中国地质学会岩矿测试技术专业委员会、国家地质实验测试中心主办

土壤碳赋存形态及分析方法研究进展

陈宗定, 许春雪, 安子怡, 王亚平, 孙德忠, 王苏明. 土壤碳赋存形态及分析方法研究进展[J]. 岩矿测试, 2019, 38(2): 233-244. doi: 10.15898/j.cnki.11-2131/td.201709270148
引用本文: 陈宗定, 许春雪, 安子怡, 王亚平, 孙德忠, 王苏明. 土壤碳赋存形态及分析方法研究进展[J]. 岩矿测试, 2019, 38(2): 233-244. doi: 10.15898/j.cnki.11-2131/td.201709270148
Zong-ding CHEN, Chun-xue XU, Zi-yi AN, Ya-ping WANG, De-zhong SUN, Su-ming WANG. Research Progress on Fraction and Analysis Methods of Soil Carbon[J]. Rock and Mineral Analysis, 2019, 38(2): 233-244. doi: 10.15898/j.cnki.11-2131/td.201709270148
Citation: Zong-ding CHEN, Chun-xue XU, Zi-yi AN, Ya-ping WANG, De-zhong SUN, Su-ming WANG. Research Progress on Fraction and Analysis Methods of Soil Carbon[J]. Rock and Mineral Analysis, 2019, 38(2): 233-244. doi: 10.15898/j.cnki.11-2131/td.201709270148

土壤碳赋存形态及分析方法研究进展

  • 基金项目:
    中国地质科学院基本科研业务费项目(YYWF201622);国家重点研发计划项目(2016YFF0201103)
详细信息
    作者简介: 陈宗定, 硕士, 主要从事地质矿产标准化研究。E-mail:ding_5424@126.com
  • 中图分类号: S151.93;O613.71

Research Progress on Fraction and Analysis Methods of Soil Carbon

  • 研究土壤碳的赋存形态不仅利于了解碳的迁移转化规律,而且可以为土壤固碳提供科学依据。目前对各形态碳(尤其是有机碳中的慢性及惰性组分)缺乏系统的分析研究。基于此,本文综述了土壤中碳的主要赋存形态,各形态碳的组成、分布及作用,土壤碳的分析、分离方法。土壤无机碳储量约占全球总碳库的38%,赋存形态以碳酸盐为主。土壤有机碳主要分为活性碳库(周转期0.1~4.5年)、慢性碳库(周转期5~50年)和惰性碳库(周转期50~3000年)。其中可溶性有机碳、易氧化有机碳和微生物量碳属于活性有机碳库这一范畴,可以较为灵敏地反映土壤理化性质的微小变化;轻组有机碳和颗粒有机碳属于慢性有机碳库,可作为土壤有机质周转变化的重要指标;重组有机碳和矿物结合态有机碳属于惰性有机碳库,是土壤有机碳固持的重要机制之一。目前土壤中碳酸盐测定方法主要为气量法和滴定法;有机碳分析方法包括容量法、比色法和重量法。本文提出,今后应加强对无机碳及有机碳中的惰性组分研究,同时对土壤有机碳各组分概念及测定方法进行统一,并开展不同地域、不同土壤类型、不同浓度的土壤碳形态标准物质研制工作。
  • 加载中
  • 图 1  我国几种典型土壤100cm深度和20cm深度的有机碳含量

    Figure 1. 

    图 2  土壤无机碳分析方法及流程

    Figure 2. 

    图 3  土壤有机碳分析方法及流程

    Figure 3. 

    表 1  土壤中不同形态有机碳分离/分析方法

    Table 1.  Methods of separation and/or analysis of organic carbon fractions in soil

    土壤有机碳组分 所属碳库 分离/分析方法 文献
    可溶性有机碳 活性库 K2SO4提取,离心 [73]
    易氧化有机碳 活性库 KMnO4氧化法 [74]
    微生物量碳 活性库 氯仿熏蒸提纯/三磷酸腺苷法/精氨酸诱导氨化法 [75]
    轻组有机碳 慢性库 NaI离心,CaCl2淋洗 [37, 76]
    颗粒有机碳 慢性库 (NaPO3)6离散,沉积 [39, 67]
    重组有机碳 惰性库 ZnBr2/NaI/溴仿+乙醇混合液等振荡离心,乙醇洗涤 [45]
    矿物结合态有机碳 惰性库 氢氟酸+盐酸(2:1, V:V)处理 [77]
    下载: 导出CSV
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出版历程
收稿日期:  2017-09-27
修回日期:  2018-06-19
录用日期:  2018-06-22

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