青海都兰县阿斯哈石英闪长岩岩石地球化学、锆石U-Pb年龄与Hf同位素特征

岳维好, 周家喜. 青海都兰县阿斯哈石英闪长岩岩石地球化学、锆石U-Pb年龄与Hf同位素特征[J]. 地质通报, 2019, 38(2-3): 328-338.
引用本文: 岳维好, 周家喜. 青海都兰县阿斯哈石英闪长岩岩石地球化学、锆石U-Pb年龄与Hf同位素特征[J]. 地质通报, 2019, 38(2-3): 328-338.
YUE Weihao, ZHOU Jiaxi. Geochemistry, zircon U-Pb age and Hf isotopic characteristics of the Asiha diorite in Dulan County, Qinghai Province[J]. Geological Bulletin of China, 2019, 38(2-3): 328-338.
Citation: YUE Weihao, ZHOU Jiaxi. Geochemistry, zircon U-Pb age and Hf isotopic characteristics of the Asiha diorite in Dulan County, Qinghai Province[J]. Geological Bulletin of China, 2019, 38(2-3): 328-338.

青海都兰县阿斯哈石英闪长岩岩石地球化学、锆石U-Pb年龄与Hf同位素特征

  • 基金项目:
    国家自然科学基金项目《滇中碳酸盐型铅锌矿床流体混合成矿机理研究》(批准号:41272111)和山东黄金集团基本科研业务费专项基金项目《青海东昆仑东段沟里地区金矿(化)集区多元成矿信息融合与高效勘查示范研究》(编号:201122010100)
详细信息
    作者简介: 岳维好(1978-), 男, 博士, 高级工程师, 从事矿产地质及综合信息成矿预测方面的教学和科研工作。E-mail:137053132@qq.com
  • 中图分类号: P588.12+2;P597+.3

Geochemistry, zircon U-Pb age and Hf isotopic characteristics of the Asiha diorite in Dulan County, Qinghai Province

  • 都兰县阿斯哈石英闪长岩体呈岩基状产出。闪长岩全岩样品具有低SiO2(56.82%~61.15%)、富碱(Na2O+K2O为5.31%~6.02%)、低TFeO(6.09%~6.65%)和低TiO2(1.02%~1.25%)含量特征,属高钾钙碱性系列岩石。岩石中Cr(24.6×10-6~47.6×10-6)和Ni(12.8×10-6~17.6×10-6)含量不高,K、Ba、Rb、Th、U等大离子亲石元素富集,而Nb、Ta、P、Ti等高场强元素亏损,具有岛弧或活动大陆边缘弧岩浆的特征。用LA-ICP-MS测得锆石206Pb/238U年龄为232.6±1.4Ma,表明岩体为中三叠世形成。锆石具有明显偏低的εHft)值(-3.71~-0.84,平均为-2.31,t=232.6Ma)和偏老的t2DM年龄(1.32~1.50Ga,平均为1.41Ga),表明岩浆来源于古老地壳物质的熔融,很可能为研究区中元古代俯冲地壳物质。阿斯哈石英闪长岩的源区具有壳-幔混合特征,是幔源基性岩浆与古老壳源花岗质岩浆混合作用的产物,岩石形成于中三叠世晚期俯冲向碰撞转换的动力学背景下,代表东昆仑晚古生代—早中生代造山过程的岩浆记录。

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  • 图 1  东昆仑东段阿斯哈金矿区地质图[1]

    Figure 1. 

    图 图版Ⅰ   

    Figure 图版Ⅰ. 

    图 2  阿斯哈石英闪长岩SiO2-K2O图解(a, 底图据参考文献[24])和A/CNK-A/NK图解(b, 底图据参考文献[25])

    Figure 2. 

    图 3  阿斯哈石英闪长岩稀土元素球粒陨石标准化配分图(a, 标准化值据参考文献[26])和微量元素原始地幔标准化蛛网图(b, 标准化值据参考文献[27])

    Figure 3. 

    图 4  阿斯哈石英闪长岩(ASH-08)锆石阴极发光图像和锆石U-Pb同位素年龄

    Figure 4. 

    图 5  阿斯哈石英闪长岩锆石U-Pb谐和图(a)和年龄加权平均值直方图(b)

    Figure 5. 

    图 6  阿斯哈石英闪长岩锆石εHf(t)直方图(a)和锆石U-Pb年龄-εHf(t)相关图(b)

    Figure 6. 

    图 7  阿斯哈石英闪长岩的R1-R2图解(底图据参考文献[34])

    Figure 7. 

    表 1  阿斯哈石英闪长岩主量、微量和稀土元素含量分析结果

    Table 1.  Major, trace and rare earth element content of the Asiha diorite

    样号 SiO2 TiO2 AI2O3 TFeO MnO MgO CaO Na2O K2O P2O5 烧失量 总量 A/CNK A/NK σ Mg# Be Sc V Cr Co
    ASH-11 56.82 1.17 15.67 6.65 0.08 6.25 6.02 3.19 2.83 0.14 1.12 99.94 0.81 1.89 2.62 63 2.09 13.3 130.0 32.0 165
    ASH-12 57.85 1.16 15.83 6.21 0.11 6.44 6.12 2.78 2.72 0.12 0.58 99.92 0.85 2.11 2.04 65 2.07 18.8 143.0 47.6 196
    ASH-13 60.11 1.02 16.03 6.45 0.09 4.74 5.37 3.11 2.44 0.17 0.49 100.02 0.91 2.07 1.80 57 2.23 13.1 101.0 26.7 136
    ASH-14 59.32 1.05 16.37 6.17 0.05 4.47 5.87 2.82 2.85 0.13 0.86 99.96 0.89 2.12 1.97 56 2.05 12.4 93.3 24.6 188
    ASH-15 60.79 1.25 15.34 6.57 0.08 4.05 5.81 3.13 2.18 0.20 0.61 100.01 0.85 2.04 1.58 52 2.00 15.2 111.0 26.8 144
    ASH-16 61.15 1.15 15.95 6.09 0.11 3.56 5.82 3.14 2.43 0.21 0.59 100.20 0.87 2.05 1.71 51 1.85 13.6 96.5 28.5 200
    ASH-17 60.08 1.07 15.98 6.53 0.12 4.73 5.33 3.15 2.41 0.10 0.57 100.07 0.91 2.05 1.81 56 2.04 16.5 105.0 36.3 124
    样号 Ni Cu Zn Ga Rb Sr Zr Nb Ba Hf Ta Pb Th U La Ce Pr Nd Sm Eu Gd
    ASH-11 16.3 23.5 95.4 21.03 72.8 504 47.32 10.4 493.74 1.52 0.60 15.65 8.40 2.59 25.4 49.1 5.80 21.0 4.03 1.22 3.43
    ASH-12 17.6 144.0 93.5 21.03 66.9 526 99.31 10.9 520.78 2.82 0.69 13.77 7.84 1.34 26.8 53.9 6.45 24.7 4.85 1.25 4.06
    ASH-13 15.4 30.0 96.7 19.93 88.7 448 76.43 10.7 668.00 2.55 0.73 18.10 11.40 1.99 35.2 66.3 7.45 27.2 5.10 1.14 4.49
    ASH-14 12.8 33.5 76.0 20.13 103.0 437 70.97 10.6 679.01 2.20 0.73 18.87 11.80 2.61 35.0 65.6 7.23 26.4 4.63 1.07 4.03
    ASH-15 13.9 35.7 98.4 20.43 91.9 505 74.87 11.1 669.00 2.44 0.74 20.32 9.90 1.62 35.0 64.8 7.26 26.6 4.89 1.17 4.41
    ASH-16 13.7 23.3 98.7 19.33 87.4 452 69.22 10.8 724.08 2.37 0.73 16.88 9.05 3.07 26.6 52.9 6.21 23.8 4.56 1.18 4.23
    ASH-17 16.3 17.1 75.9 20.63 74.9 491 89.08 12.9 445.66 2.83 0.92 12.77 10.60 1.75 26.9 54.1 6.41 24.7 4.89 1.22 4.31
    样号 Tb Dy Ho Er Tm Yb Lu Y SREE LREE HREE LREE
    /HREE
    (La/Yb)N 5Eu 5Ce
    ASH-11 0.56 2.96 0.57 1.64 0.23 1.46 0.22 15.6 117.62 106.55 11.07 9.62 12.48 0.98 0.95
    ASH-12 0.71 3.63 0.68 2.01 0.29 1.90 0.28 19.8 131.50 117.95 13.55 8.71 10.12 0.84 0.97
    ASH-13 0.7 3.69 0.69 2.11 0.30 1.99 0.27 20.1 156.64 142.39 14.24 10.00 12.69 0.71 0.95
    ASH-14 0.67 3.47 0.63 1.92 0.27 1.72 0.26 18.0 152.91 139.93 12.97 10.79 14.60 0.74 0.96
    ASH-15 0.68 3.50 0.65 1.91 0.27 1.80 0.26 18.7 153.2 139.72 13.48 10.37 13.95 0.75 0.94
    ASH-16 0.63 3.28 0.65 1.92 0.26 1.70 0.26 17.5 128.17 115.25 12.92 8.92 11.22 0.81 0.97
    ASH-17 0.72 3.57 0.71 2.08 0.28 1.88 0.29 19.2 132.06 118.22 13.84 8.54 10.26 0.79 0.98
    注:主量元素含量单位为%, 微量和稀土元素含量为10-6。A/CNK=摩尔(Al2O3)/(CaO+K2O+Na2O), A/NK=摩尔(Al2O3)/(K2O+Na2O), Mg#= 100×摩尔MgO/(MgO+FeO), TFeO指全铁
    下载: 导出CSV

    表 2  阿斯哈石英闪长岩(ASH-08)LA-ICP-MS锆石U-Th-Pb分析结果

    Table 2.  Zircon U-Th-Pb isotope compositions of the Asiha diorite sample (ASH-08) as measured by LA-ICP-MS technique

    测试
    点号
    元素含量/10-6 Th/U 同位素比值 年龄/Ma
    206Pb 232Th 238U 207Pb/206Pb 207Pb/235U 206Pb/238U 207Pb/206Pb 207Pb/235U 206Pb/238U
    01 18.6 109.7 131.4 0.83 0.0541 0.0024 0.2723 0.0092 0.0365 0.0006 374 95 244.5 7.4 231.2 3.6
    02 13.1 64.5 92.7 0.70 0.0544 0.0028 0.2730 0.0119 0.0364 0.0006 389 112 245.1 9.5 230.3 3.8
    03 11.3 46.6 77.9 0.60 0.0561 0.0029 0.2872 0.0126 0.0372 0.0006 455 112 256.3 9.9 235.1 3.9
    04 21.3 120.6 145.5 0.83 0.0564 0.0024 0.2890 0.0093 0.0372 0.0006 466 92 257.8 7.3 235.4 3.6
    05 18.1 101.5 124.2 0.82 0.0555 0.0024 0.2796 0.0095 0.0365 0.0006 433 95 250.3 7.5 231.2 3.6
    06 14.8 49.4 102.3 0.48 0.0532 0.0025 0.2682 0.0103 0.0365 0.0006 339 104 241.3 8.3 231.3 3.7
    07 11.4 56.1 79.1 0.71 0.0551 0.0028 0.2795 0.0118 0.0368 0.0006 417 109 250.3 9.3 232.8 3.8
    08 12.0 57.0 84.8 0.67 0.0519 0.0027 0.2604 0.0111 0.0364 0.0006 280 113 235.0 8.9 230.5 3.8
    09 12.0 47.2 82.9 0.57 0.0558 0.0028 0.2850 0.0115 0.0370 0.0006 445 106 254.6 9.1 234.3 3.8
    10 52.1 177.6 360.0 0.49 0.0527 0.0019 0.2650 0.0061 0.0365 0.0005 315 79 238.7 4.9 231.0 3.3
    11 19.0 95.8 129.7 0.74 0.0524 0.0024 0.2656 0.0095 0.0368 0.0006 302 100 239.1 7.6 232.8 3.6
    12 12.4 53.4 85.4 0.63 0.0540 0.0029 0.2747 0.0123 0.0369 0.0006 371 115 246.4 9.8 233.5 4.0
    13 18.1 86.8 126.4 0.69 0.0540 0.0025 0.2736 0.0103 0.0368 0.0006 370 102 245.5 8.2 232.7 3.7
    14 17.1 93.6 117.1 0.80 0.0543 0.0024 0.2758 0.0095 0.0368 0.0006 383 95 247.3 7.5 233.2 3.6
    15 12.7 62.9 85.7 0.73 0.0527 0.0029 0.2663 0.0123 0.0367 0.0006 314 119 239.7 9.9 232.1 3.9
    16 18.6 108.1 125.6 0.86 0.0539 0.0026 0.2729 0.0108 0.0367 0.0006 369 105 245.0 8.6 232.2 3.8
    17 40.8 184.0 275.5 0.67 0.0519 0.0019 0.2641 0.0065 0.0369 0.0006 280 82 238.0 5.2 233.7 3.4
    18 23.7 117.9 163.4 0.72 0.0529 0.0022 0.2676 0.0085 0.0367 0.0006 323 92 240.8 6.8 232.4 3.5
    19 24.5 135.9 163.7 0.83 0.0553 0.0022 0.2828 0.0084 0.0371 0.0006 423 88 252.8 6.7 234.8 3.5
    20 12.1 58.9 82.6 0.71 0.0514 0.0026 0.2611 0.0110 0.0369 0.0006 257 112 235.6 8.8 233.4 3.8
    21 18.9 108.2 132.8 0.81 0.0517 0.0025 0.2621 0.0102 0.0368 0.0006 271 106 236.3 8.2 232.9 3.7
    22 13.4 67.6 92.2 0.73 0.0515 0.0027 0.2615 0.0114 0.0368 0.0006 264 115 235.8 9.2 233.0 3.9
    23 21.4 119.5 146.8 0.81 0.0503 0.0021 0.2521 0.0078 0.0363 0.0006 210 93 228.3 6.4 230.0 3.5
    24 19.8 90.0 137.2 0.66 0.0499 0.0022 0.2524 0.0089 0.0367 0.0006 192 101 228.5 7.3 232.1 3.6
    25 39.1 188.2 264.9 0.71 0.0520 0.0019 0.2641 0.0065 0.0369 0.0006 284 82 238.0 5.3 233.3 3.4
    下载: 导出CSV

    表 3  阿斯哈石英闪长岩锆石原位Lu-Hf同位素组成

    Table 3.  Zircon in-situ Lu-Hf isotopic compositions of the Asiha diorite

    样号 176Yb/177Hf 176Lu/177Hf 176Hf/177Hf εHf(0) εHf(t) t2DM/Ga t2DM/Ga fLu/Hf
    01 0.024715 0.000602 0.282586 0.000013 -6.58 -1.57 0.46 0.93 1.37 -0.98
    02 0.019472 0.000471 0.282606 0.000013 -5.87 -0.84 0.46 0.90 1.32 -0.99
    03 0.032698 0.000769 0.282564 0.000016 -7.36 -2.37 0.57 0.97 1.42 -0.98
    04 0.028040 0.000654 0.282546 0.000012 -7.99 -2.99 0.42 0.99 1.46 -0.98
    05 0.044469 0.001124 0.282572 0.000012 -7.07 -2.14 0.42 0.97 1.40 -0.97
    06 0.031770 0.000744 0.282569 0.000013 -7.18 -2.19 0.46 0.96 1.41 -0.98
    07 0.015334 0.000389 0.282542 0.000015 -8.13 -3.09 0.53 0.99 1.46 -0.99
    08 0.017352 0.000417 0.282535 0.000016 -8.38 -3.34 0.57 1.00 1.48 -0.99
    09 0.027271 0.000638 0.282594 0.000017 -6.29 -1.29 0.60 0.92 1.35 -0.98
    10 0.015524 0.000376 0.282577 0.000018 -6.90 -1.85 0.64 0.94 1.38 -0.99
    11 0.037519 0.000899 0.282529 0.000017 -8.59 -3.63 0.60 1.02 1.50 -0.97
    12 0.023285 0.000563 0.282571 0.000013 -7.11 -2.09 0.46 0.95 1.40 -0.98
    13 0.024445 0.000574 0.282569 0.000014 -7.18 -2.16 0.50 0.96 1.40 -0.98
    14 0.022212 0.000522 0.282564 0.000016 -7.36 -2.33 0.57 0.96 1.41 -0.98
    15 0.020043 0.000476 0.282580 0.000015 -6.79 -1.76 0.53 0.94 1.38 -0.99
    16 0.034992 0.000796 0.282589 0.000016 -6.47 -1.49 0.57 0.93 1.36 -0.98
    17 0.040988 0.000968 0.282527 0.000015 -8.66 -3.71 0.53 1.03 1.50 -0.97
    18 0.021658 0.000502 0.282585 0.000015 -6.61 -1.59 0.53 0.93 1.37 -0.98
    19 0.015955 0.000373 0.282537 0.000011 -8.31 -3.27 0.39 1.00 1.47 -0.99
    20 0.057680 0.001296 0.282550 0.000016 -7.85 -2.95 0.57 1.00 1.45 -0.96
    21 0.036378 0.000808 0.282569 0.000017 -7.18 -2.20 0.60 0.96 1.41 -0.98
    22 0.028673 0.000641 0.282575 0.000017 -6.97 -1.96 0.60 0.95 1.39 -0.98
    注: t为样品形成年龄, 本文取232.6Ma; 现今球粒陨石和亏损地幔的176Hf/177Hf、176Lu/177Hf值分别为0.282772、0.03321和0.28325、0.03842[23]; λ=1.867×10-11 [29]
    下载: 导出CSV
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出版历程
收稿日期:  2017-09-23
修回日期:  2018-05-22
刊出日期:  2019-03-15

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