Chronology, geochemistry and tectonic significance of middle stage of Late Cretaceous adakite in Zhazuo aera, Tibet
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摘要:
为解释南冈底斯晚白垩世埃达克质岩石成因及其地球动力学机制,本文对西藏扎囊县札佐地区二长花岗岩开展了锆石U-Pb年代学、Hf同位素和全岩地球化学分析。札佐二长花岗岩锆石U-Pb定年为80.43±0.62 Ma,其SiO2为66.19%~66.84%,Al2O3为15.17%~15.48%,MgO为1.67%~1.91%,Mg#为47.4~51.5,K2O为3.86%~4.09%,A/CNK=0.91~1.01,属准铝质高钾钙碱性岩石。岩石轻稀土富集明显,高Sr(492×10−6~670.2×10−6),低Y(8.27×10−6~14.99×10−6),Yb(1.07×10−6~1.79×10−6),高Sr/Y(35.0~81.0),高La/Yb(17.4~21.4),弱负Eu异常,具埃达克岩地球化学特征。相对富集大离子亲石元素(LILE),亏损高场强元素(HFSE)和重稀土。锆石εHf(t)值为10.5~14.1,单阶段Hf模式年龄(tDM1)为184.8~326.1 Ma,平均为203.4 Ma,二阶段Hf模式年龄(tDM2)为247.2~476.0 Ma,平均为287.1 Ma,略大于侵位年龄,指示岩浆物质来源于俯冲洋壳,并可能卷入俯冲沉积物。岩石中地幔组分印记Mg#值和相容元素Ni、Cr含量较高,表明熔体在上升过程中与上覆地幔楔发生反应。研究分析表明,在新特提斯洋洋脊俯冲作用下,高温热流透过板片窗导致洋壳(及俯冲沉积物)部分熔融形成札佐埃达克质二长花岗岩。同时表明,在80 Ma左右,新特提斯洋仍处于洋脊俯冲阶段。
Abstract:In order to explain late Cretaceous adaktic rocks in South Gangdese and the geodynamic mechanism, we present zircon U-Pb chronology, Lu-Hf isotope and geochemistry analysis for the monzogranite from the Zhazuo area, Zhanang, Tibet. The zircon U-Pb dating yieldes 80.43±0.62 Ma for the Zhazuo monzogranite. The rocks are high-K Calc-alkaline metaluminous, with SiO2 (66.19%~66.84%), Al2O3 (15.17%~15.48%), MgO (1.67%~1.91%), Mg# (47.4~51.5), K2O (3.86%~4.09%), A/CNK (0.91~1.01). The rocks show typical adakitic features, with strongly riched in LREE, high Sr (492×10−6~670.2×10−6), low Y (8.27×10−6~14.99×10−6) and Yb (1.07×10−6~1.79×10−6), high Sr/Y (35.0~81.0) and La/Yb (17.4~21.4) and slightly negative Eu anomalies. They are enriched in LILE and depleted in HFSE, HREE. Zircon εHf(t) values range from 10.5 to 14.1, with tDM1 ranging from 184.8 Ma to 326.1 Ma and tDM2 ranging from 247.2 Ma to 476.0 Ma, slightly older than the emplaced age, indicating that the magma is derived from subducted oceanic crust probably with some subducted sediments.The Mg# value of the mantle component imprint in the rock and the content of compatible elements Ni and Cr are high, indicating that the melts have interacted with the mantle during ascent. Research analysis shows that the high heat flow flows through the slab window, which induce partial melting of oceanic crust and some subducted sediments, and forms the adakitic monzogranite in the Zhazuo area under the geodynamic setting of ridge subduction. It further indicates that Neo-Tethys is still in the ridge subduction stage at about 80 Ma.
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Key words:
- south Gangdese /
- Late Cretaceous /
- adakite /
- Lu-Hf /
- Ridge subduction
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图 1 青藏高原及冈底斯构造简图(a; 据朱弟成等,2009)和札佐地区地质图(b)
Figure 1.
图 4 二长花岗岩稀土元素配分曲线(a)和微量元素配分曲线(b)(稀土元素标准化值据Boynton and William,1984;微量元素标准化值据McDonough and Sun,1995)
Figure 4.
图 7 札佐二长花岗岩Y-Sr/Y(a)和YbN-(La/Yb)N(b)判别图解(据Defant and Drummond, 1990)
Figure 7.
图 9 札佐埃达克岩源区判别图解Yb-SiO2 (a)和MgO-SiO2(b)(据Wang, 2006)
Figure 9.
表 1 二长花岗岩主量、稀土、微量元素分析结果
Table 1. Major elements, REE and trace elements of the monzogranite
样号 ZZ01 ZZ02 ZZ03 ZZ04 样号 ZZ01 ZZ02 ZZ03 ZZ04 SiO2 66.19 66.84 67.56 66.48 Hf 3.12 4.64 4.45 3.69 Al2O3 15.48 15.27 15.23 15.17 Ta 0.69 0.69 0.38 0.89 TiO2 0.52 0.49 0.47 0.56 W 0.33 0.41 0.56 0.47 Fe2O3 1.59 1.82 1.62 1.73 Tl 0.44 0.75 0.66 0.53 FeO 2.05 1.75 1.57 2.05 Pb 11.1 16.6 13.1 11.4 CaO 3.11 2.87 2.4 3.39 Bi 0.07 0.12 0.06 0.055 MgO 1.85 1.81 1.67 1.91 Th 9.84 15.3 5.51 33.2 K2O 3.86 4.09 3.91 3.95 U 2.27 3.82 2.76 8.47 Na2O 3.82 3.49 3.92 3.77 La 23.56 31 21.29 29.38 MnO 0.06 0.06 0.06 0.07 Ce 45.75 61.84 38.57 56.44 P2O5 0.16 0.16 0.14 0.17 Pr 5.87 7.57 4.57 6.63 LOS 1.14 1.19 1.27 0.61 Nd 20.35 27.91 17.2 24.3 ∑ 99.84 99.85 99.82 99.86 Sm 3.42 4.77 2.85 4.16 ALK 7.68 7.58 7.82 7.72 Eu 0.86 1.1 1.1 0.99 K2O/Na2O 1.01 1.17 1 1.05 Gd 2.93 3.85 2.37 3.58 A/NK 1.48 1.5 1.43 1.45 Tb 0.39 0.56 0.33 0.49 A/ CNK 0.96 0.99 1.01 0.91 Dy 2.03 3.03 1.76 2.64 Mg# 47.44 50.84 51.54 48.23 Ho 0.37 0.54 0.32 0.49 Li 10.3 14.8 16.8 14.8 Er 1.08 1.63 0.97 1.44 Be 1.46 1.54 1.44 1.61 Tm 0.19 0.28 0.17 0.22 Sc 7.76 8.53 5.92 9.13 Yb 1.1 1.79 1.07 1.41 V 82.7 88.0 74.2 93.6 Lu 0.16 0.25 0.16 0.23 Cr 33.3 35.0 29.4 31.1 Y 11.89 14.99 8.27 13.17 Co 10.1 10.4 9.9 11.8 ∑REE 119.95 161.1 101 145.56 Ni 18.1 18.4 15.1 16.9 LREE/HREE 4.96 4.99 5.55 5.15 Cu 23.6 23.2 6.15 9.50 (La/Yb)N 14.45 11.73 13.43 14.1 Zn 47.5 47.6 36.9 47.7 δEu 0.81 0.76 1.26 0.77 Ga 15.8 19.4 17.9 19.5 Sr/Y 51.42 35.05 81.04 37.36 Rb 93.3 125 107 113 Th/Ce 0.22 0.25 0.14 0.59 Sr 611 525 670 492 Sm/Nd 0.17 0.17 0.17 0.17 Zr 101 143 141 110 (La/Sm)N 4.33 4.09 4.71 4.44 Nb 9.06 9.34 5.30 8.00 (Gd/Yb)N 2.15 1.75 1.8 2.06 Mo 0.87 0.86 0.93 1.30 Rb/Sr 0.15 0.24 0.16 0.23 Sn 0.87 1.17 0.92 1.13 Nb/Ta 13.16 13.55 13.88 8.99 Cs 1.40 2.88 2.96 4.34 Zr/Hf 32.21 30.85 31.68 29.93 Ba 443 563 713 450 Th/Yb 8.94 8.52 5.15 23.55 注:LOS为烧失量;ALK= Na2O+K2O, A/NK=Al2O3/(Na2O+K2O), A/CNK=Al2O3/(CaO+Na2O+K2O); Mg#=100×Mg/(Mg+Fe); δEu=2EuN/(SmN+GdN),其中N表示球粒陨石标准化。 表 2 二长花岗岩LA-ICP-MS锆石U-Pb分析结果
Table 2. LA-ICP-MS zircon U-Pb dating results of the monzogranite
测点 元素含量(×10−6) Th/U 同位素比值 年龄(Ma) Pb Th U 207Pb/206Pb 1σ 207Pb/235U 1σ 206Pb/238U 1σ 207Pb/206Pb 1σ 207Pb/235U 1σ 206Pb/238U 1σ ZZTW1-1 6.4 340.8 409.5 0.83 0.0471 0.0029 0.0837 0.0054 0.0128 0.0002 58 137 82 5 82 1 ZZTW1-2 3.9 194.7 248.6 0.78 0.0459 0.0028 0.0799 0.0048 0.0127 0.0002 — — 78 5 82 1 ZZTW1-3 12.2 595.0 782.6 0.76 0.0478 0.0019 0.0844 0.0034 0.0128 0.0001 87 102 82 3 82 1 ZZTW1-4 7.6 337.7 513.0 0.66 0.0473 0.0016 0.0833 0.0030 0.0128 0.0001 65 81 81 3 82 1 ZZTW1-5 6.3 306.2 442.3 0.69 0.0507 0.0020 0.0861 0.0037 0.0122 0.0002 228 58 84 3 78 1 ZZTW1-6 5.5 281.4 375.4 0.75 0.0548 0.0026 0.0929 0.0043 0.0123 0.0002 467 106 90 4 79 1 ZZTW1-7 13.4 959.5 827.1 1.16 0.0497 0.0017 0.0859 0.0029 0.0126 0.0002 189 80 84 3 81 1 ZZTW1-8 4.6 265.6 365.4 0.73 0.0593 0.0084 0.0866 0.0111 0.0108 0.0003 589 313 84 — 70 2 ZZTW1-9 4.5 229.6 314.3 0.73 0.0488 0.0026 0.0832 0.0042 0.0125 0.0002 139 124 81 4 80 1 ZZTW1-10 5.4 272.0 384.1 0.71 0.0518 0.0023 0.0890 0.0040 0.0125 0.0002 276 104 87 4 80 1 ZZTW1-11 18.5 859.3 1295.1 0.66 0.0469 0.0014 0.0800 0.0023 0.0124 0.0001 43 67 78 2 79 1 ZZTW1-12 10.0 454.6 714.0 0.64 0.0573 0.0053 0.0951 0.0092 0.0120 0.0002 502 206 92 9 77 1 ZZTW1-13 6.7 382.3 436.6 0.88 0.0520 0.0044 0.0903 0.0074 0.0126 0.0003 283 201 88 7 81 2 ZZTW1-14 3.0 167.1 191.5 0.87 0.0495 0.0031 0.0847 0.0052 0.0125 0.0002 169 146 83 5 80 1 ZZTW1-15 3.8 194.0 255.9 0.76 0.0492 0.0031 0.0835 0.0052 0.0124 0.0002 167 −51 81 5 79 1 ZZTW1-16 8.3 494.1 529.7 0.93 0.0515 0.0025 0.0888 0.0042 0.0126 0.0001 261 113 86 4 81 1 ZZTW1-17 8.7 551.4 508.8 1.08 0.0523 0.0029 0.0928 0.0055 0.0128 0.0002 298 128 90 5 82 1 ZZTW1-18 7.0 364.4 460.7 0.79 0.0467 0.0032 0.0802 0.0053 0.0125 0.0002 35 156 78 5 80 1 ZZTW1-19 5.6 285.3 350.9 0.81 0.0520 0.0026 0.0915 0.0046 0.0128 0.0002 287 115 89 4 82 1 ZZTW1-20 4.2 227.3 250.9 0.91 0.0475 0.0051 0.0826 0.0081 0.0129 0.0003 72 237 81 8 83 2 表 3 二长花岗岩锆石Hf同位素分析结果
Table 3. Zircon Hf isotopic analysis results of the monzogranite
测点号 t(Ma) 176Yb/177Hf 176Lu/177Hf 176Hf/177Hf 2σ εHf(t) tDM1(Ma) tDM2(Ma) fLu/Hf ZZTW1-2 81.65 0.016990 0.000700 0.283117 0.000069 14.0 188.1 253.2 −0.98 ZZTW1-4 81.70 0.016298 0.000716 0.283020 0.000043 10.5 326.5 476.0 −0.98 ZZTW1-5 78.37 0.022818 0.000902 0.283119 0.000277 13.9 187.6 253.4 −0.97 ZZTW1-7 80.62 0.020354 0.000822 0.283100 0.000040 13.3 213.7 294.3 −0.98 ZZTW1-10 80.12 0.021959 0.001043 0.283065 0.000042 12.0 265.5 376.1 −0.97 ZZTW1-11 79.39 0.033991 0.001611 0.283063 0.000030 11.9 272.4 382.8 −0.95 ZZTW1-13 80.92 0.019700 0.000787 0.283061 0.000039 11.9 269.1 383.4 −0.98 ZZTW1-15 79.41 0.022569 0.000905 0.283037 0.000035 11.1 303.4 438.3 −0.97 ZZTW1-16 80.57 0.017773 0.000784 0.283062 0.000027 12.0 267.3 380.8 −0.98 ZZTW1-18 80.30 0.017272 0.000738 0.283027 0.000027 10.8 316.2 459.9 −0.98 ZZTW1-19 82.17 0.018928 0.000776 0.283120 0.000039 14.1 184.8 247.2 −0.98 ZZTW1-20 82.83 0.018108 0.000779 0.283070 0.000027 12.3 255.8 360.9 −0.98 -
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