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摘要:
综述了在铜砷矿物浮选分离过程中，砷矿物的无机抑制剂、有机抑制剂、新型抑制剂、组合抑制剂的应用现状及其作用机理，以及酯类捕收剂、新型捕收剂等铜矿物高效捕收剂的研究新发现，同时介绍了铜砷矿物分离在浮选电化学领域、湿法工艺领域和火法工艺领域方面的最新研究成果，并探讨了铜砷分离研究与应用的发展方向。
Abstract:The application status and mechanism of inorganic inhibitors, organic inhibitors, new inhibitors and combined inhibitors of arsenic minerals in the process of copper arsenic mineral flotation separation were reviewed. The discoveries of high-efficiency collectors of copper minerals such as esters collectors and new collectors were also introduced. The latest research results in the field of copper and arsenic mineral separation in flotation electrochemistry, wet processes and pyrometallurgical processes were also introduced. The development direction of the research and application of copper and arsenic separation was forecasted.
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Key words:
- separation of copper and arsenic minerals /
- inhibitor /
- collector /
- mechanism of action /
- process
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[1] A. López Valdivieso A A. Sánchez López Escamilla CO, et al. Flotation and depression control of arsenopyrite through pH and pulp redox potential using xanthate as the collector[J]. International Journal of Mineral Processing, 2006, 81(1):27-34. doi: 10.1016/j.minpro.2006.06.003
[2] Fuerstenau, D. W. Froth flotation:50th anniversary volume[J]. The American Institute of Mining, Metallurgical, and Petroleum Engineers, 1962.
[3] Bhattacharyya D, Jumawan AB, Grieves RB. Separation of Toxic Heavy Metals by Sulfide Precipitation[J]. Separation Science and Technology, 1979, 14(5):441-452. doi: 10.1080/01496397908058096
[4] 何晓川, 唐晓莲.毒砂与方铅矿, 黄铜矿分离试验研究[J].矿产综合利用, 1994(3):16-18. http://www.cnki.com.cn/Article/CJFDTotal-KCZL403.004.htm
[5] 李成秀, 王昌良.铜砷浮选分离的进展[J].国外金属矿选矿, 2005, 42(9):9-12. http://d.old.wanfangdata.com.cn/Periodical/gwjskxk200509002
[6] 陈水波, 庄荣传, 范道焱, 等.某铜矿铜砷矿物分离研究[J].矿产综合利用, 2018(1):40-45. doi: 10.3969/j.issn.1000-6532.2018.01.00x9
[7] Xiong DL, Li JH, Zhong HH. Analysis of suppression mechanism of arsenopyrite by glycerol sodium xanthogenate using group electronegativity theory[J]. Journal of Central South University, 2010, 41(6):2156-2161. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=zngydxxb201006018
[8] 曾科, 覃文庆, 何名飞, 等.蒙自多金属硫化矿砷硫分离技术研究[J].矿冶工程, 2011, 31(2):65-67. doi: 10.3969/j.issn.0253-6099.2011.02.018
[9] 唐晓莲, 钱鑫.腐殖酸钠分选黄铜矿和毒砂的研究[J].有色金属(选矿部分), 1989(6):22-24. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=QK000003628359
[10] 金华爱, 彭志宏, 曾美云.用高分子有机物浮选分离黄铜矿和毒砂[J].有色金属:选矿部分, 1990(1):19-22. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=QK000004883081
[11] Gamble DS. Titration carves of fulvic acid:the analytical chemistry of a weak acid polyelectrolyte[J]. Revue Canadienne De Chimie, 1970, 48(17):2662-2669. doi: 10.1139/v70-450
[12] 纪军.毒砂与有色金属硫化矿浮选分离的理论与实践[J].国外金属矿选矿, 1993(10):30-35. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=QK000001787966
[13] Healy TW, Fuerstenau DW. The oxide-water interface-Interrelation of the zero point of charge and the heat of immersion[J]. Journal of Colloid Science, 1965, 20(4):376-386. doi: 10.1016/0095-8522(65)90083-8
[14] 杨梅金, 陈建华, 马少健, 等.新型抑制剂DAs分离铜砷[J].矿产保护与利用, 2003(6):31-32. doi: 10.3969/j.issn.1001-0076.2003.06.008 http://kcbh.cbpt.cnki.net/WKD/WebPublication/paperDigest.aspx?paperID=671b82a3-dfa9-4091-9e84-f8d9bbf52b98
[15] 熊道陵, 罗序燕, 陈湘清.DL抑制剂对黄铜矿和毒砂浮选分离的研究[J].江西化工, 2004(4):129-132. doi: 10.3969/j.issn.1008-3103.2004.04.044
[16] 廖祥文, 李成秀.某高砷铜锡矿选铜除砷试验研究[J].矿产综合利用, 2007(3):3-6. doi: 10.3969/j.issn.1000-6532.2007.03.001
[17] 张宝红.新型抑制剂在铜砷分离中的试验研究[D].赣州: 江西理工大学, 2013.
http://d.wanfangdata.com.cn/thesis/D444522 [18] 林榜立, 韦新彦, 阙绍娟, 等.取代氰化钠的新型无毒抑制剂FY02的合成及抑制性能研究[J].有色金属(选矿部分), 2015(5):82-86. doi: 10.3969/j.issn.1671-9492.2015.05.019
[19] 唐晓莲.黄铜矿与毒砂分离的抑制剂研究[J].矿产综合利用, 1996(1):12-15. http://d.old.wanfangdata.com.cn/Periodical/jiangxhg200404044
[20] 肖骏, 陈代雄, 杨建文, 等.某铜硫砷锡多金属矿选矿工艺研究[J].矿山机械, 2014, 42(8):110-116. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=ksjx201408028
[21] 严伟平, 陈晓青, 杨进忠, 等.某难选铜锌矿石的分离试验研究[J].矿山机械, 2015(4):99-103. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=ksjx201504024
[22] 刘子帅.低铜含砷难选铜锌硫化矿浮选分离工艺研究[D].赣州: 江西理工大学, 2013.
http://cdmd.cnki.com.cn/Article/CDMD-10407-1014101890.htm [23] 李玉芬.CCF组合抑制剂处理某高砷铜矿的研究[J].矿产保护与利用, 1999(1):38-40. http://kcbh.cbpt.cnki.net/WKD/WebPublication/paperDigest.aspx?paperID=e0506a50-8e88-4e9b-807d-097e54967970
[24] 陈水波, 庄荣传, 范道焱, 等.一种用于铜砷分离浮选的复合选矿抑制剂: CN105903573A[P].2016-08-31.
http://cprs.patentstar.com.cn/Search/Detail?ANE=9HCC7BGA5CCA9ECD9GHF9EFA9GBAFHIA9HFGAHCA6BDAAHIA [25] Lin SY, Liu RQ, Bu YJ, et al. Oxidative Depression of Arsenopyrite by Using Calcium Hypochlorite and Sodium Humate[J].Minerals, 2018, 8(10). http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=MDPI000000188995
[26] 王泰桧.丁黄腈酯用于黄铜矿与毒砂的分离[J].有色金属(选矿部分), 1981(4):58-59. http://www.cnki.com.cn/Article/CJFDTotal-YSXK198104018.htm
[27] 林强, 杨晓玲, 王淀佐.α-肟基膦酸酯对硫化矿物的捕收性能[J].有色金属工程, 1997(3):23-28. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=QK199700642745
[28] 于雪, 黄心廷, 杨长颖, 等.铜精矿降砷及提高选矿指标的试验研究[J].有色金属(选矿部分), 2002(6):15-18. doi: 10.3969/j.issn.1671-9492.2002.06.006
[29] 景世妍.甘南某高砷铜矿降砷试验研究[J].甘肃冶金, 2010, 32(6):54-56. doi: 10.3969/j.issn.1672-4461.2010.06.017
[30] 曹占芳, 钟宏, 刘广义, 等.秘鲁含砷铜钼矿高效浮选试验研究[J].稀有金属与硬质合金, 2012, 40(3)1-4, 12. http://www.cqvip.com/QK/91285X/201203/42283489.html
[31] 何谋海.N-烃氧羰基异硫氰酸酯及其衍生物的合成与浮选性能研究[D].长沙: 中南大学, 2011.
http://cdmd.cnki.com.cn/Article/CDMD-10533-1011180885.htm [32] Cao Z F, Qiu P, Zhong H, et al. A novel approach for flotation recovery of copper and molybdenite from a copper-arsenic ore[J]. Metallurgical Research & Technology, 2016, 113(1):103. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=92b210d0da1848ba6313a14659da1131
[33] 段景文.铜街选矿厂提铜降砷工艺技术研究[D].长沙: 中南大学, 2012.
http://d.wanfangdata.com.cn/thesis/Y2196711 [34] 苏林海, 薛春华.某高砷硫化铜锡矿浮选试验研究[J].中国高新技术企业, 2016(15):143-144. http://d.old.wanfangdata.com.cn/Periodical/zggxjsqy201610067
[35] 田华伟, 刘万峰.某含砷铜钴矿选矿工艺试验研究[J].铜业工程, 2018(5):17-19, 71. doi: 10.3969/j.issn.1009-3842.2018.05.006
[36] 鲍国富, 平福先.云锡某选矿厂铜精矿降砷技术改造实践[J].现代矿业, 2017, 33(7):80-82. doi: 10.3969/j.issn.1674-6082.2017.07.024
[37] 王成行, 胡真, 邱显扬, 等.抑砷浮铜工艺过程强化回收银的试验研究[J].矿冶工程, 2017, 37(2):64-67. doi: 10.3969/j.issn.0253-6099.2017.02.016
[38] 李柏淡, 孙水裕, 吉干芳, 王淀佐.黄铜矿自诱导浮选新技术的应用研究[J].有色金属(选矿部分), 1994(2):1-5. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=QK199400552242
[39] 因TW, 何树华, 李长根.硫砷铜矿与黄铜矿的优先浮选[J].国外金属矿选矿, 2000(10):33-36. http://www.cnki.com.cn/Article/CJFDTotal-JSXK200010008.htm
[40] 斯米斯LK, 龙忠银, 张覃, 等.采用电位控制浮选法分离北帕克斯铜金矿中的砷和铜[J].国外金属矿选矿, 2008(8):21-24. http://d.old.wanfangdata.com.cn/Periodical/gwjskxk200808005
[41] 陈锦安.黑铜中铜砷湿法分离试验研究[J].中国有色冶炼, 1999(3):26-29. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=QK199900779969
[42] 陈彩霞, 洪涛, 张晗, 等.含砷铜物料中砷、铜分离试验研究[J].铜业工程, 2014(6):26-28, 35. doi: 10.3969/j.issn.1009-3842.2014.06.007
[43] Shen Chen; Min Xiaobo; Shi Meiqing; Zhou Bosheng; Zhao Zongwen; Li Yuancheng; Zhang Chun. Separation of copper and arsenic in arsenic filtration cake[J]. Chinese Journal of Nonferrous Metals, 2017, 27(2):356-362. http://en.cnki.com.cn/Article_en/CJFDTotal-ZYXZ201702016.htm
[44] 姚瑛瑛, 郭莉, 胡中求, 等.超声辅助碱浸铜冶炼烟灰中铜砷分离[J].化工学报, 2018, 69(9):3983-3992. http://d.old.wanfangdata.com.cn/Periodical/hgxb201809025
[45] 李学鹏, 刘大春, 王娟.含砷铜烟尘砷的选择性分离试验[J].材料导报, 2018, 32(18):3110-3115. doi: 10.11896/j.issn.1005-023X.2018.18.003
[46] 田静, 赵亚峰, 马喜功, 等.金铜冶炼高砷烟尘酸浸液铜砷分离回收工艺研究[J].中国有色冶金, 2018, 47(3):33-34, 86. http://d.old.wanfangdata.com.cn/Periodical/ysyl201803008
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