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云南临沧花岗岩离子吸附型稀土矿床地球化学特征及其成因讨论

张民, 何显川, 谭伟, 马灵涯, 赵甫峰. 2022. 云南临沧花岗岩离子吸附型稀土矿床地球化学特征及其成因讨论[J]. 中国地质, 49(1): 201-214. doi: 10.12029/gc20220112
引用本文: 张民, 何显川, 谭伟, 马灵涯, 赵甫峰. 2022. 云南临沧花岗岩离子吸附型稀土矿床地球化学特征及其成因讨论[J]. 中国地质, 49(1): 201-214. doi: 10.12029/gc20220112
ZHANG Min, HE Xianchuan, TAN Wei, MA Lingya, ZHAO Fufeng. 2022. Geochemical characteristics and genesis of ion-adsorption type REE deposit in the Lincang granite, Yunnan Province[J]. Geology in China, 49(1): 201-214. doi: 10.12029/gc20220112
Citation: ZHANG Min, HE Xianchuan, TAN Wei, MA Lingya, ZHAO Fufeng. 2022. Geochemical characteristics and genesis of ion-adsorption type REE deposit in the Lincang granite, Yunnan Province[J]. Geology in China, 49(1): 201-214. doi: 10.12029/gc20220112

云南临沧花岗岩离子吸附型稀土矿床地球化学特征及其成因讨论

  • 基金项目:
    广东省基础与应用基础研究重大项目(2019B030302013)、广东省矿物物理与材料研究开发重点实验室2020年度开放基金(广东省科技计划项目)(2020B1212060055)及中国地质调查局项目(DD20160016-19)联合资助
详细信息
    作者简介: 张民, 男, 1986年生, 硕士, 工程师, 从事矿床地球化学研究及固体矿产勘查等工作; E-mail: zhangmin1179@126.com
  • 中图分类号: P618.7

Geochemical characteristics and genesis of ion-adsorption type REE deposit in the Lincang granite, Yunnan Province

  • Fund Project: Supported by Guangdong Major Project of Basic and Applied Basic Research(No. 2019B030302013); the 2020 open fund of Guangdong Provincial Key Laboratory of Mineral Physics and Materials (Science and Technology Planning Project of Guangdong Province, China)(No. 2020B1212060055); Investigation and Evaluation of Fubang Rare Earth Mine in Lancang, Yunnan (DD20160016-19) about Chengdu Center of China Geological Survey
More Information
    Author Bio: ZHANG Min, male, born in 1986, master, geological engineer, engaged in mineral deposit geochemistry research and solid mineral exploration; E-mail: zhangmin1179@126.com .
  • 研究目的

    临沧花岗岩风化壳广布,离子吸附型稀土资源潜力巨大。加强对临沧花岗岩风化壳离子吸附型稀土相态特征、浸出率等矿床地球化学特征和成矿机制的研究有利于进一步促进该区离子吸附型稀土资源的找矿工作。

    研究方法

    本文选择临沧花岗岩中段地区,通过系统实施钻探工程,详细了解稀土成矿地质及矿床地球化学特征,并对其成因进行探讨。

    研究结果

    临沧花岗岩风化壳全风化层稀土全相及浸出相稀土元素分异强烈,配分曲线呈右倾平滑的"W"型,稀土矿石类型为轻稀土元素富集的混合型稀土矿;稀土矿体赋存在花岗岩风化壳的全风化层,品位变化由上至下呈现出"上低-下高"和"上高-下低"两种类型。

    结论

    下渗的酸性溶液携带从花岗岩副矿物中解离出来的稀土离子向下运移,在风化壳的全风化层富集成矿,由于半风化层和弱风化层黏土矿物和酸性溶液的急剧减少,稀土元素富集程度大大降低。

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  • 图 1  临沧花岗岩中段地质简图(底图据方良好等, 2017, 略修改)

    Figure 1. 

    图 2  研究区花岗岩风化带分层特征示意图

    Figure 2. 

    图 3  研究区全相稀土元素(a)和浸出相稀土元素(b)配分曲线

    Figure 3. 

    图 4  样品单元素浸出率分布图

    Figure 4. 

    图 5  样品全相(a)和浸出相(b)稀土氧化物百分比分布柱状图

    Figure 5. 

    图 6  钻孔ZK102及ZK72稀土元素全相和浸出相对比图

    Figure 6. 

    图 7  钻孔ZK102稀土单元素全相和浸出相对比图

    Figure 7. 

    图 8  钻孔ZK72稀土单元素全相和浸出相对比图

    Figure 8. 

    图 9  研究区离子吸附型稀土矿成矿模式简图

    Figure 9. 

    表 1  全相稀土元素组成及相关参数(10-6

    Table 1.  Composition and related parameters of all-phase REE(10-6)

    下载: 导出CSV

    表 2  浸出相稀土元素组成及相关参数(10-6

    Table 2.  Composition and related parameters of leaching-phase REE (10-6)

    下载: 导出CSV

    表 3  稀土单元素浸出率组成及相关参数(%)

    Table 3.  Composition of single element of leaching rate and related parameters (%)

    下载: 导出CSV
  • Aubert D, Stille P, Probst A. 2001. REE fractionation during granite weathering and removal by waters and suspended loads: Sr and Nd isotopic evidence[J]. Geochimica et Cosmochimica Acta, 65(3): 387-406. doi: 10.1016/S0016-7037(00)00546-9

    Chi Ruan, Dai Zuxu, Xu Zhigao, Wu Yuanxin, Wang Cunwen. 2006. Correlation analysis on partition of rare earth in ion-exchangeable phase from weathered crust ores[J]. Transactions of Nonferrous Metals Society of China, 16: 1421-1425. doi: 10.1016/S1003-6326(07)60031-4

    Chi Ruan, Tian Jun, Li Zhongjun, Peng Cui, Wu Yuanxin, Li Shirong, Wang Cunwen, Zhou Zhiang. 2005. Existing state and partitioning of rare earth on weathered ores[J]. Journal of Rare Earths, 23(6): 756-759. https://en.cnki.com.cn/Article_en/CJFDTOTAL-YXTB200506034.htm

    Chi Ruan, Tian Jun. 2006. The Weathering Crust Eluviation Type Rare Earth Mineral Chemical Metallurgy[M]. Beijing: Science Press, 55-63.

    Chi Ruan, Tian Jun. 2007. Review of weathered crust rare earth ore[J]. Journal of the Chinese Rare Earth Society, 25(6): 641-649(in Chinese with English abstract). https://www.researchgate.net/publication/284081443_Review_of_weathered_crust_rare_earth_ore

    Chi Ruan, Wang Dianzuo. 1996. The occurrence state of rare earth and selection of separation and enrichment technology in ore[J]. Rare Metal, 20(4): 241-245. (in Chinese with English abstract).

    Chen Binghui, Xu Wenlie, Huang Limei, Wu Fuhai, Liu Huhu. 2000. An experimental study on the effects of microbes and organic acids on dissolution of REE in the weathering crust of a granite[J]. Acta Scientiarum Naturalium Universitatis Sunyatseni, 39(4): 110-113(in Chinese with English abstract). https://en.cnki.com.cn/Article_en/CJFDTOTAL-ZSDZ200004024.htm

    Dao Junshan, Huang Junkun, Jia Kui, Zhang Weizuo. 2017. Analysis of the genesis of ore deposit in Yunnan Province, east of rare earth ion adsorption type[J]. World Nonferrous Metal, (3): 194, 196 (in Chinese with English abstract).

    Ding Jiayu, Deng Guoqin. 2013. Main problems in the current ionic adsorption rare earth exploration specifications and their amendment proposals[J]. Nonferrous Metals Science and Engineering, 4(4): 96-102(in Chinese with English abstract).

    Duddy I R. 1980. Redistribution and fractionation of rare earth and other elements in a weathering profile[J]. Chemical Geology, 30: 363-381. doi: 10.1016/0009-2541(80)90102-3

    DZ/T 0204-2002. 2002. Specifications for rare earth mineral exploration[S]. 40-41.

    Fang Lianghao, Yuan Daoyang, Shao Yanxiu, He Wengui, Liu Xingwang, Zhang Bo. 2013. Characteristics of Late Quaternary tectonic activity of middle-western segment of Heihe Fault in southwestern part of Yunnan Province[J]. China Earthquake Engineering Journal, 35(2): 342-353 (in Chinese with English abstract).

    Gouveia M A, Prudencio M I, Figueiredo M O. 1993. Behaviour of REE and other trace and major elements during weathering of granitic rocks, Evora, Portugal[J]. Chem. Geol., 107: 293-296. doi: 10.1016/0009-2541(93)90194-N

    Henderson P. 1984. Rare Earth Element Geochemistry[M]. Amsterdam: Elsevier, 346-365, 492-494.

    Kong Huilei, Dong Guochen, Mo Xuanxue, Zhao Zhidan, Zhu Dicheng, Wang Shuo, LI Rong, Wang Qiaolin. 2012. Petrogenesis of Lincang granites in Sanjiang area of western Yunnan Province: Constraints from geochemistry, zircon U-Pb geochronology and Hf isotope[J]. Acta Petrologica Sinica, 28(5): 1438-1452(in Chinese with English abstract).

    Land M, öhlander B, Ingri J, Thunberg J. 1999. Olid speciation and fractionation of rare earth elements in a spodosol profile from northern Sweden as revealed by sequential extraction[J]. Chemical Geology, 160: 121-138. doi: 10.1016/S0009-2541(99)00064-9

    Ma Yingjun, Huo Runke, Xu Zhifang, Zhang Hui, Liu Congqiang. 2004. REE behavior and influence factors during chemical weathering[J]. Advances in Earth Science, 19(1): 87-94(in Chinese with English abstract). http://www.adearth.ac.cn/EN/10.11867/j.issn.1001-8166.2004.01.0087

    Minarik L, Zigova A, Bendl J. 1998. The behaviour of rare earth elements and Y during the rock weathering and soil formation in the Ricany granite massif, central bohemia[J]. The Science of the Total Environment, 215(1/2): 101-111. https://www.sciencedirect.com/science/article/pii/S0048969798001132

    Mo Xuanxue, Shen Shangyue, Zhu Qinwen, Xu Tongrui, Wei Qirong, Tan Jin, Zhang Shuanglan Cheng Huilan. 1998. Volcanics-ophiolite and Mineralization of Middle-southern Part in Shanjiang Area of Southwestern China[M]. Beijing: Geological Publishing House, 44-47 (in Chinese with English abstract).

    Nesbitt H W. 1979. Mobility and fractionation of rare earth elements during weathering of a granodiorite[J]. Nature, 279: 206-210. doi: 10.1038/279206a0

    Nesbitt H W, Wilson R E. 1992. Recent chemical weathering of basalts[J]. American Journal of Science, 292: 740-777. doi: 10.2475/ajs.292.10.740

    Peng Touping, Wang Yuejun, Fan Weiming, Liu Dunyi, Shi Yuruo, Miao Laicheng. 2006. The SHRIMP zircon U-Pb dating of the felsic igneous rocks from southern Lancangjiang and its tectonic implications[J]. Science in China (Series D), 10: 123-132 (in Chinese).

    Taunton A E, Welch S A, Banfield J F. 2000. Microbial controls on phosphate and lanthanide distributions during granite weathering and soil formation[J]. Chemical Geology, 169: 371-382. doi: 10.1016/S0009-2541(00)00215-1

    Tian Jun, Yin Jingqun, Chen kaihong, Rao Guohua, Jiang Mintao, Chi Ruan. 2011. Extraction of rare earths from the leach liquor of the weathered crustelution-deposited rare earth ore with non-precipitation[J]. International Journal of Mineral Processing, 98(3/4): 125-131. https://www.sciencedirect.com/science/article/pii/S0301751610001547

    Tian Jun CRYJ. 2010. Leaching process of rare earths from weathered crust elution-deposited rare earth ore[J]. Transactions of Nonferrous Metals Society of China, (5): 892-896. https://www.sciencedirect.com/science/article/pii/S1003632609602326

    Wang Zhonggang, Yu Xueyuan, Zhao Zhenhua, 1989. Rare Earth Element Geochemistry[M]. Beijing: Science Press, 321-342(in Chinese with English abstract).

    Wang Denghong, Wang Ruijiang, Li Jiankang, Zhao Zhi, Yu Yang, Dai Jing jing, Chen Zhenhui, Li Dexian, Qu Wenjun, Deng Maochun, Fu Xiaofang, Sun Yan, Zhen Guodong. 2013. The progress in the strategic research and survey of rare earth, rare metal and rare- scattered elements mineral resources[J]. Geology in China, 40(2): 361-370(in Chinese with English abstract). https://www.sciencedirect.com/science/article/pii/S1359645418305858

    Wu Chengyu, Huang Dianhao. 1989. Ree geochemistry in the weathering process of ganites in Longnan County, Jiangxi Province[J]. Acta Geologica Sinica, 63(4): 349-362(in Chinese with English abstract).

    Zhao Ding, Wang Denghong, Wang Zhaozhao, Xiang Jie. 2014. The study on extraction of hyperspectral remote sensing information of ion-adsorbed rare earth deposits in Yunnan-Myanmar area[J]. Mineral Deposits, 33(Supp. ): 1205-1206(in Chinese with English abstract).

    Zhong Xiangxi. 2016. The Occurrence Characteristics and Leaching Rules of Different Weathering Degree Rare Earth Ores[D]. Ganzhou: Jiangxi University of Science and Technology, 4-5(in Chinese with English abstract).

    Zhang Min, LI Yang, He Xianchuan, Feng Junlong, Wang Hongkun, Du Jingang, Wang Shushan. 2018. The mineralization characteristics study of ion-absorption type REE deposits in the middle section of Lincang granite[J]. Sedimentary Geology and Tethyan Geology, 38(4): 37-47(in Chinese with English abstract).

    池汝安, 王淀佐. 1996. 矿石中稀土赋存状态与分选富集工艺选择[J]. 稀有金属, 20 (4): 241-245.

    池汝安, 田君. 2006. 风化壳淋积型稀土矿化工冶金[M]. 北京: 科学出版社, 55-63.

    池汝安, 田君. 2007. 风化壳淋积型稀土矿评述[J]. 中国稀土学报, 25(6): 641-649. doi: 10.3321/j.issn:1000-4343.2007.06.001

    陈炳辉, 徐文烈, 黄丽玫, 毋福海, 刘琥琥. 2000. 微生物及有机酸对风化壳中REE的溶出实验[J]. 中山大学学报(自然科学版), 39(4): 110-113. doi: 10.3321/j.issn:0529-6579.2000.04.025

    丁嘉榆, 邓国庆. 2013. 现行离子型稀土勘查规范存在的主要问题与修订建议[J]. 有色金属科学与工程, 4(4): 96-102.

    刀俊山, 黄俊坤, 贾奎, 张卫座. 2017. 云南省富东离子吸附型稀土矿矿床成因浅析[J]. 世界有色金属, (3): 194, 196.

    方良好, 袁道阳, 邵盐秀, 何文贵, 刘兴旺, 张波. 2013. 滇西南地区黑河断裂中西段晚第四纪构造活动特征[J]. 地震工程学报, 35(2): 342-353. doi: 10.3969/j.issn.1000-0844.2013.02.0342

    莫宣学, 沈上越, 朱勤文, 须同瑞, 魏启荣, 谭劲, 张双全, 程惠兰. 1998. 三江中南段火山岩-蛇绿岩与成矿[M]. 北京: 地质出版社, 44-47.

    彭头平, 王岳军, 范蔚茗, 刘敦一, 石玉若, 苗来成. 2006. 澜沧江南段早中生代酸性火成岩SHRIMP锆石U-Pb定年及构造意义[J]. 中国科学(D辑), 36(2): 123-132. https://www.cnki.com.cn/Article/CJFDTOTAL-JDXK200602001.htm

    孔会磊, 董国臣, 莫宣学, 赵志丹, 朱弟成, 王硕, 李荣, 王乔林. 2012. 滇西三江地区临沧花岗岩的岩石成因: 地球化学、锆石U-Pb年代学及Hf同位素约束[J]. 岩石学报, 28(5): 1348-1452.

    马英军, 霍润科, 徐志方, 张辉, 刘丛强. 2004. 化学风化作用中的稀土元素行为及其影响因素[J]. 地球科学进展, 19(1): 87-94. doi: 10.3321/j.issn:1001-8166.2004.01.012

    王中刚, 于学元, 赵振华. 1989. 稀土元素地球化学[M]. 北京: 科学出版社, 321-342.

    王登红, 王瑞江, 李建康, 赵芝, 于扬, 代晶晶, 陈郑辉, 李德先, 屈文俊, 邓茂春, 付小方, 孙艳, 郑国栋. 2013. 中国三稀矿产资源战略调查研究进展综述[J]. 中国地质, 40(2): 361-370. doi: 10.3969/j.issn.1000-3657.2013.02.001 http://geochina.cgs.gov.cn/geochina/ch/reader/view_abstract.aspx?file_no=20130201&flag=1

    吴澄宇, 黄典豪, 郭中勋. 1989. 江西龙南花岗岩风化壳中稀土元素的地球化学研究[J]. 地质学报, 63(4): 349-362. https://www.cnki.com.cn/Article/CJFDTOTAL-DZXE198904005.htm

    DZ/T 0204-2002. 2002. 稀土矿产地质勘查规范[S]. 40-41.

    赵汀, 王登红, 王钊钊, 向杰. 2014. 滇缅地区离子吸附型稀土矿高光谱遥感信息提取方法研究[J]. 矿床地质, 33(增刊): 1205-1206. https://www.cnki.com.cn/Article/CJFDTOTAL-KCDZ2014S1605.htm

    钟祥熙. 2016. 不同风化程度离子型稀土矿赋存特征及浸出规律研究[D]. 赣州: 江西理工大学, 4-5.

    张民, 李杨, 何显川, 冯俊龙, 郑瑶, 王宏坤, 杜金刚, 王书山. 2018. 滇西临沧花岗岩中段离子吸附型稀土矿成矿特征研究[J]. 沉积与特提斯地质, 38(4): 37-47. doi: 10.3969/j.issn.1009-3850.2018.04.004

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出版历程
收稿日期:  2019-10-16
修回日期:  2019-12-17
刊出日期:  2022-02-25

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