中国地质学会岩矿测试技术专业委员会、国家地质实验测试中心主办

胶东地区新立金矿中金矿物和载金黄铁矿成因矿物学特征及地质意义

张然, 肖志斌, 付超, 付世兴, 朱昭明. 胶东地区新立金矿中金矿物和载金黄铁矿成因矿物学特征及地质意义[J]. 岩矿测试, 2022, 41(6): 997-1006. doi: 10.15898/j.cnki.11-2131/td.202111260189
引用本文: 张然, 肖志斌, 付超, 付世兴, 朱昭明. 胶东地区新立金矿中金矿物和载金黄铁矿成因矿物学特征及地质意义[J]. 岩矿测试, 2022, 41(6): 997-1006. doi: 10.15898/j.cnki.11-2131/td.202111260189
ZHANG Ran, XIAO Zhibin, FU Chao, FU Shixing, ZHU Zhaoming. Genetic Mineralogy and Geological Significance of Gold Minerals and Gold-bearing Pyrites from the Xinli Gold Deposit in the Jiaodong Area[J]. Rock and Mineral Analysis, 2022, 41(6): 997-1006. doi: 10.15898/j.cnki.11-2131/td.202111260189
Citation: ZHANG Ran, XIAO Zhibin, FU Chao, FU Shixing, ZHU Zhaoming. Genetic Mineralogy and Geological Significance of Gold Minerals and Gold-bearing Pyrites from the Xinli Gold Deposit in the Jiaodong Area[J]. Rock and Mineral Analysis, 2022, 41(6): 997-1006. doi: 10.15898/j.cnki.11-2131/td.202111260189

胶东地区新立金矿中金矿物和载金黄铁矿成因矿物学特征及地质意义

  • 基金项目:
    国家自然科学基金项目(41802207);国家重点研发计划项目(2016YFC0600107-1);中国地质调查局地质调查项目(DD20221686)
详细信息
    作者简介: 张然,硕士,工程师,主要从事成因矿物学与找矿矿物学研究。E-mail:rayna_zhang@126.com
    通讯作者: 肖志斌,硕士,高级工程师,主要从事分析地球化学研究。E-mail:zhibin_xiao@163.com 付超,硕士,高级工程师,主要从事战略性矿产调查评价与矿床学研究。E-mail: fuchaocugb@163.com
  • 中图分类号: P575.1;P578.292

Genetic Mineralogy and Geological Significance of Gold Minerals and Gold-bearing Pyrites from the Xinli Gold Deposit in the Jiaodong Area

More Information
  • 山东省胶东地区西北部是该地区最重要的金矿成矿区。新立金矿是三山岛—新立成矿带的重要矿床,也是该区典型金矿之一。对新立金矿的研究已开展多年且成果较多,但在金矿物与载金矿物的矿物学特征、矿物标型特征等方面还需开展深入研究。偏反光显微镜鉴定和电子探针定量成分分析是金矿物和载金矿物研究中的主要方法,本文将两种方法相结合,对新立金矿的金矿物和载金黄铁矿的物理性质、化学成分等矿物学特征进行详细研究,并通过矿物标型特征探讨其地质意义。结果表明:新立金矿中的金矿物主要为银金矿、少量自然金和金银矿,金成色在336.2~834.9不等,平均699.8。载金黄铁矿中S含量为51.69%~53.78%,平均53.19%;Fe含量为45.69%~47.62%,平均46.52%;S/Fe值为1.99,硫略亏损。黄铁矿形态标型呈粗粒立方体形-中细粒五角十二面体形-细粒立方体形的演化趋势,反映了不同成矿阶段热液流体温度逐渐降低的演化过程;成分标型特征显示,成矿热液具有典型的中浅成、中低温特点。据此认为,新立金矿热液蚀变期存在三阶段矿化,其中第三阶段为主成矿期,且在多阶段叠加复合部位更易富集成矿。

  • 加载中
  • 图 1  矿区大地构造位置(据王君亭等,2005[22]修改)

    Figure 1. 

    图 2  金矿物、黄铁矿的反射光和背散射图像

    Figure 2. 

    图 3  黄铁矿(a)Co-Ni图解和(b)As-Co-Ni三角图解(底图据严育通等,2012[2])

    Figure 3. 

    表 1  金矿物中元素电子探针分析结果

    Table 1.  EPMA analysis results of elements in gold minerals

    样品点号 Ag
    (%)
    As
    (%)
    Au
    (%)
    Co
    (%)
    Cr
    (%)
    Cu
    (%)
    Fe
    (%)
    Ni
    (%)
    S
    (%)
    Se
    (%)
    Zn
    (%)
    总计
    (%)
    YT-YK1-1 26.58 - 70.25 - - 0.00 0.56 - - - 0.00 97.39
    YT-YK1-2 26.49 - 72.39 - - 0.36 0.61 - - - 0.15 100.00
    YT-YK2-1 36.39 - 60.19 - - 1.70 1.72 - - - 0.00 100.00
    YT-YK2-2 64.28 - 32.86 - - 0.33 0.28 - - - 0.00 97.75
    YT-YK3-1 14.89 - 83.87 - - 0.23 0.97 - - - 0.05 100.01
    YT-YK3-2 19.30 - 80.62 - - 0.00 0.08 - - - 0.00 100.00
    YT-YK4-1 14.96 - 83.90 - - 0.00 0.31 - - - 0.31 99.48
    YT-YK4-2 14.61 - 84.80 - - 0.29 0.31 - - - 0.00 100.01
    XL-YK2-8 45.26 - 51.87 - 0.07 0.08 0.55 - 0.17 - - 98.00
    XL-YK2-9 36.42 - 61.98 - - - 1.28 0.01 0.26 - 0.01 99.97
    XL-YK2-10 35.81 - 63.52 - - - 1.12 - 0.22 0.04 - 100.71
    XL-YK2-11 38.85 - 58.01 - 0.51 0.02 0.65 - 0.15 - - 98.19
    XL-YK3-1 21.71 0.01 78.15 - 0.65 - - - 0.01 - - 100.53
    XL-YK3-2 21.19 - 77.64 0.02 0.43 - 0.37 - 0.02 - - 99.66
    XL-YK3-4 21.95 - 76.80 - 0.64 - 0.05 0.02 0.04 - - 99.50
    XL-YK3-5 21.66 - 76.76 - 0.49 - 0.03 - 0.01 - 0.05 99.01
    XL-YK4-4 27.95 - 69.44 - - - 0.81 - 0.13 - - 98.33
    XL-YK4-5 28.20 - 70.61 - - - 0.84 - 0.15 - - 99.80
    XL-YK4-6 29.27 - 69.52 0.02 - - 1.62 - 0.18 0.02 - 100.64
    XL-YK4-12 24.57 - 73.06 0.02 1.69 - 0.03 - 0.03 - 0.01 99.40
    XL-YK4-13 25.87 - 72.94 - 0.90 - - - - - - 99.72
    XL-YK4-14 23.21 - 70.37 - 3.60 0.32 0.27 - 0.05 - 0.05 97.87
    XL-YK4-15 27.61 - 67.91 - 3.16 - 0.05 - 0.01 - - 98.75
    XL-YK4-18 31.10 - 67.22 - 0.91 - 0.22 0.02 0.09 - 0.02 99.58
    注:表中“-”代表低于电子探针分析测试检测限。
    下载: 导出CSV

    表 2  载金黄铁矿中元素含量电子探针分析结果

    Table 2.  EPMA analysis results of elements in gold-bearing pyrites

    样品点号 S
    (%)
    Fe
    (%)
    As
    (%)
    Se
    (%)
    Co
    (%)
    Ni
    (%)
    Cu
    (%)
    Zn
    (%)
    Cr
    (%)
    Pb
    (%)
    Au
    (%)
    Ag
    (%)
    总计
    (%)
    XL-YK2-2 53.50 46.54 - - 0.05 - - - - - - - 100.09
    XL-YK2-4 53.31 46.50 - - 0.04 - 0.03 0.02 - - - - 99.90
    XL-YK2-6 53.35 46.79 0.05 - 0.04 - 0.02 - - - 0.05 - 100.31
    XL-YK2-7 53.22 46.14 0.11 - 0.05 - - - 0.01 - - - 99.53
    XL-YK2-12 53.01 47.05 0.37 - 0.03 - - - - - 0.04 - 100.51
    XL-YK2-13 53.42 46.94 0.03 - 0.06 - - - - - - 0.02 100.48
    XL-YK2-14 52.93 46.35 0.56 - 0.05 - - 0.03 - - - - 99.94
    XL-YK3-3 52.74 45.70 - - 0.06 0.02 - - 0.01 - - - 98.53
    XL-YK3-6 53.63 45.90 - - 0.07 - - - - - - 0.01 99.64
    XL-YK4-1 53.23 47.62 0.03 0.01 0.06 - - 0.01 - - - - 100.97
    XL-YK4-3 52.49 46.17 0.11 - 0.06 0.09 0.10 - - 0.05 - - 99.07
    XL-YK4-7 53.16 45.69 - - 0.05 - 0.03 0.01 - - 0.04 - 98.98
    XL-YK4-8 53.34 46.39 0.11 0.05 0.15 0.15 0.01 - 0.02 - - - 100.23
    XL-YK4-9 53.04 46.89 0.07 - 0.12 0.11 0.03 - 0.03 - - - 100.31
    XL-YK4-10 52.89 46.18 0.04 - 0.05 0.01 0.03 - - - - - 99.20
    XL-YK4-11 53.11 46.58 - - 0.04 0.01 - - - - - - 99.75
    XL-YK5-1 52.64 46.25 0.61 - 0.06 - 0.03 - - - - - 99.60
    XL-YK5-2 53.05 46.74 0.42 - 0.06 - - 0.03 - - - - 100.29
    XL-YK5-3 53.64 46.30 0.01 - 0.04 - - - - - - - 100.01
    XL-YK5-4 53.13 45.92 0.48 - 0.07 - - - - - - - 99.61
    XL-YK5-5 53.20 46.39 0.35 0.01 0.03 - 0.01 - - - - - 100.01
    XL-YK5-6 53.16 46.29 0.54 - 0.03 - 0.02 - - - - - 100.06
    XL-YK6-1 52.69 47.09 - - 0.04 - - 0.02 - - - - 99.85
    XL-YK6-2 51.69 46.45 0.18 - 0.03 - - - - - - - 98.36
    XL-YK6-3 52.88 46.82 0.17 - 0.08 - 0.02 - - - - 0.01 99.99
    XL-YK7-1 53.00 46.77 0.05 - 0.05 - - - - - 0.02 - 99.91
    XL-YK7-2 53.25 46.40 0.16 - 0.05 - - - - - - - 99.86
    XL-YK7-3 53.46 47.06 0.11 - 0.04 0.01 0.02 0.03 0.02 - - - 100.74
    XL-YK7-4 53.19 46.84 0.07 - 0.03 0.03 - - - - - - 100.18
    XL-YK7-5 53.32 46.86 0.04 - 0.06 0.02 0.02 - - - - - 100.33
    XL-YK7-6 52.09 46.82 - - 0.06 0.03 - - 0.29 - - - 99.29
    XL-YK10-1 53.45 46.57 0.10 0.02 0.09 0.01 - - - - - - 100.26
    XL-YK10-2 53.63 46.90 0.02 0.02 0.04 - - - - - 0.03 - 100.64
    XL-YK10-3 53.46 46.66 - 0.03 0.04 - - - - - - - 100.20
    XL-YK10-4 53.39 46.59 - 0.02 0.06 - 0.03 - - - - - 100.08
    XL-YK11-1 53.41 46.39 - - 0.04 - - - 0.03 - - - 99.88
    XL-YK11-2 53.29 46.12 - - 0.02 - - - - - - - 99.43
    XL-YK11-3 53.59 46.45 - - 0.09 - - - 0.01 - 0.02 - 100.17
    XL-YK11-6 53.33 45.94 0.09 0.02 0.07 0.04 - - - - - - 99.49
    XL-YK11-8 53.64 46.46 - - 0.04 - - - - - - - 100.14
    XL-YK11-11 53.04 45.91 - - 0.06 - 0.02 - - - - - 99.04
    XL-YK12-1 53.78 46.78 - - 0.06 0.02 - 0.03 - - 0.03 - 100.70
    XL-YK12-2 53.63 46.88 - - 0.04 0.05 0.03 - - - 0.02 0.02 100.67
    XL-YK12-3 53.45 46.72 0.04 - 0.06 - 0.02 - - - - - 100.31
    XL-YK12-4 53.61 46.49 - 0.02 0.04 0.01 - - - - - - 100.18
    注:表中“-”代表低于电子探针分析测试检测限。
    下载: 导出CSV
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出版历程
收稿日期:  2021-11-26
修回日期:  2022-03-07
录用日期:  2022-03-14
刊出日期:  2022-11-28

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