Testing of quartz ESR dating for the marine strata on the northwestern coast of Hainan Island
-
摘要:
利用石英ESR测年法对海南岛西北部出露海相地层的上部和下部进行了定年，尝试获得该出露地层的年龄范围，并探讨石英ESR法在热带海相地层年代学研究中的适用性。结果显示，上部地层年龄为（33±6.6）～（53±10.6） ka，下部地层年龄为（1 835±202）～（2 567±256）ka，反映了该地层的沉积时代基本属于更新世。根据各样品ESR信号强度与辐照剂量的线性拟合结果判断，7个样品中以最顶部和最底部2个样品的拟合度最佳，而且最底部样品的ESR信号强度随辐照剂量增大而趋于饱和，表明上部地层年龄以51±8.9 ka最为可靠，地层的底部则可能超出了更新世。本次研究是石英ESR测年法在我国热带海岸更新世海相地层的探讨性应用，其研究结果是下一步采用其他顺磁中心对该地层开展全面和深入的石英ESR测年的重要基础，同时也为更新世其他海相地层的ESR年代学研究提供参考。
Abstract:In order to obtain the age range of the marine strata exposed on the northwestern coast of Hainan Island, quartz ESR (electron spin resonance) dating method was adopted to date 7 samples from the upper and bottom outcrops of the strata. In addition, the application of quartz ESR dating method for chronostratigraphy of tropical marine strata was also discussed. Age dating results show that the upper layers are between (33±6.6) ~ (53±10.6) ka and the bottom layers are between (1 835±202) ~ (2567±256) ka, reflecting that the marine strata were accumulated mainly during the Pleistocene. According to the linear fitting results of the ESR signal intensity and irradiation dose, only two samples, one from the uppermost and one from the nethermost, have the best fit, and the ESR signal intensity of the nethermost sample tends to saturation with the irradiation dose. This indicates that 5.1±8.9 ka is the most reliable age for the upper layers, and the bottom of the strata may be beyond the Pleistocene. It is the first application of quartz ESR dating to Pleistocene marine strata of domestic tropical coast in this study. The results not only are the important basis for comprehensive and in-depth quartz ESR dating of the strata exposed in northwestern Hainan Island, but also provide great insights for the ESR dating research of other Pleistocene marine strata.
-
Key words:
- marine strata /
- quartz ESR dating /
- Pleistocene /
- Hainan Island
-
-
表 1 样品信息及石英ESR测年结果
Table 1. Sample information and results of quartz ESR dating
编号 物质 高度/m U/(μg/g) TU/(μg/g) K2O/% 含水量/% 古剂量
/Gy年剂量
/(Gy/ka)年龄
/kaST01 灰黄色粉砂 3.0 1.71 10.2 1.83 20 125±22 2.43 51±8.9 ST02 灰黄色粉砂 5.0 1.98 12.6 1.83 13 122±24 2.86 48±9.6 ST03 土黄色细砂 6.5 1.03 7.08 0.77 2.2 55±11 1.66 33±6.6 ST04 土黄色细砂 8.0 1.54 12.7 1.09 5.5 126±25 2.38 53±10.6 SJDT01 含泥砂岩 4.0 1.92 12.6 1.82 2.0 5889±648 3.24 1 835±202 SJDT03 中粗砂岩 7.0 1.17 6.99 0.487 2.0 2764±553 1.43 1 933±387 SJDT04 中细砂岩 9.0 1.91 8.16 0.781 1.0 5083±340 1.98 2567±256 
下载: 导出CSV
-
[1] 赵希涛, 于革, 邹欣庆. 海南岛神尖灯塔剖面海相更新世地层与沉积环境[J]. 第四纪研究, 2001, 21(5):470-478 doi: 10.3321/j.issn:1001-7410.2001.05.011
ZHAO Xitao, YU Ge, ZOU Xinqing. Pleistocene marine strata at Shenjian lighthouse profile of Hainan Island and the sedimentary environments [J]. Quaternary Sciences, 2001, 21(5): 470-478. doi: 10.3321/j.issn:1001-7410.2001.05.011
[2] 袁宝印. 海南岛北部第四纪玄武岩分期问题[C]//中国地理学会第一次构造地貌学术讨论会论文选集. 北京: 科学出版社, 1984: 182-187.
YUAN Baoyin. The problem of the stage of basalt in the Quaternary in the northern part of Hainan Island[C]//Selected Conference Papers of the First Symposium on Tectonic Geomorphology of Chinese Geographical Society. Beijing: Science Press, 1984: 182-187.
[3] 孙建中, 严富华, 王庆隆. 琼北地区第四纪地层年代学研究[C]//海南岛北部地震研究文集. 北京: 地震出版社, 1988: 17-25.
SUN Jianzhong, YAN Fuhua, WANG Qinglong. Quaternary chronology of the north Hainan Island[C]//Collection of Seismic research of the north Hainan Island. Beijing: Seismology Press, 1988: 17-25.
[4] 钟石兰. 海南岛西北部早上新世晚期颗石藻类组合的发现及沉积环境分析[J]. 古生物学报, 1994, 33(4):404-415
ZHONG Shilan. First report of uppermost Lower Pliocene calcareous nannofossil assemblage and sedimentary environments from northwestern Hainan Island, China [J]. Acta Palaeontologica Sinica, 1994, 33(4): 404-415.
[5] 曹琼英. 海南岛西北岸三万年前后浅海相地层的发现及其意义[J]. 南京大学学报:自然科学, 1986, 22(3):545-550
CAO Qiongying. Marine strata around coast of northwest part of Hainan Island [J]. Journal of Nanjing University:Natural Science, 1986, 22(3): 545-550.
[6] 王颖, 周旅复. 海南岛西北部火山海岸的研究[J]. 地理学报, 1990, 45(3):321-330 doi: 10.3321/j.issn:0375-5444.1990.03.008
WANG Ying, ZHOU Lüfu. The volcanic coast in the area of northwest Hainan Island [J]. Acta Geographica Sinica, 1990, 45(3): 321-330. doi: 10.3321/j.issn:0375-5444.1990.03.008
[7] 姚衍桃, 詹文欢, 孙金龙, 等. 海南岛西北部莲花山周缘海相地层的区内对比及意义[J]. 海洋地质与第四纪地质, 2009, 29(3):43-51
YAO Yantao, ZHAN Wenhuan, SUN Jinlong, et al. Correlation and implication of marine strata around Lianhua Mountain in northwest Hainan Island [J]. Marine Geology & Quaternary Geology, 2009, 29(3): 43-51.
[8] 何国富, 张连中. 海南洋浦湾北侧更新世半成岩胶结砂层工程特性分析[J]. 勘察科学技术, 2014(1):35-39
HE Guofu, ZHANG Lianzhong. Analysis of engineering characters for pleistocene epoch half-diagenesis cemented sand in north of Hainan Yangpu Bay [J]. Site Investigation Science and Technology, 2014(1): 35-39.
[9] Rink W J, Bartoll J, Schwarcz H P, et al. Testing the reliability of ESR dating of optically exposed buried quartz sediments [J]. Radiation Measurements, 2007, 42(10): 1618-1626. doi: 10.1016/j.radmeas.2007.09.005
[10] 尹功明, 江亚风, 俞岗, 等. 晚第四纪以来香山-天景山断裂左旋走滑量研究[J]. 地震地质, 2013, 35(3):472-479 doi: 10.3969/j.issn.0253-4967.2013.03.002
YIN Gongming, JIANG Yafeng, YU Gang, et al. The study of the left-lateral displacement on the Xiangshan-Tianjingshan fault in Late Quaternary [J]. Seismology and Geology, 2013, 35(3): 472-479. doi: 10.3969/j.issn.0253-4967.2013.03.002
[11] 刘春茹, 尹功明, RAINER G. 石英ESR测年信号衰退特征研究进展[J]. 地球科学进展, 2013, 28(1):24-30 doi: 10.11867/j.issn.1001-8166.2013.01.0024
LIU Chunru, YIN Gongming, RAINER G. Research progress of the resetting features of quartz ESR signal [J]. Advances in Earth Science, 2013, 28(1): 24-30. doi: 10.11867/j.issn.1001-8166.2013.01.0024
[12] 魏传义, 刘春茹, 李长安, 等. 石英ESR法物源示踪: 认识与进展[J]. 地球科学进展, 2017, 32(10):1062-1071 doi: 10.11867/j.issn.1001-8166.2017.10.1062
WEI Chuanyi, LIU Chunru, LI Chang’an, et al. Research advances in ESR provenance tracing methods of quartz in sediments [J]. Advances in Earth Science, 2017, 32(10): 1062-1071. doi: 10.11867/j.issn.1001-8166.2017.10.1062
[13] 魏传义, 刘春茹, 李长安, 等. 石英不同Ti-Li心电子自旋共振信号光晒退特征及其测年意义[J]. 地球环境学报, 2018, 9(6):607-613
WEI Chuanyi, LIU Chunru, LI Chang’an, et al. Bleaching characteristics of quartz electron spin resonance (ESR) signals of multiple Ti-Li centers: Implication for ESR dating [J]. Journal of Earth Environment, 2018, 9(6): 607-613.
[14] 李文朋. 高温烘烤作用对湖相沉积石英ESR信号特征的影响及其年代学意义[D]. 中国地震局地质研究所硕士学位论文, 2018
LI Wenpeng. The ESR signal variation characteristics and its chronological significance for lava baked lacustrine sedimentary[D]. Master Dissertation of Institute of Geology, China Earthquake Administration, 2018.
[15] Duval M, Arnold L J, Rixhon G. Electron spin resonance (ESR) dating in Quaternary studies: evolution, recent advances and applications [J]. Quaternary International, 2020, 556: 1-10. doi: 10.1016/j.quaint.2020.07.044
[16] 李振军, 牟雪松, 范育新. 石英Al心和Ti-Li心电子自旋共振信号测年结果对比: 以腾格里沙漠白碱湖地区BJ14钻孔中沉积物为例[J]. 地球环境学报, 2018, 9(6):589-598
LI Zhenjun, MOU Xuesong, FAN Yuxin. Comparison of the electron spin resonance (ESR) dating results between Al signals and Ti-Li signals in quartz grains: a case from sediments of BJ14 core drilled from the Baijian Lake in the Tengger Desert [J]. Journal of Earth Environment, 2018, 9(6): 589-598.
[17] Beerten K, Verbeeck K, Laloy E, et al. Electron spin resonance (ESR), optically stimulated luminescence (OSL) and terrestrial cosmogenic radionuclide (TCN) dating of quartz from a Plio-Pleistocene sandy formation in the Campine area, NE Belgium [J]. Quaternary International, 2020, 556: 144-158. doi: 10.1016/j.quaint.2020.06.011
[18] Fan Y X, Li Z J, Yang G L, et al. Sedimentary evidence and luminescence and ESR dating of Early Pleistocene high lake levels of Megalake Tengger, Northwestern China [J]. Journal of Quaternary Science, 2020, 35(8): 994-1006. doi: 10.1002/jqs.3246
[19] Gao L, Yin G M, Liu C R, et al. Natural sunlight bleaching of the ESR titanium center in quartz [J]. Radiation Measurements, 2009, 44(5-6): 501-504. doi: 10.1016/j.radmeas.2009.03.033
[20] Guzmán O, Díaz M, Campos C, et al. First ESR dating of quaternary sediments in Mérida Andes, Western Venezuela [J]. Journal of South American Earth Sciences, 2021, 106: 103089. doi: 10.1016/j.jsames.2020.103089
[21] Bahain J J, Voinchet P, Vietti A, et al. ESR/U-series and ESR dating of several Middle Pleistocene Italian sites: comparison with 40Ar/39Ar chronology [J]. Quaternary Geochronology, 2021, 63: 101151. doi: 10.1016/j.quageo.2021.101151
[22] Arnold L J, Duval M, Demuro M, et al. OSL dating of individual quartz ‘supergrains’ from the Ancient Middle Palaeolithic site of Cuesta de la Bajada, Spain [J]. Quaternary Geochronology, 2016, 36: 78-101. doi: 10.1016/j.quageo.2016.07.003
[23] Beerten K, Lomax J, Clémer K, et al. On the use of Ti centres for estimating burial ages of Pleistocene sedimentary quartz: multiple-grain data from Australia [J]. Quaternary Geochronology, 2006, 1(2): 151-158. doi: 10.1016/j.quageo.2006.05.037
[24] Richter M, Tsukamoto S, Long H. ESR dating of Chinese loess using the quartz Ti centre: a comparison with independent age control [J]. Quaternary International, 2020, 556: 159-164. doi: 10.1016/j.quaint.2019.04.003
[25] 张威, 毕伟力, 刘蓓蓓, 等. 基于年代学约束的白马雪山晚第四纪冰川作用[J]. 第四纪研究, 2015, 35(1):29-37
ZHANG Wei, BI Weili, LIU Beibei, et al. Geochronology constrainted on late Quaternary Glaciation of Baimaxue Shan [J]. Quaternary Sciences, 2015, 35(1): 29-37.
[26] 柴乐, 刘亮, 许姗, 等. 以ESR测年为约束的中国第四纪冰期序列研究[J]. 国土与自然资源研究, 2018(5):62-65 doi: 10.3969/j.issn.1003-7853.2018.05.019
CHAI Le, LIU Liang, XU Shan, et al. Quaternary glaciation of China, constrained by electron spin resonance dating [J]. Territory & Natural Resources Study, 2018(5): 62-65. doi: 10.3969/j.issn.1003-7853.2018.05.019
[27] Bartz M, Duval M, Brill D, et al. Testing the potential of K-feldspar pIR-IRSL and quartz ESR for dating coastal alluvial fan complexes in arid environments [J]. Quaternary International, 2020, 556: 124-143. doi: 10.1016/j.quaint.2020.03.037
[28] 彼得·马蒂尼, 朱大奎, 高学田, 等. 海南岛海岸景观与土地利用[M]. 南京: 南京大学出版社, 2004: 81-94.
MARTINI I P, ZHU Dakui, GAO Xuetian, et al. Coastal Landscape and Landuse Hainan Island, China[M]. Nanjing: Nanjing University Press, 2004: 81-94.
[29] 葛同明, 陈文寄, 徐行, 等. 雷琼地区第四纪地磁极性年表: 火山岩钾-氩年龄及古地磁学证据[J]. 地球物理学报, 1989, 32(5):550-558 doi: 10.3321/j.issn:0001-5733.1989.05.007
GE Tongming, CHEN Wenji, XU Xing, et al. The geomagnetic polarity time scale of Quaternary for Leichiong region: the K-Ar dating and palaeomagnetic evidences from igneous rocks [J]. Chinese Journal of Geophysics, 1989, 32(5): 550-558. doi: 10.3321/j.issn:0001-5733.1989.05.007
[30] 冯国荣. 华南沿海晚新生代玄武岩基本特征及其与构造环境的关系[J]. 中山大学学报论丛, 1992(1):93-103
FENG Guorong. Basic characteristics and relationship to tectonic environment of the Late Cenozoic basalts along the coast of South China Sea [J]. Supplemlnt to the Journal of Sunyatsen University, 1992(1): 93-103.
[31] 黄镇国, 蔡福祥, 韩中元, 等. 雷琼第四纪火山[M]. 北京: 科学出版社, 1993: 1-281.
HUANG Zhenguo, CAI Fuxiang, HAN Zhongyuan, et al. Leiqiong Quaternary Volcano[M]. Beijing: Science Press, 1993: 1-281.
[32] Ho K S, Chen J C, Juang W S. Geochronology and geochemistry of late Cenozoic basalts from the Leiqiong area, southern China [J]. Journal of Asian Earth Sciences, 2000, 18(3): 307-324. doi: 10.1016/S1367-9120(99)00059-0
[33] 樊祺诚, 孙谦, 李霓, 等. 琼北火山活动分期与全新世岩浆演化[J]. 岩石学报, 2004, 20(3):533-544 doi: 10.3969/j.issn.1000-0569.2004.03.017
FAN Qicheng, SU Qian, LI Ni, et al. Periods of volcanic Activity and magma evolution of Holocene in North Hainan Island [J]. Acta Petrologica Sinica, 2004, 20(3): 533-544. doi: 10.3969/j.issn.1000-0569.2004.03.017
[34] 王宝灿, 陈沈良, 龚文平, 等. 海南岛港湾海岸的形成与演变[M]. 北京: 海洋出版社, 2006: 161-162
.WANG Baocan, CHEN Shenliang, GONG Wenping, et al. The Formation and Evolution of the Embayment Coasts of Hainan Island[M]. Beijing: Ocean Press, 2006: 161-162.
[35] 赵小明, 姚华舟, 裴毅俊, 等. 海南儋州兰洋地区发现泥盆纪地层: 来自锆石U-Pb年龄的证据[J]. 地质通报, 2020, 39(6):818-826 doi: 10.12097/j.issn.1671-2552.2020.06.003
ZHAO Xiaoming, YAO Huazhou, PEI Yijun, et al. The discovery of Devonian strata in Lanyang area, Danzhou, Hainan Province: evidence from the zircon U-Pb ages [J]. Geological Bulletin of China, 2020, 39(6): 818-826. doi: 10.12097/j.issn.1671-2552.2020.06.003
[36] 海南省地质调查院. 中国区域地质志: 海南志[M]. 北京: 地质出版社, 2017
Hainan Geological Survey Institute. Regional Geology of China（Hainan ）[M]. Beijing: Geological Publishing House, 2017.
[37] 张仲英, 刘瑞华, 韩中元. 海南岛沿海的第四纪地层[J]. 热带地理, 1987, 7(1):54-64
ZHNAG Zhongying, LIU Ruihua, HAN Zhongyuan. The quaternary stratigraphy along the coastal area of Hainan Island [J]. Tropical Geography, 1987, 7(1): 54-64.
[38] Liu C R, Yin G M, Zhang H P, et al. ESR geochronology of the Minjiang River terraces at Wenchuan, eastern margin of Tibetan Plateau, China [J]. Geochronometria, 2013, 40(4): 360-367. doi: 10.2478/s13386-013-0129-2
[39] 刘春茹, 尹功明, 高璐, 等. 水相沉积物石英Ti心ESR测年可靠性初探[J]. 核技术, 2009, 32(2):110-112 doi: 10.3321/j.issn:0253-3219.2009.02.008
LIU Chunru, YIN Gongming, GAO Lu, et al. Reliability of quartz Ti-center in ESR dating of fluvial sediment [J]. Nuclear Techniques, 2009, 32(2): 110-112. doi: 10.3321/j.issn:0253-3219.2009.02.008
[40] 王萍, 李建平, 王建存, 等. 四川昔格达组地层的石英Ti心ESR测年及与磁性地层剖面的对比[J]. 核技术, 2011, 34(2):111-115
WANG Ping, LI Jianping, WANG Jiancun, et al. Quartz Ti-center in ESR dating of Xigeda formation in Sichuan and contrast with magnetic stratigraphic profiles [J]. Nuclear Techniques, 2011, 34(2): 111-115.
[41] 业渝光, 和杰, 刁少波, 等. 晚更新世海岸风成砂ESR年龄的研究[J]. 海洋地质与第四纪地质, 1993, 13(3):85-90
YE Yuguang, HE Jie, DIAO Shaobo, et al. Study on ESR ages of late Pleistocene coastal Aeolian sands [J]. Marine Geology & Quaternary Geology, 1993, 13(3): 85-90.
[42] 魏传义. 石英ESR法在长江流域沉积物源示踪中的探讨及应用[D]. 中国地质大学博士学位论文, 2019.
WEI Chuanyi. Multiple ESR center signals and crystallinity index of quartz: shed new light on Yangtze River sediments provenance tracing[D]. Doctor Dissertation of China University of Geosciences, 2019.
[43] 邱登峰, 云金表, 刘全有, 等. 断层电子自旋共振定年中石英信号强度的影响因素分析[J]. 岩矿测试, 2017, 36(1):22-31
QIU Dengfeng, YUN Jinbiao, LIU Quanyou, et al. The analysis of influence factors on electron spin resonance signal intensity in dating of quartz in fault lines [J]. Rock and Mineral Analysis, 2017, 36(1): 22-31.
[44] 周逢春. 潮滩沉积物中石英顺磁中心ESR信号研究[D]. 华东师范大学硕士学位论文, 2014.
ZHOU Fengchun. Study on the ESR signals of magnetic centers in quartz in tidal flat sediments[D]. Master Dissertation of East China Normal University, 2014.
-
图(4)
表(1)
计量
- 文章访问数: 1809
- PDF下载数: 57
- 施引文献: 0