Study on Process Mineralogy of a Copper-Nickel Polymetallic Sulfide Ore
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摘要:
本文研究了某铜镍多金属硫化矿的工艺矿物学,结果表明该矿石原矿中主要有用矿物为镍黄铁矿和黄铜矿,主要金属硫化物为磁黄铁矿,少量黄铁矿。脉石矿物主要为蛇纹石、橄榄石和阳起石等镁硅酸盐矿物。矿石具有较高的综合回收利用价值,建议开展对该矿铂、钯、金、银的赋存状态研究和相应的选矿工艺研究,以最大限度地回收该矿中贵金属矿物。
Abstract:In this study, the process mineralogy of a copper-nickel polymetallic sulfide ore was studied. Results show that the main useful minerals in the ore are nickel-pyrite and chalcopyrite. The main metal sulfides are pyrrhotite and a small amount of pyrite. The gangue minerals are mainly magnesium silicate minerals such as serpentine, olivine and actinolite. The ore has a high comprehensive recycling value. It is recommended to carry out research on the occurrence state of platinum, palladium, gold and silver and the corresponding beneficiation process to maximize the recovery of precious metal minerals in the ore.
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Key words:
- Copper-nickel polymetallic sulfide ore /
- Process mineralogy /
- Serpentine
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表 1 原矿多元素分析结果/%
Table 1. Multi-element analysis results of raw ore
Ni Cu Co *Au *Ag *Pt *Pd Zn S 0.495 0.21 0.023 0.12 4.3 0.09 0.26 0.07 2.24 Fe As CaO Al2O3 SiO2 TiO2 MgO K2O Na2O 10.94 0.004 5.89 6.67 39.96 0.50 22.61 0.27 0.25 *单位为g/t。 表 2 原矿主要矿物及含量/%
Table 2. Raw ore minerals and content
镍黄铁矿 黄铜矿 磁黄铁矿 黄铁矿 蛇纹石 绿泥石 橄榄石 阳起石 石英 1.020 0.524 3.784 0.177 48.083 1.669 5.890 17.735 0.345 长石 金云母 白云母 斜方辉石 普通角闪石 黝帘石 滑石 方解石 磁铁矿 3.735 1.440 0.600 5.926 0.43 1.795 1.448 1.597 1.728 表 3 主要矿物的粒度分布
Table 3. Particle size distribution of main minerals
粒度/mm 全硫化物 镍黄铁矿 黄铜矿 磁黄铁矿 +2.56 5.81 0 0 5.23 -2.56+1.28 12.34 0 0 12.64 -1.28+0.64 14.88 0.35 0.51 23.58 -0.64+0.32 21.42 8.81 3.74 14.21 -0.32+0.16 22.69 18.93 12.61 13.73 -0.16+0.08 11.43 19.98 22.40 11.31 -0.08+0.04 5.10 17.76 23.80 7.74 -0.04+0.02 3.21 16.37 17.47 5.60 -0.02+0.01 1.70 10.15 11.46 3.40 -0.01 1.41 7.65 7.01 2.56 合计 100.00 100.00 100.00 100.00 表 4 镍在各矿物中的平衡分配
Table 4. Balanced distribution of nickel in various minerals
矿物 矿物含量/% Ni/% 占有率/% 镍黄铁矿 1.020 33.95 68.98 磁黄铁矿 3.784 2.38 17.94 黄铜矿 0.877 0.42 0.44 脉石 94.672 0.067 12.64 合计 100.000 0.502 100.00 表 5 铜在各矿物中的平衡分配
Table 5. Balanced distribution of copper in various minerals
矿物 矿物含量/% Cu/% 占有率/% 镍黄铁矿 1.020 0.020 0.10 磁黄铁矿 3.784 0.370 6.79 黄铜矿 0.877 33.920 86.22 脉石 94.672 0.015 6.89 合计 100.000 0.206 100.00 表 6 钴在各矿物中的平衡分配
Table 6. Balanced distribution of cobalt in various minerals
矿物 矿物含量/% Co/% 占有率/% 镍黄铁矿 1.020 1.240 56.02 磁黄铁矿 3.784 0.083 13.91 黄铜矿 0.877 0.049 1.14 脉石 94.672 0.007 28.93 合计 100.000 0.023 100.00 -
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