辽东地区赛马碱性杂岩锆石U-Pb年龄、Hf同位素组成及其对构造背景的制约

杨凤超, 宋运红, 胥嘉, 顾玉超, 杨宏智. 2024. 辽东地区赛马碱性杂岩锆石U-Pb年龄、Hf同位素组成及其对构造背景的制约. 地质通报, 43(1): 76-85. doi: 10.12097/gbc.2021.12.042
引用本文: 杨凤超, 宋运红, 胥嘉, 顾玉超, 杨宏智. 2024. 辽东地区赛马碱性杂岩锆石U-Pb年龄、Hf同位素组成及其对构造背景的制约. 地质通报, 43(1): 76-85. doi: 10.12097/gbc.2021.12.042
YANG Fengchao, SONG Yunhong, XU Jia, GU Yuchao, YANG Hongzhi. 2024. Zircon U–Pb age, Hf isotope composition, and their constraints on tectonic setting of the Saima alkaling complex in the eastern Liaoning Province. Geological Bulletin of China, 43(1): 76-85. doi: 10.12097/gbc.2021.12.042
Citation: YANG Fengchao, SONG Yunhong, XU Jia, GU Yuchao, YANG Hongzhi. 2024. Zircon U–Pb age, Hf isotope composition, and their constraints on tectonic setting of the Saima alkaling complex in the eastern Liaoning Province. Geological Bulletin of China, 43(1): 76-85. doi: 10.12097/gbc.2021.12.042

辽东地区赛马碱性杂岩锆石U-Pb年龄、Hf同位素组成及其对构造背景的制约

  • 基金项目: 中国地质调查局项目《东北地区铜金稀有金属战略性矿产资源调查》(编号:DD20230028)和《辽宁甜水幅(K51E019015)、草河口幅(K51E019016)深部矿产地质调查》(编号: DD20190156-1)
详细信息
    作者简介: 杨凤超(1982− ),男,博士,正高级工程师,从事矿产地质调查及研究工作。E-mail:yangfc123@163.com
    通讯作者: 宋运红(1983− ),女,硕士,正高级工程师,从事土地质量地球化学调查及研究工作。E-mail:yunhong408@163.com
  • 中图分类号: P588.12+2; P597+3

Zircon U–Pb age, Hf isotope composition, and their constraints on tectonic setting of the Saima alkaling complex in the eastern Liaoning Province

More Information
  • 通过LA-ICP-MS测得辽宁赛马地区浅肉红色霞霓正长岩中的锆石U-Pb年龄为225.8±1.9 Ma,赛马碱性杂岩的侵位时代为晚三叠世。地球化学分析表明,霞霓正长岩SiO2含量为55.87% ~ 60.88%,Na2O为0.41% ~ 5.32%,Al2O3为17.81% ~ 19.53%,K2O为9.46% ~ 11.91%,MgO为0.46% ~ 1.36%,里特曼指数为7.54 ~ 17.01;稀土元素总量较高,高于300×10−6,强烈富集轻稀土元素,(La/Yb)N值大于10,个别达到100以上;亏损Nb、Ta、P等高场强元素,富集Rb、Th等大离子亲石元素,总体表现出富碱性岩石特征。锆石εHft)值为−13.37 ~ −9.30,对应的两阶段Hf模式年龄TDM2为2102 ~ 1855 Ma。通过岩石成因分析和构造环境判别,赛马碱性杂岩可能形成于由俯冲挤压向陆内伸展、拉张转换的动力背景下的下地壳(或上地幔)部分熔融。赛马碱性杂岩侵位时代(225.8±1.9 Ma)可能代表了华北克拉通北缘岩石圈开始伸展减薄的时间,也是郯庐断裂形成的时间。

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  • 图 1  中国东北构造地质简图(a)和辽东赛马地区碱性杂岩地质简图(b)

    Figure 1. 

    图 2  辽东赛马地区浅肉红色霞霓正长岩野外照片(a)和显微镜照片(b、c)

    Figure 2. 

    图 3  辽东赛马地区霞霓正长岩(TW04)锆石阴极发光(CL)图像及年龄

    Figure 3. 

    图 4  辽东赛马地区霞霓正长岩(TW04)锆石U-Pb谐和年龄图(a)和年龄加权平均值图(b)

    Figure 4. 

    图 5  辽东赛马地区碱性杂岩稀土元素配分曲线(a)和微量元素蛛网图(b)(标准值据Sun et al., 1989

    Figure 5. 

    图 6  辽东赛马地区霞霓正长岩锆石Lu-Hf同位素特征(底图据Yang et al.,2006)

    Figure 6. 

    图 7  辽东赛马地区碱性杂岩构造环境图解(底图据Pearce et al.,1984

    Figure 7. 

    表 1  辽东赛马地区霞霓正长岩(TW04)锆石U-Th-Pb同位素数据

    Table 1.  The U-Th-Pb isotope compositions of zircons from aegirine nepheline syenite (TW04)from Saima area in the eastern Liaoning Province

    点编号含量/10−6232Th/238U
    207Pb*/206Pb*
    206Pb*/238U
    207Pb*/235U
    误差206Pb/238U207Pb/235U谐和度
    206PbcUTh/%/%/%相关系数年龄/Ma年龄/Ma
    010.2121167918.3878.390.060.00680.040.00090.270.02290.308322662411893%
    020.22332183.656.610.080.01420.030.00100.290.03520.261619862582873%
    030.4428026213.620.940.050.00140.040.00040.250.00720.37672292225698%
    040.0015039610.022.640.060.00220.040.00040.270.01040.27302212240892%
    050.1587784.140.900.050.00290.040.00050.250.01360.250422432231199%
    060.0024719411.660.780.050.00190.040.00040.250.00920.32732313229798%
    074.20266305136.2511.450.280.00800.010.00020.430.01360.566370.3136410-36%
    080.00116735.060.620.060.00290.030.00040.270.01350.244021932401190%
    090.69108614.850.560.050.00270.040.00050.260.01230.295823232351098%
    100.0373721729.940.290.050.00120.030.00030.250.00550.37912212224498%
    110.26243182927.467.530.050.00190.040.00030.260.01000.25752252235895%
    120.072890311.5632.000.060.00590.030.00080.250.01890.328019852231587%
    130.08923477.543.790.050.00300.040.00050.250.01390.285222232301196%
    140.1516475913.564.640.070.00330.030.00060.260.00980.56941854235876%
    150.0044485853.05111.500.050.00350.040.00070.250.01790.278823142311499%
    160.1862372.790.600.050.00350.040.00060.250.01380.303622842231197%
    171.001991568.950.780.060.00230.030.00040.260.01060.26072192236992%
    180.00134415.310.310.050.00250.030.00040.240.01200.249322132211099%
    190.013155712.420.180.050.00150.040.00030.260.00730.34942272238695%
    201.34192407.550.210.050.00200.040.00040.250.00950.29342232230896%
    210.0021933512.491.530.050.00210.040.00040.260.00990.29982343233899%
    220.65296869.2023.500.050.00460.040.00070.250.01820.280223252251597%
    230.2310365811.156.360.090.00590.030.00050.360.01880.346719233141451%
    240.63402584.456.490.050.00420.040.00060.230.01790.235622742141594%
    250.3521291531.11135.980.060.00590.040.00100.270.01970.384223362461694%
    260.00170137220.788.090.050.00190.040.00040.240.00900.30302253214795%
    271.2712660212.034.790.100.00380.030.00030.410.01470.313219123461142%
    280.61642795.534.400.050.00360.040.00060.260.01690.274323442381497%
    291.085926522.780.110.050.00110.040.00030.250.00590.32562292223597%
    300.28169987.500.580.050.00220.040.00040.250.01100.24362302226998%
    下载: 导出CSV

    表 2  辽东赛马地区碱性杂岩主量、微量和稀土元素含量

    Table 2.  Major, trace and rare earth elements data for the alkaline complex from Saima area in the eastern Liaoning Province

    样品号 TW03-YQ1 TW03-YQ2 TW03-YQ3 TW03-YQ4 TW03-YQ5 TW04-YQ1 TW04-YQ2 TW04-YQ3 TW04-YQ4 TW04-YQ5
    SiO2 57.27 56.95 56.49 55.87 56.01 60.85 60.60 60.42 60.88 59.81
    TiO2 0.81 0.66 0.84 0.97 0.69 0.86 0.91 0.86 0.89 0.94
    Al2O3 19.18 18.75 18.84 18.53 19.53 18.38 18.26 17.93 18.66 17.81
    Fe2O3 1.85 1.92 2.09 2.40 1.73 4.94 5.03 5.09 4.62 6.22
    MnO 0.08 0.08 0.08 0.09 0.07 0.08 0.09 0.08 0.08 0.09
    MgO 0.64 0.86 0.59 0.58 0.75 0.62 1.36 0.84 0.46 0.47
    CaO 0.76 0.78 0.85 0.94 0.90 0.04 0.25 0.04 0.04 0.09
    Na2O 4.40 4.87 5.32 5.16 4.97 0.46 0.54 0.47 0.45 0.41
    K2O 10.03 9.46 9.68 10.09 9.50 11.76 11.11 11.91 11.69 11.78
    P2O5 0.10 0.10 0.08 0.10 0.10 0.03 0.04 0.03 0.03 0.04
    FeO 2.29 2.35 2.31 2.46 2.15 0.42 0.47 0.54 0.58 0.49
    烧失量 2.08 2.67 2.42 2.28 2.58 1.24 1.34 1.13 1.37 1.52
    A/CNK 0.99 0.95 0.91 0.88 0.97 1.35 1.37 1.31 1.39 1.31
    σ43 13.89 13.83 15.73 17.01 14.91 8.18 7.54 8.55 8.04 8.57
    总计 99.49 99.45 99.59 99.47 98.98 99.68 100 99.34 99.75 99.67
    Cr 8.94 7.92 8.56 7.98 9.34 10.9 8.53 8.63 9.39 9.28
    Ni 1.95 1.79 2.21 0.96 4.14 2.41 3.56 2.52 2.73 2.95
    Rb 515 297 358 360 549 317 324 323 334 323
    Sr 3000 3400 3300 3600 3200 1000 794 989 889 765
    Zr 819 489 644 573 1200 658 850 672 683 838
    Nb 54.7 27.5 39.0 35.5 58.4 42.1 50.3 42.0 51.8 41.3
    Ba 2800 2600 2500 2900 2700 1400 1400 1400 1400 1500
    Hf 17.5 24.2 29.1 27.0 20.2 15.8 19.4 20.1 20.9 24.4
    Ta 2.13 1.53 1.64 2.23 2.40 1.85 1.95 2.31 2.45 1.85
    Th 18.6 19.4 25.4 24.3 23.9 23.2 26.2 23.7 28.0 34.0
    U 4.92 3.54 4.68 3.77 6.37 5.51 7.06 6.00 4.68 7.59
    Li 50.8 54.6 48.9 50.7 48.6 55.0 63.6 41.5 35.1 45.2
    Be 10.3 9.64 10.4 10.8 11.6 5.48 5.47 6.23 6.36 6.72
    Co 6.12 6.70 6.20 6.43 5.39 7.23 7.79 5.97 5.33 8.72
    V 53.0 56.6 57.1 56.5 53.5 69.9 79.0 70.7 77.3 81.1
    Ga 28.4 29.4 29.2 30.9 27.5 29.3 29.9 28.8 27.0 29.2
    Sc 3.19 3.01 3.16 3.06 3.59 3.37 3.39 3.30 3.54 3.40
    Pb 69.9 86.6 84.0 111 77.5 103 106 119 121 124
    Y 14.3 11.8 13.7 15.0 14.9 8.84 11.4 8.43 10.1 9.62
    La 224 126 152 153 137 86.0 145 85.2 125 70.8
    Ce 347 280 354 359 318 261 337 259 388 327
    Pr 25.2 20.2 26.2 27.2 24.4 14.6 24.5 15.4 21.4 13.2
    Nd 78.0 61.6 81.9 87.7 80.2 47.1 76.2 49.3 66.6 43.5
    Sm 11.1 8.85 11.5 12.8 11.3 6.99 10.9 7.78 10.1 7.22
    Eu 3.53 3.00 3.46 3.75 3.35 2.07 2.72 2.20 2.50 2.21
    Gd 8.49 6.78 8.86 9.40 8.79 5.72 8.35 5.98 7.99 6.20
    Tb 0.99 0.78 1.01 1.12 1.03 0.63 0.89 0.65 0.85 0.65
    Dy 3.74 2.92 3.76 4.09 3.86 2.25 3.01 2.32 2.97 2.32
    Ho 0.56 0.46 0.57 0.61 0.60 0.35 0.44 0.35 0.44 0.36
    Er 1.61 1.25 1.57 1.69 1.66 0.97 1.27 0.99 1.20 1.04
    Tm 0.21 0.18 0.20 0.23 0.22 0.13 0.17 0.13 0.16 0.16
    Yb 1.15 1.02 1.13 1.24 1.20 0.79 1.00 0.75 0.94 1.00
    Lu 0.17 0.16 0.17 0.19 0.17 0.12 0.16 0.12 0.14 0.17
    ΣREE 706 513 647 661 592 428 611 430 628 476
    LREE 689 499 629 643 574 418 596 419 613 464
    HREE 16.91 13.54 17.27 18.57 17.53 10.97 15.28 11.29 14.69 11.90
    LREE/HREE 40.73 36.86 36.44 34.62 32.75 38.08 39.02 37.13 41.74 39.01
    (La/Yb)N 140 88.5 96.9 88.3 81.9 78.1 104 81.2 95.6 50.9
    δEu 1.11 1.18 1.05 1.05 1.03 1.00 0.87 0.98 0.85 1.01
      注:σ43为里特曼指数,σ43=[w(Na2O+K2O)]2/[w(SiO2)]−43
    下载: 导出CSV

    表 3  辽东赛马地区霞霓正长岩(TW04)锆石Hf同位素含量

    Table 3.  Hf isotope data of aegirine nepheline syenite (TW04) from Saima area in the eastern Liaoning Province

    测点编号 年龄/Ma 176Yb/177Hf 176Lu/177Hf 176Hf/177Hf 176Hf/177Hfi εHf(0) εHf(t) TDM1 /Ma TDM2 /Ma fLu/Hf
    01 226 0.053437 0.001291 0.282290 0.000013 0.282267 −17.86 −13.09 1402 2088 −0.96
    03 229 0.000917 0.000021 0.282333 0.000012 0.282310 −16.34 −11.32 1297 1979 −1.00
    04 221 0.001844 0.000041 0.282333 0.000013 0.282310 −16.34 −11.50 1298 1984 −1.00
    05 224 0.001043 0.000023 0.282302 0.000012 0.282279 −17.43 −12.52 1340 2051 −1.00
    08 219 0.001057 0.000018 0.282333 0.000019 0.282310 −16.34 −11.54 1297 1985 −1.00
    09 232 0.000687 0.000016 0.282293 0.000015 0.282270 −17.75 −12.67 1352 2066 −1.00
    10 221 0.003449 0.000068 0.282322 0.000016 0.282299 −16.73 −11.89 1314 2009 −1.00
    11 225 0.001295 0.000030 0.282306 0.000019 0.282283 −17.29 −12.36 1335 2042 −1.00
    13 222 0.000242 0.000004 0.282286 0.000013 0.282263 −18.00 −13.13 1361 2088 −1.00
    15 231 0.042501 0.000941 0.282331 0.000012 0.282308 −16.41 −11.48 1332 1990 −0.97
    16 228 0.000353 0.000008 0.282301 0.000012 0.282278 −17.47 −12.47 1341 2051 −1.00
    17 219 0.000479 0.000010 0.282323 0.000013 0.282300 −16.69 −11.89 1311 2007 −1.00
    18 221 0.000507 0.000011 0.282280 0.000017 0.282257 −18.21 −13.37 1369 2102 −1.00
    19 227 0.001331 0.000032 0.282315 0.000018 0.282292 −16.97 −12.00 1322 2020 −1.00
    20 223 0.000626 0.000016 0.282284 0.000015 0.282261 −18.07 −13.18 1364 2092 −1.00
    21 234 0.029693 0.000765 0.282310 0.000015 0.282287 −17.15 −12.14 1355 2034 −0.98
    22 232 0.035978 0.000832 0.282320 0.000012 0.282297 −16.80 −11.84 1343 2013 −0.97
    24 227 0.000551 0.000012 0.282286 0.000010 0.282263 −18.00 −13.02 1361 2085 −1.00
    25 233 0.144341 0.003151 0.282332 0.000015 0.282309 −16.37 −11.75 1413 2008 −0.91
    26 225 0.001419 0.000023 0.282330 0.000013 0.282307 −16.44 −11.51 1302 1988 −1.00
    28 234 0.001903 0.000044 0.282387 0.000014 0.282364 −14.43 −9.30 1224 1855 −1.00
    29 229 0.003627 0.000085 0.282304 0.000016 0.282281 −17.36 −12.35 1339 2044 −1.00
    30 230 0.000404 0.000010 0.282288 0.000012 0.282265 −17.93 −12.89 1358 2078 −1.00
      注:TDM1=ln[(176Hf/177Hf样品176Hf/177HfDM)/(176Lu/177Hf样品176Lu/177HfDM)+1]/λ,TDM2=ln{[176Hf/177Hf样品176Hf/177HfDM−(176Lu/177Hf样品176Lu/177HfCrust) ×(eλt−1)] /(176Lu/177HfCrust176Lu/177HfDM) +1}/λ
    下载: 导出CSV
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出版历程
收稿日期:  2021-12-31
修回日期:  2022-12-09
刊出日期:  2024-01-15

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