碳酸盐晶格硫研究进展

李鑫; 曹红; 耿威; 孙治雷; 张喜林; 闫大伟; 秦双双; 徐翠玲; 张现荣; 翟滨; 王利波

doi:10.16562/j.cnki.0256-1492.2019090801

碳酸盐晶格硫研究进展

1.
自然资源部天然气水合物重点实验室，中国地质调查局青岛海洋地质研究所，青岛 266071

2.
青岛海洋科学与技术试点国家实验室海洋矿产资源评价与探测技术功能实验室，青岛 266071

3.
中国地质大学（北京），北京 100083

4.
中国海洋大学，青岛 266100

基金项目: 国家自然科学基金“冲绳海槽海底冷泉—热液系统相互作用及资源效应（91858208）”，“西南印度洋龙旂热液区硫化物风化蚀变中元素的迁移和富集”（41606086）；青岛海洋科学与技术国家实验室开放基金“冲绳海槽弧后盆地热液金属硫化物的风化机理”（MMRZZ201809）；国家海洋局生物遗传重点实验室开放基金“微生物诱导下的热液金属硫化物风化机理”（HY201809）；中国地质调查局海洋地质调查二级项目（DD20190819）

详细信息

作者简介: 李鑫（1996—），男，硕士研究生，地球化学专业，E-mail：lixin74@163.com

通讯作者: 孙治雷（1975—），男，副研究员，主要从事深海矿产资源勘探与海洋地球化学研究，E-mail：zhileisun@yeah.net

中图分类号: P736.4

收稿日期: 2019-09-08

修回日期: 2019-11-05

刊出日期: 2020-06-25

Research progress in carbonate associated sulfate

1.
The Key Laboratory of Gas Hydrate, Ministry of Natural Resources, Qingdao Institute of Marine Geology, Qingdao 266071, China

2.
Laboratory for Marine Mineral Resources, Pilot National Laboratory for Marine Science and Technology (Qingdao), Qingdao 266071, China

3.
China University of Geosciences (Beijing), Beijing 100083, China

4.
Ocean University of China, Qingdao 266100, China

More Information

Corresponding author: SUN Zhilei, zhileisun@yeah.net

Received Date: 08 September 2019

Revised Date: 05 November 2019

Publish Date: 25 June 2020

摘要

摘要:
碳酸盐晶格硫（CAS）是古环境恢复的重要手段之一，它系指在碳酸盐成岩过程中微量的硫酸盐离子取代碳酸盐离子并保存在晶格中的硫酸盐。CAS对矿物沉淀发生时的海水硫酸根的氧、硫同位素组成、硫酸盐浓度和当时古环境的氧化还原状态都有很好的保存和记录作用，因此引发了对其持续关注，并开展了一系列卓有成效的研究。本文综述了CAS当前的研究进展，主要从前处理方法、影响因素、同位素组成和古环境恢复等重点问题来探讨CAS的成因和CAS对不同沉积环境的恢复应用，并展望了需要进一步研究的几点研究方向，希望借此能引起广大研究者的兴趣和重视。
- CAS /
- 前处理方法 /
- 硫-氧同位素 /
- 古环境恢复 /
- 冷泉
Abstract:
Carbonate associated sulfate, or CAS in brief, is one of the important indicators for paleoenvironmental restoration. Trace sulfate may enter carbonate lattice and replaces the carbonate during diagenesis. The CAS has the capability to preserve the isotopic composition of seawater sulfate and to record the sulfate concentration of seawater, as well as the changes in the paleoenvironment. In recent years, CAS has attracted great interest and attention from the geological society. In this paper, attempt has been made to address CAS with emphases on its pre-treatment methods, influencing factors, isotopic composition and its significance in paleoenvironmental reconstruction. The application of CAS to the restoration of different sedimentary environments is discussed, in addition to the future research directions. We hope that the introduction may raise interests and attentions from researchers.
- CAS /
- pretreatment method /
- sulfur-oxygen isotopes /
- paleoenvironmental reconstruction /
- cold seep

HTML全文

图 1 δ³⁴S_CAS和δ¹⁸O_CAS相关性分布图（数据来自文献[25]）

Figure 1.

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图 2 CAS提取推荐流程图（CAS是碳酸盐晶格硫，CRS是铬还原性硫^{[2, 31]}）

Figure 2.

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图 3 CAS浓度和安提科斯提岛各物种同位素组成投点图^[57]

Figure 3.

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图 4 墨西哥湾δ¹⁸O_CAS和δ³⁴S_CAS斜率配分图（黑色十字SW代表现代海水同位素组成^[48]）

Figure 4.

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图 5 现代不同地区海底δ¹⁸O_CAS和δ³⁴S_CAS斜率配分图（红色为文石，绿色为方解石^[48]）

Figure 5.

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图 6 CAS高分辨率硫同位素地层学研究^{[64, 74-75]}

Figure 6.

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图 7 沃克湖1900―1995年的硫酸盐浓度^[82]

Figure 7.

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图 8 沃克湖CAS和沃克湖硫酸盐浓度斜率配分图^[82]

Figure 8.

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表 1 一些典型的CAS提取方法

Table 1. Typical methods of extraction of CAS

样本时代	采样地点	主要的实验步骤	碳酸盐岩类型	文献来源
寒武纪	美国伊利诺斯（Illinois）	样品粉末用去离子水冲洗两次，持续24 h，偶尔搅拌一下，而后小心的倒掉上层液体；把样品用4%NaClO溶液处理，混合好后，持续反应48 h，并伴随偶尔的搅拌；样品再用去18 MΩ离子水冲洗两次	—	[32]
古生代和中生代	—	直接用NaCl进行处理	生物成因碳酸盐岩和微晶方解石	[1]
新元古代晚期	中国宜昌市	50 g样品直接放到200 mLHCl(6 mol/L)，12 h，过滤；加入5 g/(NH₄)₂(OH)Cl(1%)和两滴甲基橙，用NH₄OH和盐酸调节pH，至溶液变为红色的	—	[30]
震旦纪晚期	纳米比亚（Namibia）	将样品浸入10%NaCl溶液中，5次，持续24 h，并且不停的搅拌，每次取出后用去离子水冲洗3次	含硅质碎屑的碳酸盐岩	[33]
上三叠纪	阿尔卑斯山脉东部和南部	把样品浸入到10%NaCl溶液中搅拌24 h，过滤	—	[34]
古生代		去离子水浸泡24～36 h	—	[35]
元古代	中国天津蓟县	在5.25%NaClO中冲洗24 h，然后用蒸馏水冲洗	—	[29]
古生代	比利时乌拉尔山脉、北美中部和内华达州	用去离子水淋洗两次，每次持续24 h；再用4% NaClO溶液处理48 h	—	[36]

下载: 导出CSV

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碳酸盐晶格硫研究进展

作者简介: 李鑫（1996—），男，硕士研究生，地球化学专业，E-mail：lixin74@163.com

通讯作者: 孙治雷（1975—），男，副研究员，主要从事深海矿产资源勘探与海洋地球化学研究，E-mail：zhileisun@yeah.net

Research progress in carbonate associated sulfate

Corresponding author: SUN Zhilei, zhileisun@yeah.net

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