Geochronology and Geochemistry of the Jiachadui Ganodiorite in Xizang and its Geological Implications
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摘要:
这是一篇地球科学领域的论文。冈底斯带岩浆岩是青藏高原基础地质研究中的热门问题。现已有的研究主要集中在中新生代,本文对早古生代代表岩体加查堆似斑状黑云母二长花岗闪长岩利用LA-ICP-MS锆石U-Pb测年方法,结合岩石地球化学特征及各类图解法对加查堆花岗岩物源及区域构造属性进行分析,经研究表明岩石具有富铝(SiO2平均含量68.89%)、高碱(Na2O+K2O平均含量6.26%)、富钾(K2O/Na2O=1.03)、低TiO2(平均为0.50%)和准铝质(铝饱和指数A/CNK=0.933~1.033,平均0.991)的高钾钙碱性岩系特点。稀土元素表现Eu处呈负异常明显,为Eu亏损型,Ce具弱负异常;微量元素显示大离子亲石元素Rb、Th、Nd、La、K富集;高场强元素Nb、Ba、U、Ta、Ce、Sm、Ti亏损特征;反映了岩浆来源壳幔混合型,并有俯冲洋壳熔融存在。锆石LA-ICP-MS U-Pb同位素年龄为345.3±1.8 Ma,其形成时代为早石炭世。投点均落入I型花岗岩区,图解显示其形成于大陆岛弧环境,岩石经历了从板块碰撞前→同碰撞造山过程,显示了岩浆演化过程较长;火山岩组合及其地球化学特征标志着岛弧产生(初始岛弧)→发展(早期岛弧)→成熟(成熟岛弧)的演变过程。
Abstract:This is an article in the field of earth sciences. Magmatic rocks of the Gondwana Belt are one of the most popular problems in basic geological research on the Xizang-Qinghai Plateau. In this paper, we analyze the physical origin and regional tectonic properties of the Gachatai granite using LA-ICP-MS zircon U-Pb dating method, combined with the geochemical characteristics of the rocks and various graphical methods. The rocks are characterized by high alkali (average Na2O+K2O content of 6.26%), potassium (K2O/Na2O=1.03), low TiO2 (average 0.50%) and quasi-aluminous (aluminum saturation index A/CNK=0.933~1.033, average 0.991) high potassium-calcium-alkaline rock system. Rare earth elements show negative anomalies at Eu, which is the Eu-deficient type, and Ce has weak negative anomalies; trace elements show enrichment of large ion-parental elements Rb, Th, Nd, La and K; high field strength elements Nb, Ba, U, Ta, Ce, Sm and Ti are deficient; reflecting the mixed crust-mantle type of magma origin and the presence of subduction oceanic crustal melting. The zircon LA-ICP-MS U-Pb isotopic age is (345.3±1.8) Ma, and its formation age is Early Carboniferous. The analysis of the regional geological data suggests that this magmatic event is a product of the formation of the northern part of the eastern Gondwana continent after the breakup of the Rodinia supercontinent. The project points go to I-type granite, the discriminant diagrams indicate it’s formed from continental island arc, going through time before plate collision to co-collisional orogenic movement, which indicates a long period time of magmatic evolution; the rock geochemical characteristics show the environment of magmatic evolution changed from the start of island arc(primary island arc)-development(early stage island arc)-maturement(full-grown island arc).
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Key words:
- Earth sciences /
- LA-ICPMS U-Pb dating /
- Zircon trace elements /
- Jiacha /
- Early Carboniferous /
- Granitic amphibolite
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图 8 加查堆岩体构造环境判别[28]
Figure 8.
图 9 加查堆岩体R1-R2构造环境判别[28]
Figure 9.
图 10 加查堆岩体 Y+Nb-Rb 构造环境判别[28]
Figure 10.
表 1 加查堆岩体主量元素(%)标准矿物及特征参数表及微量元素(g/t)和稀土元素(g/t)分析数据
Table 1. 1 Major element compositions andtrace element and rare-earth element compositions in Jiachadui rock mass
岩体 样品号 岩性 化学成分/% SiO2 TiO2 Al2O3 Fe2O3 FeO MnO MgO CaO Na2O K2O P2O5 CO2 H2O+ H2O- ∑ 加查堆
岩体P1304/2-1 似斑状黑云
母二长花
岗闪长岩68.68 0.51 14.03 1.85 2.62 0.032 1.39 2.68 2.96 3.55 0.12 0.44 1.12 0.19 100.172 P1304/6-2 68.54 0.46 14.45 0.82 3.46 0.047 1.12 3.86 3.33 2.76 0.12 0.27 0.38 0.01 99.627 P1304/8-1 69.45 0.53 14.01 0.80 3.22 0.041 1.43 3.05 2.99 3.19 0.11 0.26 0.86 0.01 99.951 样品号 CIPW标准矿物及含量/% 特征参数 Or Ab An C Di Hy Q Ap σ A·R A/CNK DI SI A/MF C/MF P1304/2-1 21.22 25.33 10.01 1.71 - 6.12 30.67 0.28 1.64 2.28 1.033 77.22 11.24 1.46 0.51 P1304/6-2 16.43 28.38 16.45 - 0.43 7.63 27.68 0.28 1.45 2 0.933 72.49 9.75 1.64 0.8 P1304/8-1 19.02 25.53 13.06 0.9 - 8.09 30.35 0.26 1.44 2.14 1.007 74.9 12.3 1.52 0.6 岩体 样品号 岩性 微量元素含量/(g/t) Rb Sr Zr Nb Th Pb Ga Zn Cu Ni V Cr Hf Sc Ta Co U Ba 加查堆
岩体P1304/2-1 似斑状黑云
母二长花
岗闪长岩170.6 196 178.4 14.0 15.4 18.2 16.8 72.8 15.4 4.05 69.3 18.5 9.42 11.8 1.24 9.18 1.44 508.3 P1304/6-2 131.8 269 174.5 16.4 15.5 25.1 17.6 76.8 9.43 3.28 71.6 15.8 12.7 11.9 1.46 9.17 2.96 444.6 P1304/8-1 126.2 221 168.1 13.7 16.4 25.5 17.7 68.6 6.38 3.17 59.9 16.3 10.0 10.6 1.18 8.11 3.58 517.7 样品号 稀土元素含量/(g/t) 特征参数 La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Y ΣREE LREE HREE LREE/HREE δEu δCe (La/Yb)N P1304/2-1 45.6 80.6 9.09 32.3 5.98 1.06 6.02 1.13 6.45 1.46 4.37 0.70 4.45 0.63 45.2 199.84 174.63 25.21 6.93 0.53 0.91 7.35 P1304/6-2 41.8 73.3 8.46 30.2 5.65 0.97 5.69 1.00 6.14 1.44 4.35 0.73 4.58 0.71 45.1 185.02 160.38 24.64 6.51 0.52 0.90 6.55 P1304/8-1 45.1 78.2 8.88 31.3 5.48 0.98 5.41 0.95 5.57 1.29 3.88 0.66 4.09 0.63 40.3 192.42 169.94 22.48 7.56 0.54 0.90 7.91 表 2 加查堆岩体锆石LA-ICP-MS U-Pb同位素分析结果
Table 2. LA-ICP-MS U-Pb isotopic data of zircon from Jiachadui rock mass
样品 含量(g/t) Th/U 同位素比值 年龄/Ma 232Th 238U 207Pb/206Pb 1σ 207Pb/235U 1σ 206Pb/238U 1σ 207Pb/206Pb 1σ 207Pb/235U 1σ 206Pb/238U 1σ JCD2-TW1 1195 5361 0.22 0.0534 0.0012 0.4062 0.0102 0.0547 0.0008 346 50 346 7 343 5 JCD2-TW2 827 3833 0.22 0.0524 0.0011 0.3981 0.0087 0.0548 0.0005 302 50 340 6 344 3 JCD2-TW3 1322 5378 0.25 0.0530 0.0012 0.4025 0.0102 0.0546 0.0007 328 56 343 7 342 4 JCD2-TW4 923 4122 0.22 0.0540 0.0012 0.4172 0.0097 0.0557 0.0005 369 52 354 7 350 3 JCD2-TW5 1322 5370 0.25 0.0538 0.0012 0.4069 0.0094 0.0546 0.0007 361 44 347 7 343 4 JCD2-TW6 1030 4371 0.24 0.0542 0.0013 0.4135 0.0098 0.0550 0.0005 389 54 351 7 345 3 JCD2-TW7 1379 5699 0.24 0.0528 0.0012 0.4019 0.0099 0.0549 0.0006 320 54 343 7 345 4 JCD2-TW8 1456 5634 0.26 0.0537 0.0013 0.4072 0.0102 0.0548 0.0006 367 56 347 7 344 4 JCD2-TW9 1162 4762 0.24 0.0531 0.0014 0.4095 0.0113 0.0555 0.0006 332 59 348 8 348 4 JCD2-TW10 1099 4196 0.26 0.0531 0.0012 0.4079 0.0095 0.0553 0.0006 332 52 347 7 347 4 JCD2-TW11 1034 3317 0.31 0.0568 0.0015 0.4341 0.0110 0.0552 0.0006 483 53 366 8 346 4 JCD2-TW12 1100 4387 0.25 0.0559 0.0013 0.4301 0.0104 0.0553 0.0006 456 52 363 7 347 3 JCD2-TW13 1347 5154 0.26 0.0535 0.0012 0.4098 0.0091 0.0551 0.0004 350 52 349 7 346 3 JCD2-TW14 1538 5990 0.26 0.0532 0.0012 0.4074 0.0094 0.0549 0.0006 345 52 347 7 345 4 JCD2-TW15 1377 5588 0.25 0.0526 0.0013 0.4030 0.0099 0.0548 0.0006 322 56 344 7 344 4 表 3 加查堆岩体和邻区其他典型类型火山岩微量元素对比
Table 3. Trace element comparison between Jiachadui rock mass and adjacent areas
岩石类型 Co Cr Zr V Sc Nb Y Zr/Y Sc/Cr Cr/V Rb/Sr Ba/Rb Ba/Sr 加查堆岩体闪长岩 8.82 16.9 174 66.93 11.43 14.7 43.53 4 0.68 0.25 0.62 3.43 2.14 羌塘安山岩[29] 20.85 33.27 141.09 225.07 27.85 9.28 19.83 7.11 0.84 0.15 0.097 11.45 1.11 啊扎侵入体闪长岩[30] 18.32 16.69 105.32 88.48 - 5.6 8.66 12.16 - 0.19 0.08 8.70 0.71 丝波绒曲花岗闪长岩[31] 11.8 14 136 89.8 7.81 4.27 12.3 11.06 0.56 0.16 0.10 9.81 0.97 -
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