]	Burnard P G, Polya D A.Importance of mantle derived fluids during granite associated hydrothermal circulation:He and Ar isotopes of ore minerals from Panasqueira[J].Geochimica et Cosmochimica Acta, 2004, 68(7):1607-1615. doi: 10.1016/j.gca.2003.10.008
[102]	Jean-Baptiste P H, Fouquet Y.Abundance and isotopic composition of helium in hydrothermal sulfides from the East Pacific Rise at 13°N[J].Geochimica et Cosmochimica Acta, 1996, 60(1):87-93. doi: 10.1016/0016-7037(95)00357-6

施引文献

资源附件(0)

访问统计

图(3)

计量

文章访问数: 2849
PDF下载数: 84
施引文献: 0

原位U-Th/He同位素定年技术研究进展及其低温矿床学应用前景

中国科学院地球化学研究所矿床地球化学国家重点实验室, 贵州 贵阳 550081

作者简介: 付山岭, 博士, 助理研究员, 从事矿床地球化学和岩石学研究。E-mail:fushanling@mail.gyig.ac.cn

Progress of in situ U-Th/He Isotopic Dating Technique and Its Application to Low Temperature Deposits

State Key Laboratory of Ore Deposit Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550081, China

计量

出版历程

目录

中国科学院地球化学研究所矿床地球化学国家重点实验室, 贵州贵阳 550081