Geochemical characteristics, zircon U-Pb age and metallogenic significance of Chalong granites in the Gangdise Belt of Tibet
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摘要:
查隆花岗岩位于中冈底斯带火山岩浆弧，主要岩性为黑云花岗闪长岩、花岗闪长岩，其中中细粒花岗闪长岩锆石206Pb/238U年龄为89.88±0.55Ma(95%置信度，n=24，MSWD=0.43)，中粒黑云花岗闪长岩锆石206Pb/238U年龄为86.6±1.0Ma(95%置信度，n=30，MSWD=0.64)。岩石化学特征表明，查隆花岗岩为高钾钙碱性的偏铝质Ⅰ型花岗岩，稀土元素配分曲线呈右倾型，岩浆经过一定程度的分异；微量元素Ti、Nb、P相对亏损。该岩体为雅鲁藏布江洋壳单向俯冲作用的结果，形成于火山弧环境，为具有壳幔混合特征的中酸性岩浆的产物。与该岩体密切相关的查隆磁铁矿成因类型为矽卡岩型-热液叠加改造型，与区域上发现的矿床有极其相似的成矿地质背景。
Abstract:The Chalong granite is located in volcanic magma arc of the Mid-Gangdise belt. The granite petrologically consists of biotite granodiorite and granodiorite; the zircon U-Pb age of fine-grained granodiorite is 89.88±0.55Ma (95% conf., n=24, MSWD=0.43) and that of medium-grained biotite granodiorite is 86.6±1.0Ma (95% conf., n=30, MSWD=0.64). Their petrochemical characteristics indicate that they are high-K calc alkaline peraluminous "Ⅰ" type granite. The REE distribution curves are right-inclines, and the magma experienced differentiation to some extent. The trace elements Ti, Nb and P are relatively deficient. The intrusive rock resulted from the unidirectional subduction of the Yarlung Zangbo River crust, was formed in the volcanic arc environment, and was the product of intermediate acid magma with crust mantle mixing Characteristics. The genetic type of Chalong magnetite mineral deposit closely related to the intrusive rock is skarn hydrothermal superimposition type. Chalong magnetite mineral deposit has a similar metallogenic geological background to the discovered deposits in the area.
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表 1 查隆花岗岩主量、微量和稀土元素分析结果
Table 1. Major, trace and rare earth element compositions of granite in Chalong area
样品号 D1641-1 D1658-1 D1660-1 D1573-1 D1574-2 岩石名称 中细粒花岗闪长岩 细粒黑云母花岗闪长岩 中粒黑云花岗闪长岩 SiO2 66.5 69.19 67.74 65.32 66.74 Al2O3 14.3 14.34 13.75 15.37 15.38 MgO 2.05 1.41 1.89 1.97 1.65 CaO 2.68 2.13 2.55 3.93 3.1 Na2O 3.21 2.36 3.05 3.25 3.23 K2O 4.13 4.71 4.44 2.79 3.01 P2O5 0.2 0.14 0.19 0.18 0.15 MnO 0.14 0.06 0.07 0.11 0.1 TiO2 0.66 0.54 0.61 0.59 0.51 TFe2O3 4.86 3.86 4.47 5.11 4.48 烧失量 2.18 1.7 1.83 0.62 0.97 总计 100.91 100.44 100.59 99.24 99.32 A/NK 1.47 1.6 1.4 1.84 1.79 A/CNK 0.98 1.12 0.95 0.99 1.08 R1 2220 2598 2299 2443 2518 R2 680 588 646 834 729 Y 21.3 21.8 19.7 19.4 16 La 64.2 38.8 60.1 43.7 30 Ce 134 79 122 80 58.2 Pr 13.6 8.54 12.7 8.14 5.96 Nd 47.3 30.1 44.9 29.8 22.3 Sm 6.96 5.67 7.19 5.1 4.06 Eu 1.33 0.99 1.22 1.22 1.1 Gd 6.99 5.64 6.51 4.88 3.71 Tb 0.74 0.66 0.6 0.52 0.46 Dy 3.79 3.96 3.57 3.37 2.75 Ho 0.63 0.65 0.6 0.54 0.47 Er 1.93 2.05 1.89 1.83 1.58 Tm 0.24 0.27 0.28 0.22 0.21 Yb 1.75 2.08 1.77 1.82 1.47 Lu 0.22 0.29 0.24 0.25 0.2 ΣREE 283.38 178.7 263.47 181.39 132.47 LREE 267.09 163.1 248.01 167.96 121.62 HREE 16.29 15.6 15.46 13.43 10.85 LREE/ 16.4 10.46 16.04 12.51 11.21 HREE 26.31 13.38 24.36 17.22 14.64 (La/Yb)N 2.03 4.1 1.72 3.07 4.17 (La/Sm)N 3.82 1.82 1.62 1.61 1.91 (Gd/Lu)N 0.58 0.53 0.53 0.74 0.85 δEu 34287.26 39102.42 36860.88 23162.58 24989.02 K 3956.7 3237.3 3656.95 3537.05 3057.45 Ti 981.9 600.2 662.9 828 626 P 707.9 607.8 506.8 506 517 Ba 33.4 24.7 43 26.8 22.7 Th 3.17 2.26 6.24 2.38 1.64 U 1.06 1.28 3.61 2.39 1.78 Ta 7.41 15.8 25.1 13.7 14.2 Nb 173 200 190.8 115 127 Rb 225.4 211.5 210.1 163 126 注：元素分析由自然资源部西安矿产资源监督检测中心完成；主量元素含量单位为%，微量和稀土元素为10-6 
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表 2 查隆岩体花岗闪长岩(RZ1641-1)和黑云花岗闪长岩(RZ1573-1)LA-ICP-MS锆石U-Th-Pb同位素数据
Table 2. LA-ICP-MS zircon U-Th-Pb data of granodiorite (RZ1641-1) and biotite granodiorite(RZ1573-1)in Chalong area
测点号 同位素比值 年龄/Ma 207Pb/206Pb 1σ 207Pb/235U 1σ 206Pb/238U 1σ 208Pb/232Th 1σ 207Pb/206Pb 1σ 207Pb/235U 1σ 206Pb/238U 1σ 208Pb/232Th 1σ 花岗闪长岩 1 0.0479 0.0034 0.0936 0.0063 0.0142 0.0002 0.0043 0.0001 95 160 91 6 91 2 87 2 2 0.0475 0.0022 0.0921 0.0039 0.0141 0.0002 0.0045 0.0001 73 108 90 4 90 1 91 1 3 0.0477 0.0024 0.093 0.0043 0.0141 0.0002 0.0044 0.0001 83 116 90 4 91 1 89 2 4 0.0473 0.0061 0.0925 0.0116 0.0142 0.0004 0.0047 0.0002 65 283 90 11 91 3 94 4 5 0.0484 0.0026 0.0923 0.0045 0.0138 0.0002 0.0042 0.0001 119 120 90 4 89 1 84 2 6 0.0476 0.0021 0.0931 0.0037 0.0142 0.0002 0.0045 0.0001 76 103 90 3 91 1 91 1 7 0.0473 0.0042 0.0926 0.0079 0.0142 0.0003 0.0045 0.0001 63 199 90 7 91 2 92 3 8 0.0482 0.0071 0.0922 0.0132 0.0139 0.0004 0.0048 0.0002 107 315 90 12 89 3 97 4 9 0.0476 0.0024 0.093 0.0043 0.0142 0.0002 0.0044 0.0001 78 117 90 4 91 1 88 2 10 0.0471 0.0025 0.0927 0.0045 0.0143 0.0002 0.0047 0.0001 55 120 90 4 91 1 94 2 11 0.0481 0.0064 0.0929 0.0121 0.014 0.0004 0.0049 0.0002 106 289 90 11 90 2 98 4 12 0.0478 0.0027 0.0911 0.0047 0.0138 0.0002 0.0047 0.0001 89 128 89 4 89 1 96 2 13 0.047 0.0051 0.0916 0.0097 0.0141 0.0003 0.0048 0.0002 50 242 89 9 91 2 97 4 14 0.0479 0.004 0.0923 0.0073 0.014 0.0003 0.0045 0.0001 95 185 90 7 90 2 90 2 15 0.047 0.0023 0.0917 0.0041 0.0142 0.0002 0.0043 0.0001 49 112 89 4 91 1 86 2 16 0.0469 0.0025 0.0906 0.0045 0.014 0.0002 0.0043 0.0001 45 125 88 4 90 1 87 1 17 0.0483 0.0034 0.0933 0.0063 0.014 0.0002 0.0046 0.0001 112 160 91 6 90 1 92 2 18 0.0481 0.0029 0.0922 0.0051 0.0139 0.0002 0.0046 0.0001 102 134 90 5 89 1 92 2 19 0.0482 0.0026 0.0924 0.0046 0.0139 0.0002 0.0043 0.0001 109 122 90 4 89 1 87 2 20 0.0477 0.0036 0.0909 0.0065 0.0138 0.0002 0.0041 0.0001 85 171 88 6 89 2 83 2 21 0.0481 0.0031 0.0925 0.0056 0.014 0.0002 0.0045 0.0001 103 144 90 5 89 1 90 2 22 0.0482 0.0065 0.0936 0.0123 0.0141 0.0004 0.0046 0.0002 107 292 91 11 90 2 93 4 23 0.048 0.0065 0.0916 0.0122 0.0138 0.0004 0.0048 0.0002 97 295 89 11 89 2 97 4 24 0.0489 0.0039 0.0942 0.0071 0.014 0.0002 0.0043 0.0001 145 176 91 7 89 2 87 2 黑云花岗闪长岩 1 0.0469 0.0065 0.0885 0.0117 0.0137 0.0004 0.004 0.0003 41 301 86 11 88 3 82 6 2 0.0482 0.0052 0.0895 0.0091 0.0135 0.0004 0.0039 0.0002 111 235 87 8 86 2 78 4 3 0.0481 0.0025 0.0904 0.0039 0.0136 0.0002 0.0042 0.0001 104 117 88 4 87 1 85 2 4 0.0478 0.0029 0.0921 0.0049 0.014 0.0002 0.0045 0.0001 86 137 90 5 90 2 90 3 5 0.0477 0.0061 0.0917 0.0112 0.014 0.0004 0.0047 0.0003 82 279 89 10 89 3 95 6 6 0.048 0.0026 0.0848 0.004 0.0128 0.0002 0.0039 0.0001 97 125 83 4 82 1 79 2 7 0.0481 0.0032 0.0904 0.0053 0.0136 0.0002 0.0042 0.0001 105 148 88 5 87 2 85 2 8 0.0473 0.008 0.0853 0.014 0.0131 0.0005 0.0043 0.0004 65 360 83 13 84 3 87 7 9 0.0477 0.004 0.0901 0.0071 0.0137 0.0003 0.0041 0.0002 81 190 88 7 88 2 82 3 10 0.0477 0.0039 0.0862 0.0066 0.0131 0.0003 0.004 0.0002 85 185 84 6 84 2 80 3 11 0.0478 0.0027 0.087 0.0042 0.0132 0.0002 0.0038 0.0001 86 127 85 4 85 1 77 2 12 0.0473 0.0043 0.0863 0.0073 0.0132 0.0003 0.004 0.0002 63 202 84 7 85 2 81 3 13 0.0475 0.0028 0.0908 0.0047 0.0139 0.0002 0.004 0.0001 76 135 88 4 89 1 81 2 14 0.0478 0.004 0.0885 0.007 0.0134 0.0003 0.0041 0.0002 86 190 86 7 86 2 82 3 15 0.049 0.0166 0.0913 0.0303 0.0135 0.0009 0.0043 0.0004 146 646 89 28 87 6 86 8 16 0.0479 0.0036 0.0922 0.0064 0.014 0.0003 0.0043 0.0001 93 171 90 6 89 2 88 3 17 0.0477 0.0038 0.0924 0.0069 0.014 0.0003 0.0044 0.0002 84 181 90 6 90 2 88 3 18 0.0477 0.0028 0.0892 0.0047 0.0136 0.0002 0.0042 0.0001 81 136 87 4 87 1 84 2 19 0.0477 0.003 0.0877 0.0049 0.0133 0.0002 0.004 0.0001 85 142 85 5 85 2 81 2 20 0.0485 0.0031 0.0912 0.0053 0.0137 0.0002 0.0041 0.0001 121 146 89 5 87 2 83 2 21 0.0477 0.0028 0.0869 0.0044 0.0132 0.0002 0.0042 0.0001 81 133 85 4 85 1 85 3 22 0.0483 0.0028 0.0904 0.0045 0.0136 0.0002 0.0041 0.0001 115 129 88 4 87 1 82 3 23 0.0477 0.0032 0.0933 0.0057 0.0142 0.0003 0.0042 0.0001 85 155 91 5 91 2 85 3 24 0.0479 0.0028 0.0933 0.0047 0.0141 0.0002 0.0045 0.0001 91 132 91 4 91 2 90 2 25 0.0473 0.0029 0.0855 0.0047 0.0131 0.0002 0.004 0.0001 62 142 83 4 84 1 81 2 26 0.0482 0.0086 0.0846 0.0146 0.0127 0.0005 0.0042 0.0003 109 372 83 14 82 3 84 7 27 0.0468 0.0027 0.0877 0.0043 0.0136 0.0002 0.0041 0.0001 41 130 85 4 87 1 82 2 28 0.0482 0.0031 0.0921 0.0053 0.0139 0.0003 0.0042 0.0001 109 144 89 5 89 2 85 3 29 0.0473 0.0053 0.0865 0.0092 0.0133 0.0004 0.0043 0.0002 63 247 84 9 85 2 86 4 30 0.0478 0.0032 0.0889 0.0053 0.0135 0.0003 0.004 0.0001 89 151 87 5 86 2 81 2
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