南海东北部陆坡区浮游有孔虫壳体的原位微区Mg/Ca分析

张广璐, 杨俊, 龙海燕, 赵彦彦, 邹立, 魏浩天, 刘盛, 杨丹丹, 孙国静. 南海东北部陆坡区浮游有孔虫壳体的原位微区Mg/Ca分析[J]. 海洋地质与第四纪地质, 2022, 42(6): 43-58. doi: 10.16562/j.cnki.0256-1492.2021122101
引用本文: 张广璐, 杨俊, 龙海燕, 赵彦彦, 邹立, 魏浩天, 刘盛, 杨丹丹, 孙国静. 南海东北部陆坡区浮游有孔虫壳体的原位微区Mg/Ca分析[J]. 海洋地质与第四纪地质, 2022, 42(6): 43-58. doi: 10.16562/j.cnki.0256-1492.2021122101
ZHANG Guanglu, YANG Jun, LONG Haiyan, ZHAO Yanyan, ZOU Li, WEI Haotian, LIU Sheng, YANG Dandan, SUN Guojing. In situ geochemical analysis of Mg/Ca ratios of planktonic foraminifera shells in the northeastern continental slope of the South China Sea[J]. Marine Geology & Quaternary Geology, 2022, 42(6): 43-58. doi: 10.16562/j.cnki.0256-1492.2021122101
Citation: ZHANG Guanglu, YANG Jun, LONG Haiyan, ZHAO Yanyan, ZOU Li, WEI Haotian, LIU Sheng, YANG Dandan, SUN Guojing. In situ geochemical analysis of Mg/Ca ratios of planktonic foraminifera shells in the northeastern continental slope of the South China Sea[J]. Marine Geology & Quaternary Geology, 2022, 42(6): 43-58. doi: 10.16562/j.cnki.0256-1492.2021122101

南海东北部陆坡区浮游有孔虫壳体的原位微区Mg/Ca分析

  • 基金项目: 中央高校基本科研业务费专项(202172002);国家自然科学基金“华南新元古代盖帽白云岩沉积微相的镁硅同位素研究”(41873006);试采海底孔隙压力监测与海洋物理环境研究项目(2018C-03-186)
详细信息
    作者简介: 张广璐(1996—),女,硕士研究生,研究方向为海洋地质,E-mail:zgl4730@stu.ouc.edu.cn
    通讯作者: 赵彦彦(1978—),女,博士,教授,博士生导师,主要从事海洋沉积化学的研究,E-mail:zhaoyanyan@ouc.edu.cn
  • 中图分类号: P736.4

In situ geochemical analysis of Mg/Ca ratios of planktonic foraminifera shells in the northeastern continental slope of the South China Sea

More Information
  • 有孔虫碳酸钙质壳体是海洋沉积物中普遍存在的环境记录载体之一,原位微区分析技术的发展为更进一步详细、直观地了解有孔虫壳体内微量元素的分布和变化提供了新方法,并带动了应用有孔虫壳体微区的元素含量和比值作为工具进行古环境反演相关研究的快速发展。利用电子探针 (EPMA)、激光剥蚀电感耦合等离子体质谱 (LA-ICP-MS) 并结合扫描电镜,对南海东北部陆坡区表层沉积物中的Globigerinoides ruberNeogloboquadrina dutertreiPulleniatina obliquiloculataGloborotalia inflata 4种浮游有孔虫壳体的Mg/Ca进行了原位地球化学分析。电子探针面扫描结果显示,G.ruber具有多条高Mg条带,这些周期性的条带变化可能与共生藻类有关;而N.dutertreiP.obliquiloculataG.inflata外部具有较厚的低Mg方解石壳。同时,LA-ICP-MS测试结果也显示出N.dutertreiP.obliquiloculataG.inflata的壳体中存在明显的低Mg/Ca层,而G.ruber中可见多组Mg/Ca比的高低变化,这与电子探针面扫描的结果一致。有孔虫自身的生物矿化过程会影响壳体中Mg/Ca比的分布,而污染相的存在会导致Mg/Ca测试结果的偏高。因此,认为有孔虫壳体Mg/Ca比的较大变化不仅受到周围海水温度的影响,而且还与共生藻等因素有关。此外,利用LA-ICP-MS测试可获得较为可靠的Mg/Ca比,避免了常规复杂的前处理过程,可以为今后高效、快速、高空间分辨率、低样品量的测试提供技术依据。

  • 加载中
  • 图 1  有孔虫样品LA-ICP-MS测试的元素信号图

    Figure 1. 

    图 2  有孔虫的SEM图像

    Figure 2. 

    图 3  G.ruber的电子探针面扫描图像

    Figure 3. 

    图 4  G.inflataP.obliquiloculataN.dutertrei的电子探针面扫描图像

    Figure 4. 

    图 5  G.ruber的Mg/Ca和Sr/Ca在壳体深度上的变化

    Figure 5. 

    图 6  N.dutertreiG.inflataP.obliquiloculata 的Mg/Ca在壳体深度上的变化

    Figure 6. 

    图 7  利用GR个体f2-a位置的Mg/Ca比值恢复的温度(Mg/Ca=0.38 exp 0.09[SST−0.61h−1.6])[40]

    Figure 7. 

    图 8  G.ruber不同分析位置的Al/Ca、Mn/Ca平均值

    Figure 8. 

    表 1  DZ5重力柱状样品19 cm处的AMS14C测年数据和校正年龄

    Table 1.  AMS14C dating data and corrected age of the gravity core sample of DZ5 at 19 cm

    深度/cm测试材料AMS14C年龄/aBP日历年龄/cal.aBP2σ范围/cal.aBP
    19G.ruber3345±351162950~1383
    下载: 导出CSV

    表 2  各属种不同腔室的Mn/Ca、Al/Ca平均值

    Table 2.  Average Mn/Ca and Al/Ca values in different chambers of each species

    个体腔室Mn/Ca/
    (mmol·mol−1)
    Al/Ca/
    (mmol·mol−1)
    个体腔室Mn/Ca/
    (mmol·mol−1)
    Al/Ca/
    (mmol·mol−1)
    GR未1F0.171.62NDF0.263.29
    F10.243.25F10.132.19
    F20.407.50F20.081.11
    平均值0.274.12F30.081.73
    GR未2F0.111.04F40.114.17
    F10.141.99平均值0.132.50
    F20.162.07NDF0.100.35
    平均值0.141.70F10.060.06
    GRF0.110.09F20.050.06
    F10.090.07F30.060.06
    F20.120.12F40.080.26
    平均值0.110.09平均值0.070.15
    POF0.170.27GIF0.082.52
    F10.220.36F10.130.58
    F20.160.10F20.060.23
    F30.130.21F30.080.52
    平均值0.170.23平均值0.090.96
    POF0.160.04GIF0.210.14
    F10.110.05F10.110.05
    F20.100.04F20.110.08
    F30.090.20平均值0.140.09
    平均值0.120.08
    下载: 导出CSV
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出版历程
收稿日期:  2021-12-21
修回日期:  2022-03-19
录用日期:  2022-03-19
刊出日期:  2022-12-28

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