Dynamic characteristics and evolution mechanism of "goaf water" of coal mine in Shandi River Basin, Yangquan, Shanxi Province and its environmental effects on Niangziguan Spring Area
-
摘要:
研究目的 煤矿“老窑水”以分布范围广、隐蔽性强、污染程度重、自然净化慢、持续时间长等特点，成为后采煤时代严重威胁中国生态文明建设的重要制约因素。
研究方法 本文以山西省阳泉市山底河流域煤矿“老窑水”为研究对象，通过长系列水质和水量系统性监测，运用统计学方法系统分析了山底河流域老窑水的水量和水质动态特征及其演化机理，评估了“老窑水”对娘子关泉域岩溶水的环境效应。
研究结果 研究表明，山底河“老窑水”总出口pH值平均为3.58，TDS平均为4744 mg/L，SO42-平均为3327 mg/L；雨季地下水位上升后与采空区接触面积或体积增大和降雨量的影响滞后等是造成煤矿“老窑水”的流量与水化学特征指标电导率、SO42-浓度非线性相关的主要原因；煤系地层中黄铁矿的强氧化反应主要发生在地下水位季节变动带、包气带和地表；煤矿采空积水区的一定深度为还原环境，具备开展微生物法治理的条件；山底河煤矿“老窑水”出流后进入下游碳酸盐岩河段渗漏，对娘子关泉域岩溶水的渗漏补给量达7247.08 m3/d，水质差，是娘子关泉域岩溶地下水的重要污染源。
结论 山底河流域“老窑水”流量对降雨量的调蓄周期为半年；水化学特征指标与流量呈非线性相关，“老窑水”黄铁矿的强氧化反应主要发生在地下水位季节变动带、包气带和地表；“老窑水”出流后渗漏补给娘子关泉域达7247.08 m3/d，SO42-、Fe和Mn超标严重，对泉域岩溶水污染严重，急需开展煤矿“老窑水”的治理和废弃煤矿生态修复。
Abstract:This paper is the result of hydrogeological survey engineering.
Objective With the characteristics of wide distribution, concealment, heavy pollution, slow natural purification and long duration, the "goaf water" of coal mine has become an important restrictive factor that seriously threatens the construction of ecological civilization in China in the post coal mining era.
Methods Taking the goaf water of coal mine in Shandi River Basin of Yangquan City, Shanxi Province as the research object, this paper systematically analyzes the dynamic characteristics and evolution mechanism of water quantity and quality of goaf water in Shandi River Basin by using a long series of systematic monitoring of water quality and quantity, and statistical methods.
Results The results indicate that the average pH of the total outlet of "goaf water" in Shandi River is 3.58, the average TDS is 4744 mg/L, and the average SO42- is 3327 mg/L. After the rise of groundwater level in rainy season, the increase of contact area or volume and the lag of rainfall are the main reasons for the nonlinear correlation between the flow of goaf water and the conductivity and SO42- concentration of hydrochemical characteristic indexes. The strong oxidation reaction of pyrite in coal measure strata mainly occurs in the seasonal variation zone of groundwater level, aeration zone and surface. The certain depth of the gob ponding area of the coal mine is the reduction environment, which has the conditions for microbial treatment. After the "goaf water" flows out, the leakage recharge in the downstream carbonate section is 7247.08 m3/d, and the water quality is poor, which is an important pollution source of karst groundwater in Niangziguan Spring area.
Conclusions The regulation and storage period of "goaf water" flow to rainfall in Shandi river basin is half a year. The hydrochemical characteristic index is nonlinear related to the flow. The strong oxidation reaction of "goaf water" pyrite mainly occurs in the seasonal fluctuation zone of groundwater level, aeration zone and surface. After the "goaf water" flows out, the leakage recharge in the downstream carbonate section is 7247.08 m3/d, SO42-, Fe and Mn exceed the standard seriously, which is an important pollution source of karst groundwater in Niangziguan Spring area. It is urgent to carry out the treatment of "goaf water" in coal mines and the ecological restoration of abandoned coal mines.
-
-
表 1 各监测点月平均流量及水质现场测试结果统计表（2017.06—2020.12）
Table 1. Statistical table of monthly average flow and water quality field test results of each monitoring point (2017.06—2020.12)
下载: 导出CSV
表 2 流域水化学组分统计特征表（mg/L）
Table 2. Statistical characteristics of hydrochemical components in the Shandi River Basin (mg/L)
下载: 导出CSV
-
American Public Health Association, AWWA, Water Pollution Control Federation. 1978. Standard Methods for the Examination of Water and Wastewater(13) [M]. (Zhang Zenghui, Gu Zenan, Wang Weiyi, Yang Jianliu, Min Qiruo, Zhu Xinyuan translate). Beijing: China Architecture & Building Press.
Cheng Yi, Wu Lanzhen, Liu Fenggui, Shen Yanjun. 2022. Changes of stream flow and precipitation in the Upper Stream of Yellow River during the past 60 years[J]. Arid Land Geography, 45(4): 1022-1031 (in Chinese with English abstract).
China National Coal Association. 2023. Annual report on the development of coal industry in 2022 [EB/OL].
http://www.coalchina.org.cn/index.php?m=content&c=index&a=show&catid=464&id=146683 (in Chinese).Dogramaci Shawan, McLean Laura, Skrzypek Grzegorz. 2017. Hydrochemical and stable isotope indicators of pyrite oxidation in carbonate- rich environment; the Hamersley Basin, Western Australia[J]. Journal of Hydrology, 545: 288-298. doi: 10.1016/j.jhydrol.2016.12.009
Egon Campos Dos Santos, Juliana Cecília de Mendonça Silva, Hélio Anderson Duarte. 2016. Pyrite oxidation mechanism by oxygen in aqueous medium[J]. The Journal of Physical Chemistry, 120(5): 2760-2768.
Evangelou V P (Bill), Zhang Y L. 1995. A review: Pyrite oxidation mechanisms and acid mine drainage prevention[J]. Critical Reviews in Environmental Science and Technology, 25(2): 141-199.
Feng Haibo, Dong Shaogang, Zhang Tao, Li Yi, Liu Xiaobo, Li Zhengkui, Wang Chao. 2019. Evolution mechanism of a groundwater system in the opencast coalmine area in the typical prairie[J]. Hydrogeology & Engineering Geology, 46(1): 163-172(in Chinese with English abstract).
Gao Bo. 2019. Study on Occurrence and Biodegradation Mechanism of PAHs in Closed Coal Mine[D]. Xuzhou: China University of Mining and Technology (in Chinese with English abstract).
Guo Fang, Jiang Guanghui, Liu Shaohua, Tang Qingjia. 2018. Identifying source water compositions of karst water systems by quantifying the conductance frequency distribution of springs[J]. Advances in Water Science, 29(2): 245-251(in Chinese with English abstract).
Han Shuangbao, Li Fucheng, Wang Sai, Li Haixue, Yuan Lei, Liu Jingtao, Shen Haoyong, Zhang Xueqing, Li Changqing, Wu Xi, Ma Tao, Wei Shibo, Zhao Minmin. 2021. Groundwater resource and eco-environmental problem of the Yellow River Basin[J]. Geology in China, 48(4): 1001-1019 (in Chinese with English abstract).
Huang Shengzhi, Huang Qiang, Chang Jianxia, Leng Guoyong, Chen Yutong. 2016. Variations in precipitation and runoff from a multivariate perspective in the Wei River Basin, China[J]. Quaternary International, 440: 30-39.
Huo Jianguang, Zhao Chunhong, Liang Yongping, Wang Taoliang, Tang Chunlei, Wang Weitai, Shen Haoyong. 2015. Characteristic and cause analysis in the runoff- drainage area of Niangziguan spring[J]. Geological Science and Technology Information, 34(5): 147-152 (in Chinese with English abstract).
Juliana Aparecida Galhardi, Daniel Marcos Bonotto. 2016. Hydrogeochemical features of surface water and groundwater contaminated with acid mine drainage (AMD) in coal mining areas: A case study in southern Brazil[J]. Environmental Science and Pollution Research, 23(18): 18911-18927. doi: 10.1007/s11356-016-7077-3
Li Fengming, Wang Rujun, Wang Cunyu. 2004. Synthetically control and continuable development of resource exhausted mine area[J]. Coal Minging Technology, 9(3): 7-10 (in Chinese with English abstract).
Li Zehua, Shi Xiaogang, Tang Qiuhong, Zhang Yongqiang, Gao Huilin, Pan Xicai, Stephen J. Déryf, Zhou Ping. 2020. Partitioning the contributions of glacier melt and precipitation to the 1971-2010 runoff increases in a headwater basin of the Tarim River[J]. Journal of Hydrology, 583: 124579. doi: 10.1016/j.jhydrol.2020.124579
Liang Haoqian, Feng Qiyan, Zhou Lai, Ren Hujun, Li Xibin. 2019. Influence of water of abandoned coal mine on water environment of Yudong River Basin[J]. Research of Soil and Water Conservation, 26(6): 382-388 (in Chinese with English abstract).
Liang Yongping, Shen Haoyong, Zhao Chunhong, Wang Zhiheng, Tang Chunlei, Zhao Yi, Xie Hao, Shi Weizhi. 2021. Thinking and practice on the research direction of karst water in northern China[J]. Carsologica Sinica, 40(3): 363-380 (in Chinese with English abstract).
Liang Yongping, Shi Donghai, Li Chunji, Wang Weitai, Zhao Chunhong, Li Xiaofeng, Wei Yanhua, Xu Fengwei. 2011. Test and research on the relationship between runoff and leakage on a karst percolation zone[J]. Hydrogeology & Engineering Geology, 38(2): 19-26 (in Chinese with English abstract).
Liang Yongping, Zhao Chunhong, Tang Chunlei, Zhang Fawang. 2014. Hydrogeological and Environmental Geological Investigation and Demonstration in Northern Karst Area[R] (in Chinese).
Liu Qiang. 2018. Study on Formation Mechanism and Influence of Acid Water in the Old Goaf in Shandi River Basin of Yangquan City[D]. Taiyuan: Taiyuan University of Technology (in Chinese with English abstract).
Liu Yinxu, Liu Haihong, Jia Jiali, Yang An, Li Jun. 2019. Composition and distribution of dissolved nutrients in surface water of typical inland Rivers in Qinghai[J]. Earth and Environment, 47(5): 601-609 (in Chinese with English abstract).
Luo Yu, Qin Ningsheng, Zhou Bin, Li Jinjian, Wang Chunxue, Liu Jia, Pang Yishu. 2019. Runoff characteristics and hysteresis to precipitation in Tuotuo River Basin in source region of Yangtze River during 1961-2011[J]. Bulletion of Soil and Water Conservation, 39(2): 22-28 (in Chinese with English abstract).
Miao Deyu, Yi Peng. 2021. Trends of surface water quality in China from 2013 to 2018[J]. Water Resources and Power, 39(12): 62-64, 16 (in Chinese with English abstract).
National Bureau of Statistics. 2023. Statistical bulletin of national economic and social development of the People's Republic of China in 2022[EB/OL].
http://www.stats.gov.cn/sj/zxfb/202302/t20230228_1919011.html . (in Chinese).Oluwatosin A Onabule, Steve B Mitchell, Fay Couceiro. 2020. The effects of freshwater flow and salinity on turbidity and dissolved oxygen in a shallow Macrotidal estuary: A case study of Portsmouth Harbour[J]. Ocean & Coastal Management, 191: 105179.
Powell John D. 1988. Origin and influence of coal mine drainage on streams of the United States[J]. Environmental Earth Sciences, 11(2): 141-152.
Shi Weizhi, Zhao Chunhong, Liang Yongping, Han Zhantao, Xie Hao, Tang Chunlei. 2022. Cause analysis of low Ca/Mg value in acid mine drainage[J]. Carsologica Sinica. 41(4): 511-521 (in Chinese with English abstract).
Sun Wei, Ji Bin, Sultan Ahmed Khoso, Tang Honghu, Liu Runqing, Wang Li, Hu Yuehua. 2018. An extensive review on restoration technologies for mining tailings[J]. Environmental Science and Pollution Research, 25: 33911-33925. doi: 10.1007/s11356-018-3423-y
Tang Chunlei, Zheng Xiuqing, Liang Yongping, Zhang Fawang, Jing Ze. 2020. The hydraulic connection between Jinci and Pingquan in Taiyuan and its contribution to the reflow of Jinci spring[J]. Geology in China, 47(6): 1755-1764(in Chinese with English abstract).
Wang Fa, Chen Hongsong, Lian Jinjiao, Fu Zhiyong, Nie Yunpeng. 2020. Hydrological response of karst stream to precipitation variation recognized through the quantitative separation of runoff components[J]. Science of The Total Environment, 748: 142483. doi: 10.1016/j.scitotenv.2020.142483
Wang Taoliang, Zhao Chunhong, Liang Yongping, Huo Jianguang, Tang Chunlei, Wang Weitai, Shen Haoyong. 2015. Influence of surface water seepage on water quality in Niangziguan spring area[J]. Journal of China Hydrology, 35(5): 41-45 (in Chinese with English abstract).
Wang Zhiheng, Liang Yongping, Tang Chunlei, Shen Haoyong, Zhao Chunhong, Guo FangFang, Xie Hao, Zhao Yi. 2020. Ecological restoration pattern and quantitative evaluation of recirculation measures for northern discontinuous karst spring: A case study of Jinci Spring in Taiyuan City, Shanxi Province[J]. Geology in China, 47(6): 1726-1738(in Chinese with English abstract).
Xiao Youquan. 1982. Pollution and prevention of acid mine water [J]. Hydrogeology & Engineering Geology, (3): 7-9 (in Chinese).
Yue Mei, Zhao Fenghua, Ren Deyi. 2004. The environment geochemistry information of the coal mine acid mining drainage[J]. Coal Geology & Exploration, 32(3): 46-49 (in Chinese with English abstract).
Zhang Chunchao, Li Xiangquan, Hou Xinwei, Wang Zhenxing, Gao Ming, Gui Chunlei, Zuo Xuefeng. 2021. Water quality characteristics and evolution mechanisms of different types of goaf water in Jincheng coal mining area[J]. Journal of China Hydrology, 41(2): 94-100 (in Chinese with English abstract).
Zhang Jianli, Shen Zhaoli, Li Dongyan. 2020. Hydrochemical characteristics and formation mechanism of drainage water in coal mines of Zibo[J]. Geological Review, 46(3): 263-269 (in Chinese with English abstract).
Zhang Qiuxia, Zhou Jianwei, Kang Fengxin, Lin Shanghua, Wei Dong, Zhang Liming, Yuan Lei. 2016. Hydrodynamic analysis and isotope tracing for probing into groundwater pollution of Zibo mining area[J]. Environmental Science & Technology, 39(8): 116-122 (in Chinese with English abstract).
Zhang Qiuxia, Zhou Jianwei, Lin Shanghua, Wei Dong, Zhang Liming, Yuan Lei. 2015. Characteristics and causes of groundwater pollution after Hongshan-Zhaili mine closure in Zibo[J]. Safety and Environmental Engineering, 22(6): 23-28 (in Chinese with English abstract).
Zhang Tao, Li Yingzhi, Cai Wutian, Geng Tingting, Zhang Zhiyin, Bian Chao, Zhao Miao, Cai Yuemei. 2018. The variation characteristics of water electronic conductivity and influence factors in Niyang river basin[J]. Journal of Arid Land Resources and Environment, 32(4): 126-131 (in Chinese with English abstract).
Zhang Xiaobo, Li Xue, Gao Xubo. 2016. Hydrochemistry and coal mining activity induced karst water quality degradation in the Niangziguan karst water system, China[J]. Environmental Science and Pollution Research, 23(7): 6286-6299 doi: 10.1007/s11356-015-5838-z
Zhang Yuzhuo, Xu Zhimin, Zhang Li, Lü Weikui, Yuan Huiqing, Zhou Lijie, Gao Yating, Zhu Lulu. 2021. Hydrochemical characteristics and genetic mechanism of high TDS groundwater in Xinjulong Coal Mine[J]. Coal Geology & Exploration, 49(5): 52-62 (in Chinese with English abstract). doi: 10.1007/s12665-021-09823-z?utm_content=meta
Zhao Fenghua. 2005. Geochemistry of Acid Water in Coal Mine[M]. Beijing: China Coal Industry Publishing House (in Chinese).
Zhao Yuhua, Ye Yangfang, Liu Xuedong. 1997. Sulfate reducing bacteria and its influencing factors[J]. Environmental Pollution & Control, 19(5): 41-43 (in Chinese).
Zhong Zuoxing, Tang Minggao, Zhang Jianli. 1999. Influence of mining drainage of Zibo coal mines on quality of surface water and groundwater[J]. Earth Science Frontiers, 6(S1): 238-244 (in Chinese with English abstract).
Zhu Biao, Chem Xi, Zhang Zhicai, Peng Tao, Zhang Lechen, Chen Bo, Zhao Meigang. 2019. Characteristics of groundwater conductivity in dry season and water- rock interaction implications in a southwest Karst Basin[J]. Earth and Environment, 47(4): 459-463(in Chinese with English abstract).
成艺, 武兰珍, 刘峰贵, 沈彦俊. 2022. 黄河上游近60 a径流量与降水量变化特征研究[J]. 干旱区地理, 45(4): 1022-1031. https://www.cnki.com.cn/Article/CJFDTOTAL-GHDL202204003.htm
冯海波, 董少刚, 张涛, 李铱, 刘晓波, 李政葵, 王超. 2019. 典型草原露天煤矿区地下水环境演化机理研究[J]. 水文地质工程地质, 46(1): 163-172. https://www.cnki.com.cn/Article/CJFDTOTAL-SWDG201901022.htm
高波. 2019. 关闭煤矿多环芳烃的赋存特征及生物降解机理研究[D]. 徐州: 中国矿业大学.
郭芳, 姜光辉, 刘绍华, 汤庆佳. 2018. 利用泉水电导率频率分布辨别岩溶含水系统的水源组分[J]. 水科学进展, 29(2): 245-251. https://www.cnki.com.cn/Article/CJFDTOTAL-SKXJ201802013.htm
国家统计局. 2023. 中华人民共和国2022年国民经济和社会发展统计公报[EB/OL].
http://www.stats.gov.cn/sj/zxfb/202302/t20230228_1919011.html .韩双宝, 李甫成, 王赛, 李海学, 袁磊, 刘景涛, 申豪勇, 张学庆, 李长青, 吴玺, 马涛, 魏世博, 赵敏敏. 2021. 黄河流域地下水资源状况及其生态环境问题[J]. 中国地质, 48(4): 1001-1019. http://geochina.cgs.gov.cn/geochina/article/abstract/20210402?st=search
霍建光, 赵春红, 梁永平, 王桃良, 唐春雷, 王维泰, 申豪勇. 2015. 娘子关泉域径流-排泄区岩溶水污染特征及成因分析[J]. 地质科技情报, 34(5): 147-152. https://www.cnki.com.cn/Article/CJFDTOTAL-DZKQ201505023.htm
李凤明, 王儒军, 王存煜. 2004. 资源枯竭型矿区综合治理与可持续发展[J]. 煤矿开采, 9(3): 7-10. https://www.cnki.com.cn/Article/CJFDTOTAL-MKKC200403003.htm
梁浩乾, 冯启言, 周来, 任虎俊, 李曦滨. 2019. 鱼洞河流域废弃煤矿矿井水对水环境的影响[J]. 水土保持研究, 26(6): 382-388. https://www.cnki.com.cn/Article/CJFDTOTAL-STBY201906058.htm
梁永平, 申豪勇, 赵春红, 王志恒, 唐春雷, 赵一, 谢浩, 石维芝. 2021. 对中国北方岩溶水研究方向的思考与实践[J]. 中国岩溶, 40(3): 363-380. https://www.cnki.com.cn/Article/CJFDTOTAL-ZGYR202103001.htm
梁永平, 石东海, 李纯纪, 王维泰, 赵春红, 李晓峰, 魏燕花, 徐峰伟. 2011. 岩溶渗漏河段来水量与渗漏量间关系测试研究[J]. 水文地质工程地质, 38(2): 19-26. https://www.cnki.com.cn/Article/CJFDTOTAL-SWDG201102006.htm
梁永平, 赵春红, 唐春雷, 张发旺. 2014. 北方岩溶区水文地质环境地质调查示范[R].
刘强. 2018. 阳泉市山底河流域酸性老窑水形成机制及其影响研究[D]. 太原: 太原理工大学.
刘胤序, 刘海红, 贾佳丽, 杨安, 李军. 2019. 青海典型内陆河流域地表水溶解性养分组成及分布特征[J]. 地球与环境, 47(5): 601-609. https://www.cnki.com.cn/Article/CJFDTOTAL-DZDQ201905004.htm
罗玉, 秦宁生, 周斌, 李金建, 王春学, 刘佳, 庞轶舒. 2019. 长江源区沱沱河流域1961-2011年径流特征及其对降水的滞后效应[J]. 水土保持通报, 39(2): 22-28.0 https://www.cnki.com.cn/Article/CJFDTOTAL-STTB201902004.htm
美国公共卫生协会, 美国自来水协会, 水污染控制联合会. 1978. 水和废水标准检验法第13版[M]. (张曾譓, 顾泽南, 王维一, 杨建六, 闵奇若, 朱新源译). 北京: 中国建筑工业出版社.
苗得雨, 衣鹏. 2021. 2013-2018年我国地表水水质变化趋势分析[J]. 水电能源科学, 39(12): 62-64, 16. https://www.cnki.com.cn/Article/CJFDTOTAL-SDNY202112015.htm
石维芝, 赵春红, 梁永平, 韩占涛, 谢浩, 唐春雷. 2022. 煤矿酸性"老窑水" 低Ca/Mg成因机制[J]. 中国岩溶, 41(4): 511-521. https://www.cnki.com.cn/Article/CJFDTOTAL-ZGYR202204002.htm
唐春雷, 郑秀清, 梁永平, 张发旺, 景泽. 2020. 山西太原晋祠-平泉水力联系及对晋祠泉复流的贡献[J]. 中国地质, 47(6): 1755-1764. http://geochina.cgs.gov.cn/geochina/article/abstract/20200612?st=search
王桃良, 赵春红, 梁永平, 霍建光, 唐春雷, 王维泰, 申豪勇. 2015. 地表水渗漏对娘子关岩溶泉泉水水质的影响[J]. 水文, 35(5): 41-45. https://www.cnki.com.cn/Article/CJFDTOTAL-SWZZ201505008.htm
王志恒, 梁永平, 唐春雷, 申豪勇, 赵春红, 郭芳芳, 谢浩, 赵一. 2020. 北方断流岩溶大泉复流的生态修复模式与复流措施效果的定量评价——以山西太原晋祠泉为例[J]. 中国地质, 47(6): 1726-1738. http://geochina.cgs.gov.cn/geochina/article/abstract/20200610?st=search
肖有权. 1982. 试谈酸性矿坑水的污染与防治[J]. 水文地质工程地质, (3): 7-9. https://www.cnki.com.cn/Article/CJFDTOTAL-SWDG198203002.htm
岳梅, 赵峰华, 任德贻. 2004. 煤矿酸性水水化学特征及其环境地球化学信息研究[J]. 煤田地质与勘探, 32(3): 46-49. https://www.cnki.com.cn/Article/CJFDTOTAL-MDKT200403015.htm
张春潮, 李向, 侯新伟, 王振兴, 高明, 桂春雷, 左雪峰. 2021. 晋城矿区不同类型老空水水质特征及演化机理[J]. 水文, 41(2): 94-100. https://www.cnki.com.cn/Article/CJFDTOTAL-SWZZ202102017.htm
张建立, 沈照理, 李东艳. 2000. 淄博煤矿矿坑排水的水化学特征及其形成机理的初步研究[J]. 地质论评, 46(3): 263-269. https://www.cnki.com.cn/Article/CJFDTOTAL-DZLP200003007.htm
张秋霞, 周建伟, 康凤新, 林尚华, 魏东, 张黎明, 袁磊. 2016. 淄博煤矿区地下水污染水动力和同位素解析[J]. 环境科学与技术, 39(8): 116-122. https://www.cnki.com.cn/Article/CJFDTOTAL-FJKS201608019.htm
张秋霞, 周建伟, 林尚华, 魏东, 张黎明, 袁磊. 2015. 淄博洪山、寨里煤矿区闭坑后地下水污染特征及成因分析[J]. 安全与环境工程, 22(6): 23-28. https://www.cnki.com.cn/Article/CJFDTOTAL-KTAQ201506005.htm
张涛, 李颖智, 蔡五田, 耿婷婷, 张智印, 边超, 赵淼, 蔡月梅. 2018. 尼洋河流域不同水体电导率变化特征及影响因素[J]. 干旱区资源与环境, 32(4): 126-131. https://www.cnki.com.cn/Article/CJFDTOTAL-GHZH201804023.htm
张玉卓, 徐智敏, 张莉, 吕伟魁, 袁慧卿, 周丽洁, 高雅婷, 朱璐璐. 2021. 山东新巨龙煤矿区场地高TDS地下水水化学特征及成因机制[J]. 煤田地质与勘探, 49(5): 52-62. https://www.cnki.com.cn/Article/CJFDTOTAL-MDKT202105006.htm
赵峰华. 2005. 煤矿酸性水地球化学[M]. 北京: 煤炭工业出版社.
赵宇华, 叶央芳, 刘学东. 1997. 硫酸盐还原菌及其影响因子[J]. 环境污染与防治, 19(5): 41-43. https://www.cnki.com.cn/Article/CJFDTOTAL-HJWR199705013.htm
中国煤炭工业协会. 2023. 2022煤炭行业发展年度报告[EB/OL].
http://www.coalchina.org.cn/index.php?m=content&c=index&a=show&catid=464&id=146683 .钟佐燊, 汤鸣皋, 张建立. 1999. 淄博煤矿矿坑排水对地表水体的污染及对地下水水质影响的研究[J]. 地学前缘, 6(S1): 238-244. https://www.cnki.com.cn/Article/CJFDTOTAL-DXQY1999S1040.htm
朱彪, 陈喜, 张志才, 彭韬, 张乐辰, 陈波, 赵美刚. 2019. 西南喀斯特流域枯季地下水电导率特征及水-岩作用分析[J]. 地球与环境, 47(4): 459-463. https://www.cnki.com.cn/Article/CJFDTOTAL-DZDQ201904007.htm
-
图(10)
表(2)
计量
- 文章访问数: 1616
- PDF下载数: 98
- 施引文献: 0