-
摘要: 淀粉作为一种天然的高分子化合物,具有绿色无毒、来源广泛、成本低、易于改性等特点。近年来,随着我国环保力度的日益增强,淀粉类产品在矿物加工中的应用越来越受关注。本文介绍了淀粉类产品在矿物加工中的应用情况,重点阐述其作为抑制剂和絮凝剂在选矿中的应用及研究进展,并对其在矿物加工中的应用前景进行了展望,以期为淀粉的高效利用提供参考。Abstract: As a natural polymer compound, starch has the characteristics of green non-toxic, wide source, low cost and easy modification. In recent years, with the strengthen of environmental protection, the application of starch products in mineral processing has attracted more and more attention of researchers. In this paper, the application of starch products in mineral processing was elaborated. The typical application of starch products as inhibitors and flocculants in mineral processing was emphatically introduced, and the development direction of starch products in mineral processing was prospected to provide the reference for the efficient utilization of starch.
-
Key words:
- starch /
- depressant /
- flocculant /
- mineral processing /
- flotation
-
[1] 韩跃新, 孙永升, 李艳军, 等.我国铁矿选矿技术最新进展[J].金属矿山, 2015(2):1-11. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=jsks201502001
[2] 孙传尧, 周俊武, 贾木欣, 等.基因矿物加工工程研究[J].有色金属(选矿部分), 2018(1):1-7. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=ysjs-xk201801001
[3] 侯华丽, 吴尚昆, 蒋芳, 等.新时代我国绿色矿山建设规划的思考[J].中国矿业, 2019, 28(7):81-85, 93. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=zgky201907014
[4] DONG A Q, XIE J, WANG W M, et al. A novel method for amino starch preparation and its adsorption for Cu(II) and Cr(VI).[J]. Journal of hazardous materials, 2010, 181: 1-3. doi: 10.1016/j.jhazmat.2010.04.120
[5] 邹永强.淀粉改性高效絮凝剂的合成与应用研究[D].西安: 西北大学, 2016.
[6] 肖志刚, 邵晨, 杨柳, 等.淀粉改性方法的研究现状及进展[J].农产品加工, 2020(3):81-84, 88. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=ncqjg-xk202002021
[7] 赵凯强, 杨超, 王晨.阳离子改性淀粉絮凝剂的研究进展[J].当代工, 2019, 48(9):2162- 2166. http://www.cnki.com.cn/Article/CJFDTotal-SYHH201909072.htm
[8] 王烨, 唐敏.淀粉与氧化铁矿物的应用及其作用机理的研究进展[J].矿产综合利用, 2015(5):17-22. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=kczhly201505004
[9] 杨爽.改性淀粉絮凝剂在工业废水处理中的应用进展[J].环境科学导刊, 2015, 34(3):81-83. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=ynhjkx201503021
[10] 朱建光.选矿药剂[M].北京:冶金工业出版社[M], 1993, 151-155.
[11] PERES A E C, CORREA M I. Depression of iron oxides with corn starches[J]. Minerals Engineering, 1996, 9(12): 1227-1234. doi: 10.1016/S0892-6875(96)00118-5
[12] GABRIELA F. MOREIRA, ELAYNNE R. et al. XPS study on the mechanism of starch-hematite surface chemical complexation[J]. Minerals Engineering, 2017. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=dcf3823692a85157a02196f75271617c
[13] SHRIMALI K, ATLUTI V, WANG Y, et al. The nature of hematite depression with corn starch in the reverse flotation of iron ore[J]. Journal of Colloid & Interface ence, 2018, 524: 337. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=7c678938ab118e695a278c3a31826f83
[14] 朱俊士.选矿试验研究与产业化[M].北京:冶金工业出版社, 2004, 12-13.
[15] 徐冬林, 朱巨建, 刘国振.赤铁矿石浮选抑制剂的应用现状及研发前景[J].能源与节能, 2014(10):100-102. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=sxnyyjn201410043
[16] 刘顺兵, 葛英勇, 高钦, 等.过氧羟基油酸作为铁矿石反浮选捕收剂试验研究[J].金属矿山, 2020(3):85-89. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=jsks202003013
[17] 张兆元, 刘桂云.阴离子捕收剂LKY试验室试验及工业试验研究[J].中国矿业, 2003(10):44-45. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=zgky200310013
[18] 尹明水, 杨久流, 任爱军.磷酸酯淀粉对赤铁矿抑制性能研究[J].有色金属(选矿部分), 2013(2):64-67. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=ysjs-xk201302017
[19] 朱一民, 贾静文, 任佳, 等.高取代度羧甲基淀粉作齐大山铁矿反浮选抑制剂[J].金属矿山, 2013(7):67-70. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=jsks201307018
[20] 刘洁, 钟建玲, 李彬华, 等.赤铁矿反浮选抑制剂变性淀粉的制备及应用性能[J].化工技术与开发, 2019, 48(6):1-5. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=gxhg201906001
[21] 李晔, 彭勇军, 刘奇, 许时.多糖在硫化矿物浮选中的应用及其作用机理[J].武汉化工学院学报., 1998(2):41-45 http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=QK199800927423
[22] J.S.拉斯科夫斯基, 徐柏辉.多糖-用于硫化矿物优先浮选的天然无毒调整剂[J].国外金属矿选矿, 1994(10):21-27. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=QK199400267620
[23] YANG S, LI C, WANG L. Dissolution of starch and its role in the flotation separation of quartz from hematite[J]. Powder Technology, 2017, 320: 346-357. doi: 10.1016/j.powtec.2017.07.061
[24] 韩会丽, 印万忠, 姚金.东鞍山含碳酸盐磁选混合精矿分步与分散浮选协同工艺研究[J].金属矿山, 2016(12):71-76. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=jsks201612016
[25] 邱仙辉, 孙传尧.磷酸酯淀粉在黄铜矿及方铅矿表面吸附研究[J].有色金属(选矿部分), 2014(3):86-90. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=ysjs-xk201403021
[26] G Han, S WEN, HAN W, et al. Effect of starch on surface properties of pyrite and chalcopyrite and its response to flotation separation at low alkalinity[J]. Minerals Engineering, 2019, 143: 1-8. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=11ffca52d9919f7b656fb32720cb63c1
[27] 周灵初, 张一敏.淀粉对红柱石矿浮选分离过程的影响研究[J].矿冶工程, 2011, 31(2):35-38, 41. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=kygc201102010
[28] 冯博, 朱贤文, 王金庆, 汪惠惠, 王鹏程.高分子抑制剂在绿泥石浮选中的双重作用[J].矿物学报, 2016, 36(1):115-118. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=kwxb201601018
[29] 陈代雄, 薛伟, 杨建文等.一种硫化铜矿物与滑石浮选分离方法: CN103008113A[P].2013-04-03.
[30] 李海普, 张莎莎, 蒋昊, 等.羧甲基淀粉的取代度对其在反浮选中抑制一水硬铝石的影响(英文)[J].Transactions of Nonferrous Metals Society of China, 2011, 21(8): 1868-1873. http://d.wanfangdata.com.cn/Periodical/zgysjsxb-e201108029
[31] WONDER C, BRENTON F, YONGJUN P. The differential depression of an oxidized starch on the flotation of chalcopyrite and graphite[J].Minerals Engineering, 2020, 146: 1-8. http://www.sciencedirect.com/science/article/pii/S0892687519305254
[32] 胡岳华.矿物浮选[M].长沙:中南大学出版社, 2014, 147-151.
[33] 魏德洲.固体物料分选学[M].北京:冶金工业出版社, 2009, 326-328.
[34] 刘邦瑞.赤铁矿选择性絮凝的初步研究[J].云南冶金, 1978(5):19-27. http://www.cnki.com.cn/Article/CJFDTotal-YNYJ197805004.htm
[35] 牛福生, 张晓亮, 张晋霞, 等.淀粉对赤铁矿的絮凝特性及作用机理研究[J].矿冶工程, 2016, 36(6):30-34. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=kygc201606008
[36] P.K. WEISSENBORN, L.J. WARREN, J.G. DUNN. Selective flocculation of ultrafine iron ore 1. Mechanism of adsorption of starch onto hematite[J]. Colloids & Surfaces A Physicochemical & Engineering Aspects, 1995, 99(1): 11-27. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=f00f855405bed33ae1454e38ba0d5a36
[37] 夏妍, 李福全, 姜效军.阳离子淀粉的合成及在选矿废水处理中的应用[J].梅山科技, 2006(3):29-31. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=mskj200603012
[38] 高明, 徐志强.两性型淀粉-丙烯酰胺接枝共聚物的合成与在煤泥水处理中的应用[J].中国煤炭, 2013, 39(11):90-93, 107. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=zgmt201311024
[39] 屈佳, 樊雪梅, 王毅梦, 等.丙烯酰胺接枝淀粉在选矿废水絮凝处理中的应用[J].工业用水与废水, 2017, 48(2):43-46. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=gyysyfs201702011
[40] 屈佳, 曹宝月, 张梦萌, 等.改性淀粉絮凝剂在选矿废水处理中的应用[J].中国矿业, 2017, 26(4):135-139. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=zgky201704027