中国地质学会岩矿测试技术专业委员会、国家地质实验测试中心主办

蚀变粗面岩中再平衡结构黑云母的电子探针分析

聂潇, 王宗起, 陈雷, 陈浦浦, 王刚. 蚀变粗面岩中再平衡结构黑云母的电子探针分析[J]. 岩矿测试, 2019, 38(5): 565-574. doi: 10.15898/j.cnki.11-2131/td.201807100081
引用本文: 聂潇, 王宗起, 陈雷, 陈浦浦, 王刚. 蚀变粗面岩中再平衡结构黑云母的电子探针分析[J]. 岩矿测试, 2019, 38(5): 565-574. doi: 10.15898/j.cnki.11-2131/td.201807100081
Xiao NIE, Zong-qi WANG, Lei CHEN, Pu-pu CHEN, Gang WANG. Electron Microprobe Analysis of Biotite with Reequilibration Texture in Altered Trachyte[J]. Rock and Mineral Analysis, 2019, 38(5): 565-574. doi: 10.15898/j.cnki.11-2131/td.201807100081
Citation: Xiao NIE, Zong-qi WANG, Lei CHEN, Pu-pu CHEN, Gang WANG. Electron Microprobe Analysis of Biotite with Reequilibration Texture in Altered Trachyte[J]. Rock and Mineral Analysis, 2019, 38(5): 565-574. doi: 10.15898/j.cnki.11-2131/td.201807100081

蚀变粗面岩中再平衡结构黑云母的电子探针分析

  • 基金项目:
    国家自然科学基金面上项目(41872092);中国地质调查局地质调查项目“境外大型矿产资源基地及资源潜力评价”(DD20190437),“矿产资源国情调查数据集成与动态更新”(DD20190613)
详细信息
    作者简介: 聂潇, 博士, 矿物学、岩石学、矿床学专业。E-mail:niexiao369@qq.com
    通讯作者: 陈雷, 博士, 副研究员, 从事矿床地质学研究。E-mail:chenleihx@gmail.com
  • 中图分类号: P575.1

Electron Microprobe Analysis of Biotite with Reequilibration Texture in Altered Trachyte

More Information
  • 黑云母的化学成分中蕴含着重要的成因信息,对具有交代结构的黑云母进行微区成分分析,能够精细反映交代蚀变过程中元素迁移情况,为解决矿床形成机制方面的科学问题提供矿物学证据。本文以北大巴山平利地区蚀变粗面岩中具有再平衡结构的黑云母斑晶为研究对象,进行电子探针面扫描和剖面成分分析。结果表明,斑晶内部为岩浆成因黑云母,边缘为"扩散-反应"过程所致的再平衡成因黑云母。斑晶边缘与内部相比,TiO2含量由平均5.78%降至2.22%,表明在交代蚀变过程中黑云母中Ti等高场强元素被淋滤出进入流体;而CaO含量由平均0.06%升至0.14%,F含量由平均0.60%升至0.80%,指示蚀变流体内富含Ca、F等组分。本研究揭示了粗面岩中铌矿床的形成与热液作用关系密切,成矿流体中Ca、F等组分在铌元素的迁移及富集过程中具有重要作用。
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  • 图 1  (a) 粗面岩手标本照片(隐晶质结构,块状构造),(b)黑云母斑晶单偏光镜下照片

    Figure 1. 

    图 2  黑云母斑晶背散射(BSE)图像和成分剖面上不同组分含量变化情况

    Figure 2. 

    图 3  黑云母斑晶背散射(BSE)图像和对应Ti、Mg、Fe元素的面扫描图

    Figure 3. 

    图 4  黑云母成分10×TiO2-FeO*-MgO图解(据文献[14])

    Figure 4. 

    表 1  黑云母斑晶电子探针分析结果

    Table 1.  Representative electron microprobe analysis of biotite phenocrysts

    成分 斑晶内部 斑晶边缘
    TC-B3-20(7个分析点) TC-B3-30(6个分析点) 平均值
    (%)
    TC-B3-20(6个分析点) TC-B3-30(4个分析点) 平均值
    (%)
    最小值
    (%)
    最大值
    (%)
    平均值
    (%)
    最小值
    (%)
    最大值
    (%)
    平均值
    (%)
    最小值
    (%)
    最大值
    (%)
    平均值
    (%)
    最小值
    (%)
    最大值
    (%)
    平均值
    (%)
    SiO2 34.62 36.02 35.30 34.00 35.56 34.89 35.10 35.81 36.36 36.11 35.72 36.56 36.25 36.18
    TiO2 4.72 7.39 5.93 4.65 7.14 5.62 5.78 1.98 2.19 2.11 2.23 2.44 2.33 2.22
    Al2O3 12.27 13.30 12.63 12.26 13.09 12.60 12.62 13.90 14.59 14.33 13.53 13.86 13.71 14.02
    FeOT 21.30 22.50 21.82 20.32 21.52 21.17 21.50 22.06 23.08 22.48 21.65 22.36 21.98 22.23
    MnO 0.97 1.28 1.16 1.25 2.00 1.51 1.34 1.21 1.36 1.31 1.23 1.43 1.33 1.32
    MgO 8.92 9.50 9.19 9.22 10.27 9.82 9.51 9.14 9.52 9.32 9.47 9.85 9.73 9.53
    CaO 0.05 0.22 0.11 0.00 0.00 0.00 0.06 0.06 0.33 0.16 0.05 0.14 0.11 0.14
    Na2O 0.13 0.26 0.21 0.20 0.31 0.25 0.23 0.27 0.47 0.35 0.22 0.33 0.28 0.32
    K2O 8.78 9.23 8.99 8.71 9.35 9.11 9.05 8.85 9.32 9.12 9.18 9.59 9.42 9.27
    F 0.33 0.68 0.48 0.68 0.73 0.71 0.60 0.62 0.83 0.70 0.82 0.98 0.90 0.80
    总量 94.25 96.57 95.34 94.70 95.22 94.96 95.15 94.82 95.91 95.27 94.75 95.49 95.11 95.19
    XFeO* 0.70 0.73 0.72 0.69 0.71 0.70 0.71 0.71 0.72 0.72 0.70 0.71 0.71 0.72
    基于22个O原子计算阳离子数
    成分 斑晶内部 斑晶边缘
    TC-B3-20(7个分析点) TC-B3-30(6个分析点) 平均值
    (%)
    TC-B3-20(6个分析点) TC-B3-30(4个分析点) 平均值
    (%)
    最小值
    (%)
    最大值
    (%)
    平均值
    (%)
    最小值
    (%)
    最大值
    (%)
    平均值
    (%)
    最小值
    (%)
    最大值
    (%)
    平均值
    (%)
    最小值
    (%)
    最大值
    (%)
    平均值
    (%)
    Si 5.45 5.56 5.51 5.37 5.54 5.48 5.50 5.58 5.69 5.64 5.63 5.70 5.67 5.66
    Al 2.22 2.45 2.33 2.25 2.44 2.33 2.33 2.31 2.42 2.36 2.30 2.37 2.33 2.35
    Al 0.00 0.03 0.00 0.00 0.00 0.00 0.00 0.24 0.33 0.28 0.18 0.23 0.20 0.24
    Ti 0.56 0.85 0.70 0.55 0.84 0.66 0.68 0.23 0.26 0.25 0.26 0.29 0.27 0.26
    Fe 2.76 2.95 2.85 2.64 2.84 2.78 2.82 2.88 3.01 2.94 2.82 2.95 2.88 2.91
    Mn 0.13 0.17 0.15 0.16 0.27 0.20 0.18 0.16 0.18 0.17 0.16 0.19 0.18 0.18
    Mg 2.06 2.24 2.14 2.14 2.40 2.30 2.22 2.14 2.22 2.17 2.22 2.30 2.27 2.22
    Ca 0.01 0.04 0.02 0.00 0.00 0.00 0.01 0.01 0.06 0.03 0.00 0.02 0.01 0.02
    Na 0.04 0.08 0.06 0.06 0.09 0.08 0.07 0.08 0.14 0.10 0.07 0.10 0.08 0.09
    K 1.74 1.84 1.79 1.75 1.87 1.82 1.81 1.77 1.85 1.82 1.84 1.90 1.88 1.85
    XMg 0.41 0.44 0.43 0.44 0.46 0.45 0.44 0.42 0.43 0.42 0.43 0.45 0.44 0.43
    T(℃) 737 792 766 738 792 763 765 601 622 614 625 645 635 625
    注:FeOT表示电子探针测试的全铁含量;XFeO*=FeO*/(FeO*+MgO);FeO*=FeOT+MnO;XMg=Mg/(Mg+Fe)。T(℃)计算据公式:T={[ln(Ti)-a-c×(XMg)3]/b}0.333[21]
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出版历程
收稿日期:  2018-07-10
修回日期:  2019-03-05
录用日期:  2019-07-16

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