-
摘要:
我国原生金红石矿具有矿物成分复杂、目的矿物品位低、嵌布粒度较细等特点, 浮选法是回收利用金红石和提高其品位的重要手段, 其中浮选药剂是关键。浮选金红石的捕收剂主要有脂肪酸类、膦酸类、胂酸类、羟肟酸类, 调整剂可分为活化剂与抑制剂。为促进金红石选矿技术的进步, 以及为选矿工作者们提供技术理论的参考, 文章在概述了金红石矿性质、浮选难点以及微纳气泡浮选的基础上, 对捕收剂、抑制剂、活化剂的研究进展与作用机理进行了详细的阐述, 以加深对原生金红石矿浮选药剂的认识与了解, 并对未来药剂的研究方向进行了展望。
Abstract:Primary rutile ore in China has the characteristics of complex mineral composition, low grade of target mineral and fine disseminated grain size. Flotation is an important means of recovering and utilizing rutile and improving its grade, among which flotation reagent is the key. The collectors of flotation rutile mainly include fatty acid, phosphonic acid, arsine acid and hydroxamic acid, and the regulator can be divided into activator and inhibitor. To promote the progress of rutile mineral processing technology, as well as the theory of ore dressing workers to provide technical reference, based on the overview of the rutile ore properties, micro-nano flotation and flotation difficulties, the research progress and action mechanism of collectors, inhibitors and activators were summarized in detail to deepen the understanding of primary rutile flotation reagents, and the future research directions of reagents were also prospected.
-
Key words:
- primary rutile ore /
- flotation reagent /
- collector /
- inhibitor /
- activator
-
-
[1] 陈骞. 榴辉岩型金红石浮选药剂制度及作用机理研究[D]. 武汉: 武汉理工大学, 2020.
CHEN Q. Study on flotation separation scheme of rutile from eclogite ore and adsorption mechanism of agents on mineral surface[D]. Wuhan: Wuhan University of Technology, 2020.
[2] 吴贤, 张健. 中国的钛资源分布及特点[J]. 钛工业进展, 2006(6): 8-12. doi: 10.3969/j.issn.1009-9964.2006.06.004
WU X, ZHANG J. Distribution and characteristics of titanium resources in China[J]. Progress in Titanium Industry, 2006(6): 8-12. doi: 10.3969/j.issn.1009-9964.2006.06.004
[3] 胡克俊. 钛资源开发及产品利用状况[J]. 中国金属通报, 2007(16): 2-6. https://www.cnki.com.cn/Article/CJFDTOTAL-JSTB200716002.htm
HU K J. Development and utilization of titanium resources[J]. China Metals Bulletin, 2007(16): 2-6. https://www.cnki.com.cn/Article/CJFDTOTAL-JSTB200716002.htm
[4] 汪镜亮. 颜料二氧化钛的应用及当前钛矿物的需求[J]. 矿产综合利用, 1992(4): 13-22. https://www.cnki.com.cn/Article/CJFDTOTAL-KCZL199204004.htm
WANG J L. Application of pigment titanium dioxide and current demand of titanium minerals[J]. Comprehensive Utilization of Mineral Resources, 1992(4): 13-22. https://www.cnki.com.cn/Article/CJFDTOTAL-KCZL199204004.htm
[5] 邓国珠. 世界钛资源及其开发利用现状[J]. 钛工业进展, 2002(5): 9-12. doi: 10.3969/j.issn.1009-9964.2002.05.003
DENG G Z. Status quo of development and utilization of titanium resources in the world[J]. Progress in Titanium Industry, 2002(5): 9-12. doi: 10.3969/j.issn.1009-9964.2002.05.003
[6] 王立平, 王镐, 高颀, 等. 我国钛资源分布和生产现状[J]. 稀有金属, 2004(1): 265-267. doi: 10.3969/j.issn.0258-7076.2004.01.065
WANG L P, WANG H, GAO Q, et al. Distribution and production status of titanium resources in China[J]. Rare Metals, 2004(1): 265-267. doi: 10.3969/j.issn.0258-7076.2004.01.065
[7] 王勇海. 榴辉岩型金红石矿选矿工艺研究[D]. 长沙: 中南大学, 2010.
WANG Y H. Study on mineral processing of eclogite-type rutile ore[D]. Changsha: Central South University, 2010.
[8] 李洪强, 苗呈佶, 翁孝卿, 等. 金红石与石榴石浮选分离试验研究[J]. 金属矿山, 2018(5): 84-87. https://www.cnki.com.cn/Article/CJFDTOTAL-JSKS201805020.htm
LI H Q, MIAO C J, WENG X Q, et al. Experimental study on flotation Separation of Rutile and garnet[J]. Metal Mine, 2018(5): 84-87. https://www.cnki.com.cn/Article/CJFDTOTAL-JSKS201805020.htm
[9] 张云, 管永诗, 田玉珍. 我国金红石矿资源开发利用现状[J]. 矿产保护与利用, 2000(5): 27-30. doi: 10.3969/j.issn.1001-0076.2000.05.007 http://kcbh.cbpt.cnki.net/WKD/WebPublication/paperDigest.aspx?paperID=0d368128-1070-45dc-b99b-84d03c085ff9
ZHANG Y, GUAN Y S, TIAN Y Z. Status quo of exploitation and utilization of rutile resources in China[J]. Conservation and Utilization of Mineral Resources, 2000(5): 27-30. doi: 10.3969/j.issn.1001-0076.2000.05.007 http://kcbh.cbpt.cnki.net/WKD/WebPublication/paperDigest.aspx?paperID=0d368128-1070-45dc-b99b-84d03c085ff9
[10] 常田仓, 章晓林, 赵文迪, 等. 金红石选矿技术研究综述[J]. 矿产保护与利用, 2019, 39(5): 167-173. http://kcbh.cbpt.cnki.net/WKD/WebPublication/paperDigest.aspx?paperID=21be3a0d-bda3-4e66-94fa-a65170a13534
CHANG T C, ZHANG X L, ZHAO W D, et al. Review on beneficiation technology of rutile[J]. Conservation and Utilization of Mineral Resources, 2019, 39(5): 167-173. http://kcbh.cbpt.cnki.net/WKD/WebPublication/paperDigest.aspx?paperID=21be3a0d-bda3-4e66-94fa-a65170a13534
[11] 吴婧, 秦善, 罗泽敏, 等. 热处理金红石晶体结构及其光催化活性分析[J]. 高校地质学报, 2011, 17(1): 118-124. doi: 10.3969/j.issn.1006-7493.2011.01.016
WU J, QIN S, LUO Z M, et al. Crystal structure and photocatalytic activity of heat-treated rutile[J]. Geological journal of China universities, 2011, 17(1): 118-124. doi: 10.3969/j.issn.1006-7493.2011.01.016
[12] 张木辰, 赵喜民, 李伟. 方城金红石矿带五间房矿床地质特征[J]. 河南地质, 1993(2): 81-86. https://www.cnki.com.cn/Article/CJFDTOTAL-HNDD199302000.htm
ZHAN M C, ZHAO X M, LI W. Geological characteristics of Wujianfang deposit in Fangcheng rutile belt[J]. Henan Geology, 1993(2): 81-86. https://www.cnki.com.cn/Article/CJFDTOTAL-HNDD199302000.htm
[13] HONAKER R. Nanobubble generation and its application in froth flotation (part Ⅰ): nanobubble generation and its effects on properties of microbubble and millimeter scale bubble solutions[J]. Mining Science and Technology, 2010, 20(1): 1-19.
[14] ASHUTOSH A, WUN J N, YU L. Principle and applications of microbubble and nanobubble technology for water treatment[J]. Chemosphere, 2011, 84(9): 30-48.
[15] DONGPING T, AHMED S. Nanobubble effects on hydrodynamic interactions between particles and bubbles[J]. Powder Technology, 2019, 346: 101-134.
[16] 肖巍. 枣阳微细粒难选原生金红石矿强化浮选分离机理[M]. 北京: 冶金工业出版社, 2019.7.
XIAO W. Enhanced flotation separation mechanism of Zaoyang micro-fine refractory primary rutile Ore[M]. Beijing: Metallurgical Industry Press, 2019. 7.
[17] 赵西泽. 西安户县金红石矿地质特征及矿石选矿试验[J]. 非金属矿, 1995(6): 14-16. https://www.cnki.com.cn/Article/CJFDTOTAL-FJSK506.001.htm
ZHAO X Z. Geological characteristics and beneficiation test of rutile ore in Huxian county, Xi'an[J]. Non-metallic Ores, 1995(6): 14-16. https://www.cnki.com.cn/Article/CJFDTOTAL-FJSK506.001.htm
[18] 万丽, 高玉德. 山东某金红石矿石浮选试验研究[J]. 金属矿山, 2013(12): 70-72. https://www.cnki.com.cn/Article/CJFDTOTAL-JSKS201312020.htm
WAN L, GAO Y D. Experimental research on flotation of a rutile ore in Shandong[J]. Metal Mine, 2013(12): 70-72. https://www.cnki.com.cn/Article/CJFDTOTAL-JSKS201312020.htm
[19] 王军, 程宏伟, 赵红波, 等. 油酸钠作用下金红石的浮选行为及作用机理[J]. 中国有色金属学报, 2014, 24(3): 820-825. https://www.cnki.com.cn/Article/CJFDTOTAL-ZYXZ201403033.htm
WANG J, CHENG H W, ZHAO H B, et al. Flotation behavior and mechanism of rutile under sodium oleate[J]. The Chinese Journal of Nonferrous Metals, 2014, 24(3): 820-825. https://www.cnki.com.cn/Article/CJFDTOTAL-ZYXZ201403033.htm
[20] PAN C, J H Z, W S, et al. The activation mechanism of lead ions in the flotation of ilmenite using sodium oleate as a collector[J]. Minerals Engineering, 2017, 111.
[21] 冯其明, 席振伟, 张国范, 等. 脂肪酸捕收剂浮选钛铁矿性能研究[J]. 金属矿山, 2009(5): 46-49. doi: 10.3321/j.issn:1001-1250.2009.05.012
FENG Q M, X Z W, Z G F, et al. Research on flotation performance of ilmenite by fatty acid collector[J]. Metal Mine, 2009(5): 46-49. doi: 10.3321/j.issn:1001-1250.2009.05.012
[22] 张庆鹏, 刘润清, 曹学锋, 等. 脂肪酸类白钨矿捕收剂的结构性能关系研究[J]. 有色金属科学与工程, 2013, 4(5): 85-90. https://www.cnki.com.cn/Article/CJFDTOTAL-JXYS201305019.htm
ZHAN Q P, LIU R Q, CAO X F, et al. Study on structure and properties of fatty acid scheelite collector[J]. Non-ferrous Metals Science and Engineering, 2013, 4(5): 85-90. https://www.cnki.com.cn/Article/CJFDTOTAL-JXYS201305019.htm
[23] 沈智慧, 张覃, 卯松, 等. 脂肪酸结构对胶磷矿表面润湿性的影响研究[J]. 矿产保护与利用, 2018(3): 105-111. http://kcbh.cbpt.cnki.net/WKD/WebPublication/paperDigest.aspx?paperID=500e730f-d8bb-43b6-a3b7-155f44bd9262
SHEN Z H, ZHAN Q, MAO S, et al. Effect of fatty acid structure on surface wettability of collophosphite[J]. Conservation and Utilization of Mineral Resources, 2018(3): 105-111. http://kcbh.cbpt.cnki.net/WKD/WebPublication/paperDigest.aspx?paperID=500e730f-d8bb-43b6-a3b7-155f44bd9262
[24] 杨耀辉. 白钨矿浮选过程中脂肪酸类捕收剂的混合效应[D]. 长沙: 中南大学, 2010.
YAN Y H. Mixing effect of fatty acid collectors in scheelite flotation process[D]. Changsha: Central South University, 2010.
[25] 江庆梅. 混合脂肪酸在白钨矿与萤石、方解石分离中的作用[D]. 长沙: 中南大学, 2009.
JIANG Q M. Effects of mixed fatty acids on separation of scheelite from fluorite and calcite[D]. Changsha: Central South University, 2009.
[26] 江庆梅, 戴子林. 混合脂肪酸在白钨矿与萤石、方解石分离中的作用[J]. 矿冶工程, 2012, 32(2): 42-44. doi: 10.3969/j.issn.0253-6099.2012.02.011
JIANG Q M, DAI Z L. Effect of mixed fatty acids on separation of scheelite from fluorite and calcite[J]. Mining and metallurgy engineering, 2012, 32(2): 42-44. doi: 10.3969/j.issn.0253-6099.2012.02.011
[27] C. S M, John C W. Some copolymers of dimethyl 1-propene-2-phosphonate and of 1-phenylvinylphosphonic acid[J]. Journal of Polymer Science, 1952, 8(2): 10-18.
[28] I. N T, A. K B, G. V S, et al. Synthesis and pharmacological activity of alkylphosphonic and oxy derivatives[J]. Pharmaceutical Chemistry Journal, 1988, 22(2): 31-40.
[29] 彭勇军, 许时, 刘奇. 复合捕收剂浮选原生金红石矿的研究[J]. 有色金属, 1995(2): 34-40. https://www.cnki.com.cn/Article/CJFDTOTAL-YOUS502.006.htm
PENG Y J, XU S, LIU Q. Study on flotation of primary rutile ore with compound collector[J]. Nonferrous Metals, 1995(2): 34-40. https://www.cnki.com.cn/Article/CJFDTOTAL-YOUS502.006.htm
[30] 肖巍, 杨娟, 胡聪, 等. 正辛醇对苯乙烯膦酸浮选金红石过程的影响[J]. 矿冶工程, 2019, 39(6): 35-38. doi: 10.3969/j.issn.0253-6099.2019.06.008
XIAO W, YANG J, HU C, et al. Effect of n-octanol on the flotation process of styrene phosphonic acid rutile[J]. Mining and metallurgy engineering, 2019, 39(6): 35-38. doi: 10.3969/j.issn.0253-6099.2019.06.008
[31] XIAO T H, WEI X, HONG B Z, et al. Hydrophobic flocculation flotation of rutile fines in presence of styryl phosphonic acid[J]. Transactions of Nonferrous Metals Society of China, 2018, 28(7): 1424-1432. . doi: 10.1016/S1003-6326(18)64781-8
[32] 杜岩. 烷胺双甲基膦酸浮选金红石的研究[J]. 矿冶工程, 1993(2): 34-37. https://www.cnki.com.cn/Article/CJFDTOTAL-KYGC199302007.htm
DU Y. Study on flotation of rutile by alkylamine dimethylphosphonic acid[J]. Mining and Metallurgy Engineering, 1993(2): 34-37. https://www.cnki.com.cn/Article/CJFDTOTAL-KYGC199302007.htm
[33] 王雅静. 安康难选金红石矿选矿试验研究[D]. 昆明: 昆明理工大学, 2006.
WANG Y J. Experimental study on beneficiation of Ankang refractory rutile ore[D]. Kunming: Kunming University of Science and Technology, 2006.
[34] 黄余. 铅离子作用下混合捕收剂对金红石的浮选机理研究[D]. 昆明: 昆明理工大学, 2019.
HUANG Y. Study on the flotation mechanism of rutile with mixed collector under the action of lead ions[D]. Kunming: Kunming University of Science and Technology, 2019.
[35] 崔林, 刘均彪. 金红石和石榴石浮选分离的研究[J]. 化工矿山技术, 1986(5): 32-33. https://www.cnki.com.cn/Article/CJFDTOTAL-HGKJ198605011.htm
CUI L, LIU J B. Study on flotation separation of rutile and garnet[J]. Chemical Mining Technology, 1986(5): 32-33. https://www.cnki.com.cn/Article/CJFDTOTAL-HGKJ198605011.htm
[36] 刘贝, 王军, 覃文庆, 等. 湖北枣阳细粒原生金红石矿浮选分离研究[J]. 有色金属(选矿部分), 2014(6): 38-42. doi: 10.3969/j.issn.1671-9492.2014.06.010
LIU B, WANG J, QIN W Q, et al. Flotation separation of fine primary rutile ore from Zaoyang in Hubei Province[J]. Nonferrous Metals (Mineral Processing Section, 2014(6): 38-42. doi: 10.3969/j.issn.1671-9492.2014.06.010
[37] 李晔, 许时. 提高胂酸对金红石浮选性能的研究[J]. 中国矿业, 1997(2): 58-61. https://www.cnki.com.cn/Article/CJFDTOTAL-ZGKA199702017.htm
LI Y, XU S. Study on improving the flotation performance of rutile by arsenic acid[J]. China Mining, 1997(2): 58-61. https://www.cnki.com.cn/Article/CJFDTOTAL-ZGKA199702017.htm
[38] 刘均彪, 崔林. 钛铁矿、金红石的浮选理论及实践[J]. 有色金属, 1987(2): 34-40. https://www.cnki.com.cn/Article/CJFDTOTAL-YOUS198702005.htm
LIU J B, CUI L. Flotation theory and practice of Ilmenite and rutile[J]. Nonferrous Metals, 1987(2): 34-40. https://www.cnki.com.cn/Article/CJFDTOTAL-YOUS198702005.htm
[39] 朱建光. 浮选金红石用的捕收剂和调整剂[J]. 国外金属矿选矿, 2008(2): 3-8. https://www.cnki.com.cn/Article/CJFDTOTAL-JSXK200802001.htm
ZHU J G. Collector and regulator for flotation of rutile[J]. Metal Ore Dressing Abroad, 2008(2): 3-8. https://www.cnki.com.cn/Article/CJFDTOTAL-JSXK200802001.htm
[40] 唐清. C-8羟肟酸的合成及其浮选性能研究[D]. 长沙: 中南大学, 2014.
TANG Q. Synthesis of C-8 hydroxamic acid and its flotation performance[D]. Changsha: Central South University, 2014.
[41] 张宝元. 羟肟酸类捕收剂的合成及其对钛铁矿的浮选性能研究[D]. 长沙: 中南大学, 2011.
ZHANG Y B. Synthesis of hydroxamic acid collector and its flotation performance on ilmenite[D]. Changsha: Central South University, 2011.
[42] 朱诗曼, 李怡霏, 张喆怡, 等. 羟肟酸类捕收剂浮选金红石特性及其机理[J]. 矿产保护与利用, 2021, 41(4): 59-63. http://kcbh.cbpt.cnki.net/WKD/WebPublication/paperDigest.aspx?paperID=413f7969-972f-4776-8c76-2b7f21d5000e
ZHU S M, LI Y F, ZHANG Z Y, et al. Flotation characteristics and mechanism of rutile with hydroxamic acid collectors[J]. Conservation and Utilization of Mineral Resources, 2022, 41(4): 50-63. http://kcbh.cbpt.cnki.net/WKD/WebPublication/paperDigest.aspx?paperID=413f7969-972f-4776-8c76-2b7f21d5000e
[43] JUN W, HONG W C, HONG B Z, et al. Flotation behavior and mechanism of rutile with nonyl hydroxamic acid[J]. Rare Metals, 2016, 35(5): 419-424. doi: 10.1007/s12598-014-0386-0
[44] QIN W Q, REN L Y, XU Y B, et al. Adsorption mechanism of mixed salicylhydroxamic acid and tributyl phosphate collectors in fine cassiterite electro-flotation system[J]. Journal of Central South University, 2012, 19(6): 1711-1717. doi: 10.1007/s11771-012-1197-9
[45] 贺智明, 董雍赓. 水杨氧肟酸浮选金红石的机理研究[J]. 矿产保护与利用, 1995(1): 25-29. http://kcbh.cbpt.cnki.net/WKD/WebPublication/paperDigest.aspx?paperID=47b68ba8-52a6-4324-8f84-8085299e118a
HE Z M, DONG Y G. Study on flotation mechanism of rutile by salicylic oxime acid[J]. Conservation and Utilization of Mineral Resources, 1995(1): 25-29. http://kcbh.cbpt.cnki.net/WKD/WebPublication/paperDigest.aspx?paperID=47b68ba8-52a6-4324-8f84-8085299e118a
[46] 姬俊梅. 烷基羟肟酸盐与铌铁金红石的作用机理研究[J]. 有色金属(选矿部分), 2004(4): 42-44. doi: 10.3969/j.issn.1671-9492.2004.04.012
JI J M. Study on the interaction mechanism between alkyl hydroxamate and niobium ferric rutile[J]. Nonferrous Metals (Mineral Processing Section), 2004(4): 42-44. doi: 10.3969/j.issn.1671-9492.2004.04.012
[47] 李洪强, 母顺兴, 张艳清, 等. 乳化煤油在金红石与石榴石浮选分离中的增效作用研究[J]. 金属矿山, 2018(3): 97-101. https://www.cnki.com.cn/Article/CJFDTOTAL-JSKS201803018.htm
LI H Q, MU S X, ZHANG Y Q, et al. Study on synergism of emulsified Kerosene in flotation separation of rutile and garnet[J]. Metal Mine, 2018(3): 97-101. https://www.cnki.com.cn/Article/CJFDTOTAL-JSKS201803018.htm
[48] 周源, 高崇峰. 某难选含金矿石的载体浮选研究[J]. 江西有色金属, 2000(4): 12-14. doi: 10.3969/j.issn.1674-9669.2000.04.004
ZHOU Y, GAO C F. Research on carrier flotation of a refractory gold-bearing ore[J]. Jiangxi Nonferrous Metals, 2000(4): 12-14. doi: 10.3969/j.issn.1674-9669.2000.04.004
[49] 朱申红, 荀志运, 冯婕, 等. 浮选氟碳铈矿的捕收剂及药剂混用的研究[J]. 金属矿山, 2000(8): 32-34. doi: 10.3321/j.issn:1001-1250.2000.08.011
ZHU S H, XUN Z Y, FENG J, et al. Study on the mixture of collector and reagent of flotation bastnaesite[J]. Metal Mine, 2000(8): 32-34. doi: 10.3321/j.issn:1001-1250.2000.08.011
[50] CYRIL M, OLIVIER D, PIERRE B. Ion foam flotation of neodymium: from speciation to extraction[J]. Journal of Molecular Liquids, 253(2018): 217-227.
[51] Chemical Engineering; study data from Wuhan University of technology update understanding of chemical engineering (Rutile flotation with Pb2+ ions as activator: Adsorption of Pb2+ at rutile/water interface)[J]. Journal of Engineering, 506(2016): 431-437.
[52] 贺智明, 董雍赓, 孙笈. 铅离子对水杨氧肟酸浮选金红石的活化作用研究[J]. 有色金属, 1994(4): 43-48. https://www.cnki.com.cn/Article/CJFDTOTAL-YOUS404.008.htm
HE Z M, DONG Y G, SUN J. Study on the activation of lead ion on salicylic acid flotation rutile[J]. Nonferrous Metals, 1994(4): 43-48. https://www.cnki.com.cn/Article/CJFDTOTAL-YOUS404.008.htm
[53] 刘明宝, 鱼博, 魏锐, 等. Pb2+活化金红石的界面热力学和动力学机制[J]. 有色金属工程, 2018, 8(1): 71-76. doi: 10.3969/j.issn.2095-1744.2018.01.015
LIU M B, YU B, WEI R, et al. Interfacial thermodynamics and kinetics of Pb2+activated rutile[J]. Nonferrous Metals Engineering, 2018, 8(1): 71-76. doi: 10.3969/j.issn.2095-1744.2018.01.015
[54] 张蕾, 刘雪岩, 姜晓庆, 等. 纳米TiO2对钼(Ⅵ)的吸附性能[J]. 中国有色金属学报, 2010, 20(2): 301-307. https://www.cnki.com.cn/Article/CJFDTOTAL-ZYXZ201002021.htm
ZHANG L, LIU X Y, JIANG X Q, et al. Adsorption of molybdenum (ⅵ) by TiO2[J]. The Chinese Journal of Nonferrous Metals, 2010, 20(2): 301-307. https://www.cnki.com.cn/Article/CJFDTOTAL-ZYXZ201002021.htm
[55] WEI X, PAN C, QIAN N L, et al. Adsorption behavior and mechanism of Bi (Ⅲ) ions on rutile-water interface in the presence of nonyl hydroxamic acid[J]. Transactions of Nonferrous Metals Society of China, 2018, 28(2): 89.
[56] QI C F, WEN J Z, SHU M W, et al. Activation mechanism of lead ions in cassiterite flotation with salicylhydroxamic acid as collector[J]. Separation and Purification Technology, 2017, 178.
[57] QIN B C, XIU M C, QI C F, et al. Activation mechanism of lead ion in the flotation of stibnite[J]. Minerals Engineering, 2018(119): 173-182.
[58] P. F A B, A. P C, A. B L, et al. The use of dextrin in purification by flotation of molybdenite concentrates[J]. International Journal of Mineral Processing, 2014(127): 23-27.
[59] 李晔, 刘奇, 许时. 矿物表面金属离子组分与糊精的相互作用(Ⅲ)——糊精存在时萤石/方解石、萤石/金红石的浮选分离[J]. 化工矿山技术, 1994(6): 23-25. https://www.cnki.com.cn/Article/CJFDTOTAL-HGKJ406.007.htm
LI Ye, LIU Q, XU S. Interaction between metal Ion components on mineral surface and dextrin (Ⅲ)-flotation separation of fluorite/calcite and fluorite/rutile in the presence of dextrin[J]. Chemical Mining Technology, 1994(6): 23-25. https://www.cnki.com.cn/Article/CJFDTOTAL-HGKJ406.007.htm
[60] 马光荣. 变质岩微细粒金红石浮选研究[J]. 有色金属(选矿部分), 1989(3): 12-13. https://www.cnki.com.cn/Article/CJFDTOTAL-YSXK198903002.htm
MA G R. Study on flotation of metamorphic rock micro-fine rutile[J]. Nonferrous Metals (Mineral Processing Section), 1989(3): 12-13. https://www.cnki.com.cn/Article/CJFDTOTAL-YSXK198903002.htm
[61] 丁浩, 崔林. 六偏磷酸钠在金红石与硅钙质矿物浮选分离中的作用机理[J]. 有色金属, 1991(4): 33-40. https://www.cnki.com.cn/Article/CJFDTOTAL-YOUS199104006.htm
DING H, CUI L. Mechanism of sodium hexametaphosphate in flotation separation of rutile and silica-calcareous minerals[J]. Nonferrous Metals, 1991(4): 33-40. https://www.cnki.com.cn/Article/CJFDTOTAL-YOUS199104006.htm
[62] 丁浩. 金红石浮选中消除Ca2+对石英活化作用的研究[J]. 矿产保护与利用, 1994(1): 40-42. http://kcbh.cbpt.cnki.net/WKD/WebPublication/paperDigest.aspx?paperID=e8283484-0988-432f-a392-434a51b24d20
DING H. Study on eliminating Ca2+on quartz activation in rutile flotation[J]. Conservation and Utilization of Mineral Resources, 1994(1): 40-42. http://kcbh.cbpt.cnki.net/WKD/WebPublication/paperDigest.aspx?paperID=e8283484-0988-432f-a392-434a51b24d20
[63] 丁浩, 任瑞晨, 邓雁希, 等. 金红石与石榴石浮选分离及调整剂作用机理[J]. 辽宁工程技术大学学报, 2007(5): 787-790. https://www.cnki.com.cn/Article/CJFDTOTAL-FXKY200705043.htm
DING H, REN R C, DENG Y X, et al. Flotation separation of rutile and garnet and mechanism of regulator[J]. Journal of Liaoning Technical University, 2007(5): 787-790. https://www.cnki.com.cn/Article/CJFDTOTAL-FXKY200705043.htm
[64] 岳铁兵. 细粒金红石的浮选分离研究[D]. 沈阳: 东北大学, 2006.
YUE T B. Study on the floatation of fine rutile ore[D]. Shenyang: Northeastern University, 2006.
[65] 徐玉琴, 欧阳坚, 卢寿慈. 金红石与一水硬铝石的浮选分离[J]. 矿产综合利用, 1996(4): 1-6. https://www.cnki.com.cn/Article/CJFDTOTAL-KCZL604.000.htm
XU Y Q, OUYANG J, LU S C. Flotation separation of rutile and diaspore[J]. Multipurpose Utilization of Mineral Resources, 1996(4): 1-6. https://www.cnki.com.cn/Article/CJFDTOTAL-KCZL604.000.htm
[66] 丁浩. 金红石与磷灰石浮选分离中硫酸铝的作用研究[J]. 化工矿山技术, 1997(3): 13-16. https://www.cnki.com.cn/Article/CJFDTOTAL-HGKJ199703003.htm
DING H. Study on the effect of aluminum sulfate in flotation separation of rutile and apatite[J]. Chemical Mining Technology, 1997(3): 13-16. https://www.cnki.com.cn/Article/CJFDTOTAL-HGKJ199703003.htm
[67] 高利坤. 微细粒难选金红石矿的选矿试验研究[D]. 昆明: 昆明理工大学, 2003.
GAO L K. Experimental study on beneficiation of micro-fine refractory rutile ore[D]. Kunming: Kunming University of Science and Technology, 2003.
-
下载:
图(4)
表(1)
计量
- 文章访问数: 1969
- PDF下载数: 30
- 施引文献: 0