两种赤泥对宁夏煤灰熔融温度的影响

温艳. 两种赤泥对宁夏煤灰熔融温度的影响[J]. 矿产综合利用, 2023, 44(6): 141-145, 153. doi: 10.3969/j.issn.1000-6532.2023.06.021
引用本文: 温艳. 两种赤泥对宁夏煤灰熔融温度的影响[J]. 矿产综合利用, 2023, 44(6): 141-145, 153. doi: 10.3969/j.issn.1000-6532.2023.06.021
Wen Yan. Influence of Two Kinds of Red Mud on the Melting Temperature of Coal Ash in Ningxia[J]. Multipurpose Utilization of Mineral Resources, 2023, 44(6): 141-145, 153. doi: 10.3969/j.issn.1000-6532.2023.06.021
Citation: Wen Yan. Influence of Two Kinds of Red Mud on the Melting Temperature of Coal Ash in Ningxia[J]. Multipurpose Utilization of Mineral Resources, 2023, 44(6): 141-145, 153. doi: 10.3969/j.issn.1000-6532.2023.06.021

两种赤泥对宁夏煤灰熔融温度的影响

  • 基金项目: 2020年度宁夏高等学校科学研究项目:碱土金属修饰的CuFe2SO4复合载氧体煤/生物质化学链气化制氢特性研究(NGY2020154)
详细信息
    作者简介: 温艳(1977-),女,硕士,副教授,主要研究方向为煤化工工艺
  • 中图分类号: TD985

Influence of Two Kinds of Red Mud on the Melting Temperature of Coal Ash in Ningxia

  • 这是一篇冶金工程领域的论文。在宁夏煤中按照一定比例分别添加拜耳赤泥和烧结赤泥,研究这两种不同的赤泥对宁夏煤灰熔融温度的影响,采用Factsage软件研究了灰熔融温度改变机理。实验结果表明,宁夏煤灰矿物质中含有大量的莫来石,导致其煤灰的灰熔点较高,向其中加入赤泥能够有效地降低煤灰熔点。随着拜耳赤泥添加量的增加,煤灰中的莫来石的成分逐步减少,而钙长石与钠长石逐步增多,降低了煤灰的熔融温度。随烧结赤泥添加量的增加煤灰中莫来石的含量逐渐减少,长石的含量逐渐增多。赤泥使宁夏煤灰熔融温度降低的主要原因是由于赤泥中的碱性氧化物与煤灰中的酸性氧化物发生反应生成了低熔点的矿物质以及这些矿物质之间相互作用生成了低温共熔物。

  • 加载中
  • 图 1  烧结赤泥对宁夏煤灰熔融特性的影响

    Figure 1. 

    图 2  拜耳赤泥对宁夏煤灰熔融特性的影响

    Figure 2. 

    图 3  宁夏煤灰的在高温下矿物质含量与温度的关系

    Figure 3. 

    图 4  烧结赤泥与宁夏煤灰混合后矿物质含量与温度的关系

    Figure 4. 

    图 5  拜耳赤泥与宁夏煤灰混合后矿物质含量与温度的关系

    Figure 5. 

    表 1  宁夏煤灰及赤泥成分分析/%

    Table 1.  Compositional analysis of coal ash and red mud in Ningxia

    成分SiO2Al2O3Fe2O3CaOMgOK2ONa2OSO2TiO2P2O5
    宁夏煤灰47.4337.693.192.740.280.270.300.791.170.14
    拜耳赤泥33.2927.748.8915.400.640.177.010.975.490.40
    烧结赤泥36.115.796.7841.091.780.272.830.874.100.38
    下载: 导出CSV
  • [1]

    南相莉, 张廷安, 刘燕, 等. 我国赤泥综合利用分析[J]. 过程工程学报, 2010, 10(Z1):264-270. NAN X L, ZHANG T A, LIU Y, et al. Analysis of comprehensive utilisation of red mud in China[J]. Journal of Process Engineering, 2010, 10(Z1):264-270.

    NAN X L, ZHANG T A, LIU Y, et al. Analysis of comprehensive utilisation of red mud in China[J]. Journal of Process Engineering, 2010, 10(Z1): 264-270.

    [2]

    陈玉爽, 张忠孝, 乌晓江, 等. 配煤对煤灰熔融特性影响的实验与量化研究[J]. 燃料化学学报, 2009, 37(5):521-526. CHEN Y S, ZHANG Z X, WU X J, et al. Experimental and quantitative study of the effect of coal blending on the melting characteristics of coal ash[J]. Journal of Fuel Chemistry, 2009, 37(5):521-526.

    CHEN Y S, ZHANG Z X, WU X J, et al. Experimental and quantitative study of the effect of coal blending on the melting characteristics of coal ash[J]. Journal of Fuel Chemistry, 2009, 37(5): 521- 526.

    [3]

    乌晓江, 张忠孝, 徐雪元, 等. 宁夏煤气化特性及灰渣熔融特性的研究[J]. 动力工程学报, 2011, 31(7):558-562. WU X J, ZHANG Z X, XU X Y, et al. Study on the characteristics of coal gasification and the melting characteristics of ash in Ningxia[J]. Journal of Power Engineering, 2011, 31(7):558-562.

    WU X J, ZHANG Z X, XU X Y, et al. Study on the characteristics of coal gasification and the melting characteristics of ash in Ningxia[J]. Journal of Power Engineering, 2011, 31(7): 558-562.

    [4]

    Brown R, Liu Q, Norton G. Catalytic effects observed during the co-gasification of coal and switchgrass[J]. Biomass and Bioenergy, 2017, 18(6):499-506.

    [5]

    谢良才, 李风海, 薛兆民, 等. 配煤对高熔点煤灰熔融特性影响的研究[J]. 燃料化学学报, 2016, 44(12):1430-1439. XIE L C, LI F H, XUE Z M, et al. Study on the effect of coal blending on the melting characteristics of high melting point coal ash[J]. Journal of Fuel Chemistry, 2016, 44(12):1430-1439.

    XIE L C, LI F H, XUE Z M, et al. Study on the effect of coal blending on the melting characteristics of high melting point coal ash[J]. Journal of Fuel Chemistry, 2016, 44(12): 1430- 1439.

    [6]

    沈铭科, 邱坤赞, 黄振宇, 等. 准东煤掺烧高岭土对固钠率及灰熔融特性影响研究[J]. 燃料化学学报, 2015, 43(9):1044-1051. SHEN M K, QIU K Z, HUANG Z Y, et al. Study on the effect of kaolin blended with Jundong coal on sodium fixation rate and ash melting characteristics[J]. Journal of Fuel Chemistry, 2015, 43(9):1044-1051.

    SHEN M K, QIU K Z, HUANG Z Y, et al. Study on the effect of kaolin blended with Jundong coal on sodium fixation rate and ash melting characteristics[J]. Journal of Fuel Chemistry, 2015, 43(9): 1044- 1051.

    [7]

    蒋武锋, 马腾飞, 郝素菊, 等. 利用钢渣余热还原含锌粉尘可行性的探讨[J]. 矿产综合利用, 2019(6):140-144. JIANG W F, MA T F, HAO S J, et al. Discussion on feasibility of reducing zinc-containing dust by residual heat of steel slag[J]. Multipurpose Utilization of Mineral Resources, 2019(6):140-144. doi: 10.3969/j.issn.1000-6532.2019.06.030

    JIANG W F, MA T F, HAO S J, et al. Discussion on feasibility of reducing zinc-containing dust by residual heat of steel slag[J]. Multipurpose Utilization of Mineral Resources, 2019(6): 140-144. doi: 10.3969/j.issn.1000-6532.2019.06.030

    [8]

    Fenghai Li, Quanrun Liu, Meng Li, et al. Understanding fly-ash formation during fluidized-bed gasification of high-silicon-aluminum coal based on its characteristics[J]. Energy, 2018, 150:110-115.

    [9]

    王志, 韩敏芳, 张以河, 等. 拜耳法赤泥的湿法碳化脱碱工艺研究[J]. 硅酸盐通报, 2013, 32(9):1851-1855. WANG Z, HAN M F, ZHANG Y H, et al. Research on wet carbonisation and dealkalisation process of Bayer red mud[J]. Silicate Bulletin, 2013, 32(9):1851-1855. doi: 10.16552/j.cnki.issn1001-1625.2013.09.043

    WANG Z, HAN M F, ZHANG Y H, et al. Research on wet carbonisation and dealkalisation process of Bayer red mud[J]. Silicate Bulletin, 2013, 32(9): 1851-1855. doi: 10.16552/j.cnki.issn1001-1625.2013.09.043

    [10]

    乌晓江, 张忠孝, 朴桂林, 等. 配煤对降低高灰熔融性煤的三元相图分析[J]. 洁净煤技术, 2007(3):64-67. WU X J, ZHANG Z X, PU G L, et al. Ternary phase diagram analysis of coal blending for reducing high ash fusibility coals[J]. Clean Coal Technology, 2007(3):64-67. doi: 10.3969/j.issn.1006-6772.2007.03.016

    WU X J, ZHANG Z X, PU G L, et al. Ternary phase diagram analysis of coal blending for reducing high ash fusibility coals[J]. Clean Coal Technology, 2007(3): 64-67. doi: 10.3969/j.issn.1006-6772.2007.03.016

  • 加载中

(5)

(1)

计量
  • 文章访问数:  840
  • PDF下载数:  98
  • 施引文献:  0
出版历程
收稿日期:  2021-04-24
刊出日期:  2023-12-25

目录