南秦岭镇安西部晚三叠世煌斑岩脉地球化学特征及其对构造环境的指示

孙万龙, 韩奎, 鲁麟, 薛旭平, 王明志, 贾忠胜, 刘能, 孟磊, 刘坤, 田科. 南秦岭镇安西部晚三叠世煌斑岩脉地球化学特征及其对构造环境的指示[J]. 地质通报, 2022, 41(11): 1982-1995. doi: 10.12097/j.issn.1671-2552.2022.11.007
引用本文: 孙万龙, 韩奎, 鲁麟, 薛旭平, 王明志, 贾忠胜, 刘能, 孟磊, 刘坤, 田科. 南秦岭镇安西部晚三叠世煌斑岩脉地球化学特征及其对构造环境的指示[J]. 地质通报, 2022, 41(11): 1982-1995. doi: 10.12097/j.issn.1671-2552.2022.11.007
SUN Wanlong, HAN Kui, LU Lin, XUE Xuping, WANG Mingzhi, JIA Zhongsheng, LIU Neng, MENG Lei, LIU Kun, TIAN Ke. Geochemical characteristics of Late Triassic lamprophyres from the western Zhen'an, South Qinling and its indicative significance for tectonic environment[J]. Geological Bulletin of China, 2022, 41(11): 1982-1995. doi: 10.12097/j.issn.1671-2552.2022.11.007
Citation: SUN Wanlong, HAN Kui, LU Lin, XUE Xuping, WANG Mingzhi, JIA Zhongsheng, LIU Neng, MENG Lei, LIU Kun, TIAN Ke. Geochemical characteristics of Late Triassic lamprophyres from the western Zhen'an, South Qinling and its indicative significance for tectonic environment[J]. Geological Bulletin of China, 2022, 41(11): 1982-1995. doi: 10.12097/j.issn.1671-2552.2022.11.007

南秦岭镇安西部晚三叠世煌斑岩脉地球化学特征及其对构造环境的指示

  • 基金项目:
    陕西省公益性地质调查项目《陕西省镇安县杨泗镇—东川镇钨钼多金属矿产地质调查》(编号: 202106)、陕西省自然科学基础研究计划资助项目《白钨矿矿物学对南秦岭镇安西部石英脉型钨矿岩浆-热液演化的约束》(编号: 2020JQ-974)和陕西省地质勘查基金项目《陕西省镇安西部整装勘查区基础地质调查》(编号: 61201707318)、《陕西典型小岩体成矿预测与勘查示范》(编号: 61201908334)
详细信息
    作者简介: 孙万龙(1992-), 男, 硕士, 助理工程师, 从事基础地质调查与矿产勘查工作。E-mail: 1203268139@qq.com
  • 中图分类号: P534.51;P588.13

Geochemical characteristics of Late Triassic lamprophyres from the western Zhen'an, South Qinling and its indicative significance for tectonic environment

  • 煌斑岩是反映深部构造-岩浆作用和源区地球化学性质的良好地质体。对南秦岭镇安西部地区出露的煌斑岩脉进行系统研究, 用LA-ICP-MS测定了煌斑岩中锆石U-Pb同位素, 得到其206Pb/238U年龄为222.2±1.2Ma(MSWD=0.38, n=15), 此年龄代表脉体的形成年龄, 属晚三叠世。地球化学分析表明, 岩石属钙碱性钾质-超钾质系列, 轻稀土元素和Rb、Ba等大离子亲石元素富集, 重稀土元素和Nb、Ti等高场强元素亏损, 具有俯冲带幔源岩石的成分特征; 岩石具有较高的(87Sr/86Sr)i值(0.7066~0.7076)和较低的εNd(t)值(-5.77~-4.62);锆石176Hf/177Hf值为0.28250~0.28287, εHf(t)值为-4.75~1.89, 锆石二阶段Hf模式年龄与全岩Nd二阶段模式年龄主要集中于中元古代(1.3~1.5Ga)。综合分析表明, 煌斑岩的源区为中元古代富集地幔, 形成于后碰撞伸展构造环境。在晚三叠世(220Ma左右)后碰撞伸展构造环境下, 勉略洋壳俯冲过程中形成的流体交代富集地幔在构造减压、深部物质上涌提供热和流体的共同作用下, 发生部分熔融, 形成具EMⅡ型同位素特征的镁铁质岩浆, 镁铁质岩浆沿后碰撞伸展阶段形成的裂隙上升侵位形成煌斑岩脉。

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  • 图 1  秦岭造山带及邻区大地构造略图(a,据参考文献[3]修改) 和南秦岭镇安西部地区地质简图(b,据参考文献修改)

    Figure 1. 

    图 2  煌斑岩脉岩脉野外(a)、手标本(b)及岩石薄片单偏光照片(c)

    Figure 2. 

    图 3  南秦岭镇安西部煌斑岩锆石阴极发光图像(a)及U-Pb谐和图(b)

    Figure 3. 

    图 4  煌斑岩TAS分类图(a)[31-32]和K/(K+Na)- K/Al图解(b)[33] (张家河煌斑岩数据据参考文献[19]; 沙河湾岩体附近煌斑岩数据据参考文献[17])

    Figure 4. 

    图 5  南秦岭镇安西部煌斑岩球粒陨石标准化稀土元素配分图(a)和原始地幔标准化微量元素蛛网图(b)

    Figure 5. 

    图 6  南秦岭镇安西部煌斑岩t - εHf(t)图解(a,底图据参考文献[39]) 和二阶段模式年龄值柱状图(b)

    Figure 6. 

    图 7  南秦岭镇安西部煌斑岩87Sr/86Sr - 143Nd/144Nd图解(a)和(87Sr/86Sr)i - εNd(t)图解(b) (a底图据参考文献[34],b底图据参考文献[11])

    Figure 7. 

    表 1  南秦岭镇安西部煌斑岩LA-ICP-MS锆石U-Th-Pb同位素数据

    Table 1.  U-Th-Pb isotopic data of zircon in the lamprohyres from western Zhen'an, South Qinling, as measured by LA-ICP-MS

    测点号 含量/10-6 Th/U 同位素比值 年龄/Ma
    Pb 232Th 238U 207Pb/206Pb 207Pb/235U 206Pb/238U 208Pb/232Th 206Pb/238U
    RZ1742-02 739 2377 1547 1.5 0.0619 0.0023 0.2965 0.013 0.0350 0.00067 0.0199 0.0010 221.7 4.2
    RZ1742-04 132 538 1499 0.4 0.0503 0.0017 0.2424 0.008 0.0349 0.00032 0.0116 0.0005 221.4 2.0
    RZ1742-05 816 2317 3327 0.7 0.0680 0.0023 0.3283 0.009 0.0352 0.00036 0.0212 0.0008 222.8 2.3
    RZ1742-10 501 1996 2020 1.0 0.0765 0.0030 0.3686 0.014 0.0348 0.00036 0.0153 0.0010 220.7 2.3
    RZ1742-11 1216 3875 2062 1.9 0.0799 0.0022 0.3916 0.010 0.0356 0.00033 0.0201 0.0008 225.4 2.0
    RZ1742-12 897 2727 2109 1.3 0.0585 0.0019 0.2823 0.009 0.0350 0.00029 0.0209 0.0008 221.8 1.8
    RZ1742-13 587 1516 3788 0.4 0.0614 0.0028 0.2944 0.009 0.0354 0.00053 0.0217 0.0009 224.3 3.3
    RZ1742-14 223 1052 1418 0.7 0.0628 0.0020 0.3042 0.012 0.0349 0.00048 0.0122 0.0005 221.3 3.0
    RZ1742-15 193 698 1655 0.4 0.0717 0.0021 0.3481 0.011 0.0350 0.00039 0.0146 0.0007 222.0 2.4
    RZ1742-17 288 1269 1985 0.6 0.0623 0.0021 0.3012 0.010 0.0351 0.00035 0.0129 0.0007 222.4 2.2
    RZ1742-18 1115 3410 2129 1.6 0.0699 0.0027 0.3367 0.012 0.0352 0.00039 0.0220 0.0011 222.8 2.4
    RZ1742-19 300 1317 2263 0.6 0.0629 0.0021 0.3038 0.010 0.0351 0.00032 0.0129 0.0006 222.1 2.0
    RZ1742-20 421 2090 1848 1.1 0.0717 0.0025 0.3426 0.012 0.0347 0.00033 0.0128 0.0007 219.6 2.1
    RZ1742-24 720 2236 1464 1.5 0.0716 0.0028 0.3417 0.015 0.0352 0.00064 0.0208 0.0010 222.8 4.0
    RZ1742-25 701 1884 2482 0.8 0.0804 0.0032 0.3893 0.016 0.0352 0.00044 0.0236 0.0013 222.8 2.7
    下载: 导出CSV

    表 2  南秦岭镇安西部煌斑岩主量、微量和稀土元素含量

    Table 2.  Major, trace elements and REE compositions of lamprohyres from western Zhen'an, South Qinling

    样号 SiO2 TiO2 Al2O3 Fe2O3 FeO MnO MgO CaO Na2O K2O P2O5 烧失量 总计 K2O+Na2O K2O/Na2O Mg# TFe2O3
    1742-1 51.05 0.805 11.25 2.4 3.23 0.0937 6.4 8.32 0.581 4.98 1.59 8.45 99.15 5.56 8.57 77.93 5.99
    1742-3 56.23 0.653 10.38 2.25 3.2 0.0904 5.36 6.88 1.72 3.64 1.09 7.48 98.97 5.36 2.12 74.91 5.81
    1742-4 53.52 0.607 10.65 3.36 2.42 0.0993 5.02 7.73 0.498 4.43 0.882 9.95 99.17 4.93 8.90 78.71 6.05
    1742-5 52.89 0.744 11.38 2.45 2.93 0.0921 5.59 7.97 0.751 4.59 1.36 8.26 99.01 5.34 6.11 77.28 5.71
    样号 Nb Zr Th U Ba Co Cr Ni Hf Rb Ta La Ce Pr Nd Sm Eu
    1742-1 3.29 1354 17.3 7.47 3945 22.8 273 183 32.3 177 0.17 69.7 142 17.9 69.4 13.0 3.84
    1742-3 4.34 670 13.9 4.11 1239 25.6 205 123 17.2 144 0.21 53.4 113 14.1 55.6 10.6 2.52
    1742-4 3.82 1309 21.9 8.18 3158 23.5 139 85.5 31.6 144 0.20 75.3 153 18.9 72.5 13.3 3.68
    1742-5 3.61 1411 17.5 7.30 3189 21.1 279 151 34.0 161 0.18 64.6 132 16.5 62.9 12.0 3.40
    样号 Gd Tb Dy Ho Er Tm Yb Lu Y ∑REE LREE HREE LREE/HREE LaN/YbN LaN/SmN GdN/YbN δEu
    1742-1 10.3 1.42 6.96 1.18 3.19 0.43 2.41 0.34 32.0 342.07 315.84 26.23 12.04 20.75 3.46 3.54 0.98
    1742-3 8.55 1.28 6.40 1.13 3.02 0.43 2.34 0.35 28.9 272.72 249.22 23.50 10.61 16.37 3.25 3.02 0.78
    1742-4 10.2 1.38 6.70 1.11 2.97 0.41 2.34 0.34 29.8 362.13 336.68 25.45 13.23 23.08 3.65 3.61 0.93
    1742-5 9.52 1.36 6.48 1.17 3.04 0.42 2.55 0.33 30.3 316.27 291.40 24.87 11.72 18.17 3.48 3.09 0.94
    注:Mg=100×Mg2+/(Mg2++ Fe2+),TFe2O3=Fe2O3+1.111×FeO,δEu =EuN /(SmN + GdN)1/2;主量元素含量单位为%, 微量和稀土元素含量单位为10-6
    下载: 导出CSV

    表 3  南秦岭镇安西部煌斑岩Sr-Nd同位素数据

    Table 3.  Sr-Nd isotopic results of lamprohyres from western Zhen'an, South Qinling

    样品号 Rb /10-6 Sr/10-6 (87Sr/86Sr) ±2σ 87Rb/86Sr (87Sr/86Sr)i Sm /10-6 Nd /10-6 143Nd/144Nd ±2σ 147Sm/144Nd (143Nd/144Nd)i εNd(t) TDM2 /Ga
    1742-1 177 720 0.708876 0.000010 0.71 0.70663 13.0 69.4 0.512281 0.000006 0.1140 0.512115 -4.62 1.38
    1742-3 144 628 0.709141 0.000010 0.66 0.70705 10.6 55.6 0.512225 0.000006 0.1160 0.512056 -5.77 1.47
    1742-4 144 1179 0.708715 0.000008 0.35 0.70760 13.3 72.5 0.512276 0.000006 0.1117 0.512114 -4.65 1.38
    1742-5 161 624 0.708946 0.000008 0.75 0.70659 12.0 62.9 0.512275 0.000005 0.1161 0.512106 -4.80 1.39
    注:εNd(t)= {[(143Nd/144Nd)样品-(147Sm/144Nd)样品×(eλt -1)]/[(143Nd/144Nd)CHUR-(147Sm/144Nd)CHUR×(eλt -1)-1]}×10000; TDM=(1/ λ)×ln {1+[(143Nd/144Nd)样品-(143Nd/144Nd)亏损地幔]/[(147Sm/144Nd)样品-(147Sm /144Nd)亏损地幔]}; (143Nd/144Nd)CHUR=0.512638,(147Sm/144Nd)CHUR=0.1967,(143Nd/144Nd)亏损地幔=0.51315,(147Sm /144Nd)亏损地幔=0.2137
    下载: 导出CSV

    表 4  南秦岭镇安西部煌斑岩锆石Lu-Hf同位素数据

    Table 4.  Zircon Lu-Hf isotopic results of lamprohyres from western Zhen'an, South Qinling

    测点号 176Yb/177Hf 176Lu/177Hf 176Hf/177Hf 206Pb/238U/Ma (176Hf/177Hf)i εHf(0) εHf(t) TDM1 /Ga TDM2 /Ga fLu/Hf
    1742-02 0.03738 0.00040 0.00110 0.000010 0.28260 0.000039 221.7 0.282591 -6.25 -1.54 0.93 1.35 -0.97
    1742-04 0.01466 0.00012 0.00043 0.000003 0.28260 0.000043 221.4 0.282597 -6.12 -1.32 0.91 1.34 -0.99
    1742-05 0.02554 0.00043 0.00079 0.000012 0.28266 0.000025 222.7 0.282660 -3.84 0.94 0.83 1.20 -0.98
    1742-10 0.03345 0.00011 0.00107 0.000006 0.28265 0.000017 220.7 0.282648 -4.24 0.45 0.85 1.23 -0.97
    1742-11 0.02177 0.00023 0.00071 0.000006 0.28250 0.000065 225.4 0.282498 -9.59 -4.74 1.05 1.56 -0.98
    1742-12 0.06097 0.00046 0.00155 0.000006 0.28269 0.000033 221.8 0.282688 -2.75 1.89 0.80 1.14 -0.95
    1742-13 0.00727 0.00004 0.00019 0.000001 0.28253 0.000021 224.3 0.282527 -8.63 -3.73 1.00 1.49 -0.99
    1742-14 0.03868 0.00046 0.00131 0.000013 0.28263 0.000029 221.3 0.282628 -4.89 -0.22 0.88 1.27 -0.96
    1742-15 0.00843 0.00008 0.00030 0.000002 0.28257 0.000018 222.0 0.282568 -7.16 -2.33 0.95 1.40 -0.99
    1742-17 0.01063 0.00007 0.00034 0.000002 0.28258 0.000020 222.3 0.282577 -6.85 -2.01 0.94 1.38 -0.99
    1742-18 0.01278 0.00007 0.00042 0.000003 0.28258 0.000022 222.7 0.282583 -6.63 -1.80 0.93 1.37 -0.99
    1742-19 0.01617 0.00005 0.00050 0.000002 0.28252 0.000037 222.1 0.282515 -9.00 -4.20 1.03 1.52 -0.99
    1742-20 0.03132 0.00009 0.00112 0.000002 0.28260 0.000021 219.6 0.282597 -6.02 -1.36 0.92 1.34 -0.97
    注:εHf(t)={[(176Hf/177Hf)s -(176Lu/177Hf)s ×(eλt -1)]/[(176Hf/177Hf)CHUR, 0 -(176Lu/177Hf)CHUR, 0×(eλt -1)]-1 }×10000; TDM1=(1/ λ)×ln {1+[(176Hf / 177Hf)s -(176Hf/177Hf)DM]/[(176Lu / 177Hf)s -(176Lu/177Hf)DM]}; TDM2=t+(1/ λ)×ln {1+[(176Hf / 177Hf)s , t-(176Hf/177Hf)DM, t]/[(176Lu / 177Hf)c -(176Lu/177Hf)DM]} ; fLu/Hf =(176Lu/177Hf)s /(176Lu/177Hf)CHUR, 0-1; 其中(176Lu/177Hf)s和(176Hf/177Hf)s为样品测定值,(176Lu/177Hf)CHUR, 0=0.0332, (176Hf/177Hf)CHUR, 0=0.282772, (176Lu/177Hf)DM =0.0384,(176Hf/177Hf)DM=0.28325,(176Lu/177Hf)c =0.015, λ=1.867×10-11/a,t为锆石结晶年龄
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收稿日期:  2021-10-10
修回日期:  2022-01-24
刊出日期:  2022-11-15

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