碳酸盐矿物中稀土元素分馏特征及其获取方法研究进展

王意茹; 武晓郯; 何静; 李崇瑛

doi:10.15898/j.cnki.11-2131/td.202204180081

碳酸盐矿物中稀土元素分馏特征及其获取方法研究进展

成都理工大学材料与化学化工学院，四川成都 610059

基金项目:
国家自然科学基金项目“碳酸盐岩中碳酸盐矿物的稀土元素分析方法研究”(41573014)

详细信息

作者简介: 王意茹，硕士研究生，研究方向为矿产资源化学与地球化学。E-mail: wangyiru@stu.cdut.edu.cn

通讯作者: 李崇瑛，硕士，教授，研究方向为分析化学、矿产资源化学与地球化学。E-mail: lichy@cdut.edu.cn

中图分类号: O614.33; O657.63

收稿日期: 2022-04-18

修回日期: 2022-05-30

录用日期: 2022-07-29

刊出日期: 2022-11-28

A Review of Research Progress on Fractionation Characteristics and Acquisition Methods of Rare Earth Elements in Carbonate Minerals

School of Materials and Chemistry and Chemical Engineering, Chengdu University of Technology, Chengdu 610059, China

More Information

Corresponding author: LI Chongying, lichy@cdut.edu.cn

Received Date: 18 April 2022

Revised Date: 30 May 2022

Accepted Date: 29 July 2022

Publish Date: 28 November 2022

摘要

摘要:
古地表水中自生沉积的碳酸盐矿物能够较完整地保留沉积时水体稀土元素的分馏特征，这些特征主要受水体环境条件的影响，因此可以作为沉积水体古环境信息的良好指标。本文根据前人研究，综述了古地表水pH、盐度、溶氧量和热液输入等环境因素对稀土元素分馏特征的影响，总结了碳酸盐矿物稀土元素分馏特征示踪沉积水体古环境信息和主要获取碳酸盐矿物中稀土元素分馏特征信息的方法。目前，激光剥蚀电感耦合等离子体质谱法(LA-ICP-MS)和酸溶-电感耦合等离子体质谱法是主要的获取碳酸盐矿物中稀土元素分馏特征的分析方法。单纯只含碳酸盐矿物的样品较少见，出露地表的通常是碳酸盐岩，其在形成过程中会不可避免地混入陆源矿物(如黏土、石英、长石等)和自生沉积的非碳酸盐矿物，这些矿物带入的稀土元素会扰乱碳酸盐矿物中原始稀土元素分馏特征，而这两种方法均未能找到有效地避免这些非碳酸盐矿物干扰的途径。因此，未来稀土元素分馏特征示踪古环境信息的研究首先应该探究能准确获取碳酸盐岩中碳酸盐矿物稀土元素分馏特征的方法。
- 碳酸盐矿物 /
- 稀土元素 /
- 激光剥蚀电感耦合等离子体质谱法 /
- 分馏特征
Abstract: BACKGROUND
Authigenic carbonate minerals deposited from paleo-surface water can retain the fractionation characteristics of rare earth elements in water when deposited. The environmental conditions of the water at the time affect these characteristics. Therefore, these characteristics can be used as a reliable indicator for the paleo-environmental information of deposited water.
OBJECTIVES
Based on previous studies, the influence of pH, salinity, dissolved oxygen and hydrothermal input of paleo-surface water on the fractionation characteristics of rare earth elements are reviewed, and the methods of tracing the paleo-environment information and obtaining the characteristics information of rare earth elements in carbonate minerals are summarized.
METHODS
At present, laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) and acid dissolution-inductively coupled plasma-mass spectrometry are the mainstream analytical methods used to obtain the fractionation characteristics of rare earth elements in carbonate minerals.
RESULTS
It is rare to find samples that only contain carbonate minerals, so samples are usually carbonate rocks exposed on the earth's surface. However, carbonate rocks have been inevitably mixed with terrigenous minerals (such as clay, quartz, feldspar) and authigenic non-carbonate minerals during their formation, which will disturb the original rare earth elements fractionation characteristics of the carbonate minerals. Unfortunately, neither method mentioned earlier was successful in avoiding this interference.
CONCLUSIONS
The future study on the fractionation characteristics of rare earth elements should first explore the methods to accurately obtain the fractionation characteristics of carbonate minerals in carbonate rocks.
- carbonate minerals /
- rare earth elements /
- laser ablation inductively coupled plasma-mass spectrometry /
- fractionation characteristics

HTML全文

图 1 常见地表水稀土元素配分模式图(据赵彦彦等^[39]和Fee等^[48]修改)

Figure 1.

下载: 全尺寸图片幻灯片

表 1 各类地表水稀土元素分馏特征

Table 1. Fractionation characteristics of rare earth elements in various surface waters

地表水	稀土元素分馏特征				参考文献
地表水	稀土元素配分模式	La异常值	Ce异常值	Y/Ho	参考文献
海水	HREE相对富集	> 3	负异常	44~74	Liang等^[36]，Rieger等^[55]，施泽进等^[60]
河水	平坦型	< 2	轻微负异常	25~28	Zhao等^[46]，Kamber等^[61]，Goldstein等^[62]
湖水	MREE相对富集或平坦型	—	无明显异常现象	—	赵彦彦等^[39]，Johannesson等^[41]，Fee等^[48]
注：因湖泊存在淡水湖和盐湖，稀土元素分馏特征较复杂，La异常值与Y/Ho值变化较大。

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参考文献(82)

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