Geochemical Characteristics of Calcite and Bastnäsite U–Th–Pb Age of the Huangshui’an Carbonatite–hosted Mo–REE Deposit, Eastern Qinling
-
摘要:
黄水庵矿床位于华北克拉通南缘熊耳山矿集区，是东秦岭钼矿带典型的碳酸岩型Mo–REE矿床之一。黄水庵矿床的Mo–REE矿体主要产于碳酸岩中，碳酸岩呈脉状和隐爆角砾岩体侵入太华群。笔者通过碳酸岩方解石微量元素、C–O同位素以及氟碳铈矿U–Th–Pb年龄的研究，探讨了碳酸岩岩浆的来源、成岩成矿年龄和构造地质背景，对东秦岭地区的构造演化和成矿作用提供约束。方解石的微量元素具有富集大离子亲石元素、亏损高场强元素的特征，稀土配分模式为轻稀土元素富集的右倾型（LREE/HREE=3.08～10.33）。方解石δ13 CV-PDB值为−4.11‰～−5.62‰、δ18OV-SMOW值为6.40‰～7.62‰，指示初始火成碳酸岩特征。氟碳铈矿U–Th–Pb定年的加权平均年龄为（213.5±2.9）Ma，代表了黄水庵REE矿化的时限。综合已有成岩成矿年龄和同位素研究结果，认为黄水庵矿床的成矿时代为晚三叠世，形成于秦岭造山带碰撞后的伸展背景。富Mo下地壳与富集地幔的部分熔融形成碳酸岩岩浆，其中地壳物质的再循环是形成碳酸岩型Mo–REE矿化的关键因素之一。
-
关键词:
- 碳酸岩 /
- 方解石微量元素 /
- 碳氧同位素 /
- 氟碳铈矿U–Th–Pb定年 /
- 黄水庵矿床
Abstract:The Huangshui’an deposit, located in Xiong’ershan ore concentration area in the southern margin of the North China Craton, is one of the typical carbonatite–hosted Mo–REE deposit in the East Qinling Mo metallogenic belts. The Mo–REE ore bodies of the Huangshui’an deposit mainly are hosted in carbonatite which occur as veins and cryptoexplosive breccia intrusions in the Taihua Group. Based on the study of trace elements and C–O isotopic compostion of calcite, and bastnäsite U–Th–Pb dating, we discuss the origin of carbonatite, metallogenic age and tectonic setting, which provide constraints for tectonic evolution and mineralization in the East Qinling belt. The trace elements of calcite are characterized by enrichment of large ion lithophile elements and depletion of high field strength elements, and are enriched in LREE (LREE/HREE=3.08～10.33). The δ13 CV-PDB values of calcite ranging from −4.11‰ to −5.62‰ and δ18 OV-SMOW values ranging from 6.40‰ to 7.62‰ indicate the characteristics of primary mantle–derived carbonatite. The weighted average age of U–Th–Pb dating of bastnäsite is 213.5±2.9 Ma, representing the age of REE mineralization in the Huangshui'an deposit. Based on diagenetic and metallogenic age and available isotopic ages, we propose that the metallogenic age of the Huangshui’an deposit is Late Triassic. The Huangshui’an carbonatite–hosted deposit was formed in the post–collisional setting of the Qinling orogenic belt. The partial melting of Mo–fertile lower crust and enriched mantle formed the carbonatite magma, and the recycling of crustal material is one of the key factors for the formation of carbonatite–hosted Mo–REE mineralization.
-
-
图 1 秦岭造山带构造构架图（A）与熊耳山矿集区地质简图（B）（修改自Tang et al.，2021）
Figure 1.
图 5 黄水庵碳酸岩中方解石C–O同位素图解（底图据Keller et al.，1995）
Figure 5.
表 1 黄水庵Mo–REE矿床方解石微量元素及稀土元素组成（10−6）
Table 1. Trace element and REE content (10−6) from the Huangshui’an Mo–REE deposit
样品号 HAS-9 HAS-10 HAS-11 HAS-12 HAS-13 HAS-14 18HAS-20 19HAS-13 Li 0.150 0.210 0.238 0.130 0.097 0.103 0.009 0.039 Be 0.648 0.646 0.021 1.490 0.155 0.274 0.100 0.124 Sc 3.230 3.340 0.315 3.050 0.970 2.030 1.310 2.710 V 1.390 1.060 0.369 1.250 0.307 0.376 0.576 0.350 Cr 1.65 1.47 1.32 1.63 1.38 1.70 1.28 1.58 Co 1.13 1.05 1.12 1.14 1.02 1.10 1.12 1.15 Ni 22.5 20.1 21.7 18.3 21.6 19.8 21.4 23.7 Cu 0.977 0.696 0.318 0.322 0.331 0.190 0.373 0.114 Zn 19.20 4.30 1.84 3.48 2.26 2.65 3.08 2.55 Ga 2.04 2.01 3.25 2.25 1.58 1.63 2.77 1.13 Rb 0.319 0.201 0.062 0.189 0.053 0.035 0.035 0.028 Sr 5997 5960 7546 5913 6040 5787 7890 5297 Y 193 193 167 193 137 169 171 148 Mo 14.3 18.90 22.00 1.89 0.64 1.36 0.17 0.09 Cd 0.643 0.488 0.303 0.533 0.366 0.259 0.660 0.421 Sb 0.067 0.024 0.066 0.036 0.023 0.016 0.014 0.111 Cs 0.031 0.014 0.022 0.023 0.027 0.022 0.021 0.016 Ba 923 772 236 806 789 788 1587 691 La 91.3 87.6 253 108 84.8 82.4 183 43.6 Ce 218 206 484 246 184 185 375 99.9 Pr 31.1 29.0 53.5 35.2 25.0 23.8 47.5 14.1 Nd 126 119 200 145 96.3 99.5 177 60.8 Sm 25.9 24.7 28.6 28.6 18.4 19.1 29.5 14.1 Eu 7.61 7.49 7.78 8.05 5.88 5.88 7.88 4.71 Gd 23.3 22.1 28.1 25.1 17.4 17.8 26.7 12.5 Tb 4.08 4.1 4.04 4.40 2.99 3.35 4.23 2.55 Dy 24.3 22.5 22.2 25.1 17.4 19.6 21.6 16.5 Ho 5.94 5.51 5.02 5.95 4.11 5.05 4.95 4.28 Er 19.5 19.3 17.0 20.9 14.7 17.2 17.3 15.6 Tm 3.69 3.49 2.84 3.81 2.61 3.26 2.97 2.88 Yb 25.6 25.0 18.1 24.6 16.8 21.4 19.4 20.0 Lu 3.51 3.46 2.12 3.49 2.45 2.95 2.59 2.66 W 4.770 0.836 0.514 0.590 0.426 0.346 0.548 0.247 Pb 86.0 85.7 43.0 45.5 46.0 41.8 53.0 43.1 Bi 0.164 0.203 0.029 0.038 0.012 0.011 0.033 0.016 Th 0.381 0.367 0.057 0.475 0.156 0.096 0.739 0.071 U 1.340 2.340 0.137 1.320 0.883 0.222 0.449 0.822 Nb 3.690 5.80 0.049 2.840 0.758 0.042 0.094 0.478 Ta 0.055 0.056 0.053 0.050 0.035 0.053 0.046 0.040 Zr 0.339 0.097 0.123 0.076 0.037 0.085 0.033 0.065 Hf 0.222 0.245 0.239 0.247 0.161 0.180 0.213 0.168 
下载: 导出CSV
表 2 黄水庵Mo–REE矿床的方解石C–O同位素组成
Table 2. C–O isotope contents of calcite from the Huangshui’an Mo–REE deposit
样号 δ13 CV-PDB(‰) δ18 OV-PDB(‰) δ18 OV-SMOW(‰) HSA02 −5.18 −22.49 7.72 HSA03 −5.62 −23.00 7.19 HSA04 −4.11 −23.76 6.40 HSA14 −5.31 −23.07 7.12 19HSA-13 −5.14 −22.58 7.62 19HSA-14 −5.39 −22.62 7.58
下载: 导出CSV
表 3 东秦岭黄水庵Mo–REE矿床氟碳铈矿U–Th–Pb分析结果表
Table 3. Bastnäsite U–Th–Pb isotopic data from the Huangshui’an Mo–REE deposit, East Qinling
分析点 Th U Th/U 同位素比值 表面年龄(Ma) 207Pb/206Pb ±1σ 207Pb/235U ±1σ 206Pb/238U ±1σ 208Pb/232Th ±1σ 19HSA-16-01 12 908 82.9 155.7 0.630 7 0.016 5 11.640 7 0.391 6 0.134 2 0.0032 217 2.5 19HSA-16-02 9 144 61.3 149.3 0.563 5 0.016 5 9.655 7 0.640 6 0.114 5 0.0056 225 2.6 19HSA-16-03 9 136 68.4 133.6 0.075 2 0.004 8 0.436 4 0.025 5 0.044 7 0.0010 216 2.5 19HSA-16-04 14 191 92.2 154.0 0.215 2 0.010 9 1.503 7 0.091 7 0.046 7 0.0010 218 2.4 19HSA-16-05 7 391 47.3 156.4 0.154 2 0.009 8 0.994 8 0.0783 0.045 0 0.0012 218 2.8 19HSA-16-06 8 723 55.1 158.3 0.251 7 0.019 4 2.133 1 0.201 2 0.054 0 0.0021 211 2.4 19HSA-16-07 7 222 53.8 134.2 0.210 6 0.013 3 1.994 9 0.178 2 0.058 8 0.0021 219 2.5 19HSA-16-08 11 312 53.2 212.5 0.259 2 0.018 6 3.398 8 0.479 4 0.071 3 0.0069 206 2.7 19HSA-16-09 7 420 50.6 146.5 0.372 4 0.011 6 3.505 8 0.128 3 0.069 0 0.0014 217 2.2 19HSA-16-10 6 284 105 59.7 0.263 0 0.012 3 2.359 5 0.217 4 0.053 4 0.0022 206 2.6 19HSA-16-11 5 586 55.1 101.4 0.138 4 0.013 4 1.132 4 0.174 7 0.046 5 0.0019 207 2.4 19HSA-16-12 17 925 85.4 209.9 0.149 4 0.010 9 1.416 4 0.138 2 0.054 9 0.0016 213 2.3 19HSA-16-13 3 139 64.2 48.9 0.248 0 0.012 5 1.594 1 0.092 2 0.046 0 0.0011 205 2.3 19HSA-16-14 19 660 109 179.6 0.076 5 0.004 5 0.437 7 0.026 3 0.042 4 0.0008 213 2.2 19HSA-16-15 12 267 97.5 125.8 0.129 1 0.005 8 0.749 4 0.037 0 0.041 7 0.0009 201 2.3
下载: 导出CSV
表 4 秦岭造山带碳酸岩型矿床的成矿时代
Table 4. Geochronological data for the carbonatite deposits in the Qinling orogenic belt
矿床 矿床类型 测试方法 年龄(Ma) 资料来源 黄水庵 碳酸岩型Mo–REE矿床 辉钼矿Re–Os 209.5±4.2 黄典豪等，2009 辉钼矿Re–Os 208.4±3.6 曹晶等，2014 氟碳铈矿U–Th–Pb 206.5±3.8 Zhang et al.，2019 氟碳铈矿U–Th–Pb 211.7±3.1 Feng et al.，2022 209.6±2.1 氟碳铈矿U–Th–Pb 213.5±2.9 本文 黄龙铺 碳酸岩型Mo–REE矿床 辉钼矿Re–Os 221.5±0.3 Stein，1997 辉钼矿Re–Os 222.0±7.0 Huang et al.，1995 辉钼矿Re–Os 225.0 ± 7.6 Song et al.，2015 独居石U–Th–Pb 208.9±4.6
213.6± 4.0Song et al.，2016 华阳川 碳酸岩型U–Nb–Pb–REE矿床 独居石U–Th–Pb 222.5±6.7 王佳营等，2020 晶质铀矿U–Th–Pb 221.9±5.1
137.1±2.0黄卉等，2020 榍石U–Pb 208.5±3.2 Zheng et al.，2020 辉钼矿Re–Os 196.8±2.4 Zheng et al.，2020 庙垭 碳酸岩型Nb-REE矿床 独居石U–Th–Pb 233.6±1.7 Xu et al.，2014 氟碳铈矿U–Th–Pb 205.8±3.6 Zhang et al.，2019 独居石U–Pb 231.0±2.3 Zhang et al.，2019 锆石U–Th–Pb 426.5±8.0 Ying et al.，2017 独居石U–Th–Pb 238.3±4.1 Ying et al.，2017 铌铁矿U–Pb 232.8±3.7 Ying et al.，2017
下载: 导出CSV
-
曹华文, 李光明, 张林奎, 等. 西藏山南列麦始新世花岗岩独居石U-Th-Pb年龄及地质意义[J]. 沉积与特提斯地质, 2020, 40(2): 31-42.
CAO Huawen, LI Guangming, ZHANG Lingkui, et al. Monazite U-Th-Pb age of Liemai Eocene granites in the southern Tibet and its geological implications[J]. Sedimentary Geology and Tethyan Geology, 2020, 40(2), 31-42.
曹晶. 东秦岭黄水庵碳酸岩型钼矿床成矿作用研究[D]. 北京: 中国地质大学(北京), 2018
CAO Jing. Mineralization of the Huangshui’an carbonatite Mo deposit in East Qinling[D]. Beijing: China University of Geosciences (Beijing), 2018.
曹晶, 叶会寿, 李正远, 等. 东秦岭磨沟碱性岩体年代学、地球化学及岩石成因[J]. 岩石矿物学杂志, 2015, 34(05): 665-684 doi: 10.3969/j.issn.1000-6524.2015.05.006
CAO Jing, YE Huishou, LI Zhengyuan, et al. Geochronology, geochemistry and petrogenesis of the Mogou alkalic pluton in the East Qinling orogenic belt [J]. Acta Petrologica et Mineralogica, 2015, 34(05): 665-684. doi: 10.3969/j.issn.1000-6524.2015.05.006
曹晶, 叶会寿, 李洪英, 等. 河南嵩县黄水庵碳酸岩脉型钼(铅)矿床地质特征及辉钼矿Re-Os同位素年龄[J]. 矿床地质, 2014, 33(1): 53-69 doi: 10.3969/j.issn.0258-7106.2014.01.004
CAO Jing, YE Huishou, LI Hongying, et al. Geological characteristics and molybdenite Re-Os isotopic dating of Huangshuian carbonatite vein-type Mo(Pb) deposit in Songxian County, Henan Province[J]. Mineral Deposits, 2014, 33(1): 53-69. doi: 10.3969/j.issn.0258-7106.2014.01.004
曹晶, 叶会寿, 陈小丹, 等. 豫西雷门沟钼矿区花岗斑岩年代学、地球化学和Sr-Nd-Hf同位素研究[J]. 矿床地质, 2016, 35(4): 677-695 doi: 10.16111/j.0258-7106.2016.04.004
CAO Jing, YE Huishou, CHEN Xiaodan, et al. Geochronology, geochemistry and Sr-Nd-Hf isotopic compositions of granite porphyry in Leimengou Mo deposit, western Henan Province[J]. Mineral Deposits, 2016, 35(4): 677-695. doi: 10.16111/j.0258-7106.2016.04.004
付鑫宁, 唐利, 姚梅青, 等. 东秦岭黄水庵钼矿床的碳酸岩成因与地质意义: 来自痕量元素和Sr-Nd-Pb同位素的约束[J]. 成都理工大学学报(自然科学版), 2021, 48(5): 525-538
FU Xinning, TANG Li, YAO Meiqing, et al. Genesis and geological significance of the carbonatite in the Huangshui'an Mo deposit in Eastern Qinling area of China: Constraints from trace elements and Sr-Nd-Pb isotopes[J]. Journal of Chengdu University of Technology (Science & Technology Edition), 2021, 48(5): 525-538.
黄典豪, 侯增谦, 杨志明, 等. 东秦岭钼矿带内碳酸岩脉型钼(铅)矿床地质-地球化学特征、成矿机制及成矿构造背景[J]. 地质学报, 2009, 83(12): 1968-1984 doi: 10.3321/j.issn:0001-5717.2009.12.012
HUANG Dianhao, HOU Zengqian, YANG Zhiming, et al. Geological and Geochemical Characteristics, Metallogenetic Mechanism and Tectonic Setting of Carbonatite Vein-Type Mo(Pb)Deposits in the East Qinling Molybdenum Ore Belt[J]. Acta Geologica Sinica, 2009, 83(12): 1968-1984. doi: 10.3321/j.issn:0001-5717.2009.12.012
黄卉, 潘家永, 洪斌跃, 等. 陕西华阳川铀-多金属矿床晶质铀矿电子探针U-Th-Pb化学定年及其地质意义[J]. 矿床地质, 2020, 39(2): 351-368 doi: 10.16111/j.0258-7106.2020.02.009
HUANG Hui, PAN Jiayong, HONG Binyue, et al. EPMA chemical U-Th-Pb dating of uraninite in Huayangchuan U-polymetallic deposit of Shaanxi Province and its geological significance[J]. Mineral Deposits, 2020, 39(2): 351-368. doi: 10.16111/j.0258-7106.2020.02.009
胡乐, 李以科, 孙盛, 等. 内蒙古白云鄂博地区识别出新火成碳酸岩[J/OL]. 中国地质, 2021: 1-23.
HU Le, LI Yike, SUN Sheng, et al. Identification of new igneous carbonatites in the Bayan Obo area, Inner Mongolia[J/OL], Geology in China, 2021: 1-23.
李诺, 陈衍景, 张辉, 等. 东秦岭斑岩钼矿带的地质特征和成矿构造背景[J]. 地学前缘, 2007, 5: 186-198.
LI Nuo, CHEN Yanjing, ZHANG Hui, et al. Molybdenum deposits in East Qinling[J]. Earth Science Frontiers, 2007, 5: 186-198.
李永峰. 豫西熊耳山地区中生代花岗岩类时空演化与钼(金)成矿作用[D]. 北京: 中国地质大学(北京), 2005
LI Yongfeng. The Temporal-spatial Evolution of Mesozoic Granitoids in Xiong' ershan Area and Their Relationship to Molybdenum-gold Mineralization[D]. Beijing: China University of Geosciences (Beijing), 2005.
梁涛, 白凤军, 罗照华, 等. 豫西熊耳山斑竹寺花岗斑岩岩体锆石U-Pb定年及地质意义[J]. 西北地质, 2014, 47(2): 41-50 doi: 10.3969/j.issn.1009-6248.2014.02.006
LIANG Tao, BAI Fengjun, LUO Zhaohua, et al. LA-ICP-MS Zircon U-Pb Dating and Its Geological Implications of Banzhusi Granitic Porphyry in Xiongershan of Western Henan Province[J]. Northwestern Geology, 2014, 47(2): 41-50. doi: 10.3969/j.issn.1009-6248.2014.02.006
卢欣祥, 罗照华, 黄凡, 等. 秦岭-大别山地区钼矿类型与矿化组合特征[J]. 中国地质, 2011, 38(6): 1518-1535 doi: 10.3969/j.issn.1000-3657.2011.06.012
LU Xinxiang, LUO Zhaofan, HUANG Fan, et al. Mo deposit types and mineralization assemblage characteristics in QinlingDabie Mountain area[J]. Geology in China, 2011, 38(6): 1518-1535. doi: 10.3969/j.issn.1000-3657.2011.06.012
卢欣祥, 尉向东, 肖庆辉, 等. 秦岭环斑花岗岩的年代学研究及其意义[J]. 高校地质学报, 1999, 5(4): 372 – 377
LU Xinxiang, WEI Xiangdong, XIAO Qinghui, et al. Geochronological studies of rapakivi granites in Qingling and its geological implication[J]. Geological Journal of China Universities, 1999, 5(4): 372-377.
罗涛, 赵赫, 张文, 等. 激光剥蚀电感耦合等离子体质谱非基体匹配氟碳铈矿U-Th-Pb定年[J]. 中国科学: 地球科学, 2021, 51(06): 874-883 doi: 10.1360/N072020-0267
LUO Tao, ZHAO He, ZHANG Wen, et al. Non-matrix-matched analysis of U-Th-Pb geochronology of bastnasite by laser ablation inductively coupled plasma mass spectrometry[J]. Scientia Sinica (Terrae), 2021, 51(06): 874-883. doi: 10.1360/N072020-0267
罗铮娴, 黄小龙, 王雪, 等. 华北克拉通崤山太华群TTG质片麻岩年代学与地球化学特征: 岩石成因机制探讨[J]. 大地构造与成矿学, 2018, 42(2): 332-347
LUO Zhengxian, HUANG Xiaolong, WANG Xue, et al. Geochronology and Geochemistry of the TTG Gneisses from the Taihua Group in the Xiaoshan Area, North China Craton: Constraints on Petrogenesis[J]. Geotectonica et Metallogenia, 2018, 42(2): 332-347.
毛景文, 谢桂青, 张作衡, 等. 中国北方中生代大规模成矿作用的期次及其地球动力学背景[J]. 岩石学报, 2005, 21(1): 169-188
MAO Jingwen, XIE Guiqing, ZHANG Zuoheng, et al. Mesozoic large-scale metallogenic pulses in North China and corresponding geodynamic settings[J]. Acta Petrologica Sinica, 2005, 21(1): 169-188.
毛帆, 裴先治, 李瑞保, 等. 扬子板块西北缘碧口微地块南华系碎屑锆石U-Pb年龄及其物源示踪[J]. 沉积与特提斯地质, 2021, 41(1): 41-57 doi: 10.19826/j.cnki.1009-3850.2020.10009
MAO Fang, PEI Xianzhi, LI Ruibao, et al. The LA-ICP-MS U-Pb dating of detrital zircons from the Nanhua System in Bikou Terrane, northwestern margin of Yangtze Block[J]. Sedimentary Geology and Tethyan Geology, 2021, 41(1): 41-57. doi: 10.19826/j.cnki.1009-3850.2020.10009
齐进英. 东秦岭太华群变质岩系及其形成条件[J]. 地质科学, 1992, 112: 94-107
QI Jinying. Metamorphic rock series of Taihua Group and conditions for its formation in Eastern Qinling[J]. Chines Journal of Geology, 1992, 112: 94-107
秦江锋. 秦岭造山带晚三叠世花岗岩类成因机制及深部动力学背景[D]. 西安: 西北大学, 2010
QING Jiangfeng. Petrogenesis and Geodynamic Implications of the Late-Triassic Granitoids from the Qinling Orogenic Belt[D]. Xi’an: Northwest University, 2010.
邱啸飞, 蔡应雄, 江拓, 等. 庙垭铌-稀土矿床的热液蚀变作用: 来自碳酸岩碳-氧同位素的制约[J]. 华南地质与矿产, 2017, 33(03): 275-281 doi: 10.3969/j.issn.1007-3701.2017.03.008
QIU Xiaofei, CAI Yingxiong, JIANG Tuo, et al. Hydrothermal alteration for the Miaoya Nb-REE deposit: constraints from C-O isotope composition of the carbonatite[J]. Geology and Mineral Resources of South China, 2017, 33(03): 275-281. doi: 10.3969/j.issn.1007-3701.2017.03.008
宋文磊, 许成, 刘琼, 等. 火成碳酸岩的实验岩石学研究及对地球深部碳循环的意义[J]. 地质论评, 2012, 4: 726-744 doi: 10.3969/j.issn.0371-5736.2012.04.014
SONG Wenlei, XU Chen, LIU Qiong, et al. Experimental Petrological Study of Carbonatite and Its Significances on the Earth Deep Carbon Cycle[J]. Geological Review, 2012, 4: 726-744. doi: 10.3969/j.issn.0371-5736.2012.04.014
王佳营, 李志丹, 张祺, 等. 东秦岭地区碳酸岩型钼-铀多金属矿床成矿时代: 来自LA-ICP-MS独居石U-Pb和辉钼矿Re-Os年龄的证据[J]. 地质学报, 2020, 94(10): 2946-2964 doi: 10.3969/j.issn.0001-5717.2020.10.011
WANG JiaYing, LI Zhidan, ZHANG Qi, et al. Metallogenic epoch of the carbonatite-type Mo-U polymetallic deposit in east Qinling: evidence from the monazite LA-ICP-MS U-Pb and molybdenite Re-Os isotopic dating[J]. Acta Geologica Sinica, 2020, 94(10): 2946-2964. doi: 10.3969/j.issn.0001-5717.2020.10.011
姚书振, 周宗桂, 吕新彪, 等. 秦岭成矿带成矿特征和找矿方向[J]. 西北地质, 2006, 39(2): 156-178 doi: 10.3969/j.issn.1009-6248.2006.02.010
YAO Shunzhen, ZHOU Zonggui, LV Xinbiao, et al. Mineralization Characteristics and Prospecting Potential in the Qinling Metallogenic Belt[J]. Northwestern Geology, 2006, 39(2): 156-178. doi: 10.3969/j.issn.1009-6248.2006.02.010
张成立, 王涛, 王晓霞. 秦岭造山带早中生代花岗岩成因及其构造环境[J]. 高校地质学报, 2008, 3: 304-316 doi: 10.3969/j.issn.1006-7493.2008.03.003
ZHANG Chengli, WANG Tao, WANG Xiaoxia. Origin and Tectonic Setting of the Early Mesozoic Granitoids in Qinling Orogenic Belt[J]. Geological Journal of China Universities, 2008, 3: 304-316. doi: 10.3969/j.issn.1006-7493.2008.03.003
张传昱, 李文昌, 余海军, 等. 云南水头山铅锌矿床闪锌矿Rb-Sr定年及其地质意义[J]. 沉积与特提斯地质, 2022, 42(1): 122-132 doi: 10.19826/j.cnki.1009-3850.2022.01006
ZHANG Chuanyu, LI Wenchang, YU Haijun, et al. Sphalerites Rb-Sr dating and geological significance of the Shuitoushan Pb-Zn deposit in Yunnan Province, SW China [J]. Sedimentary Geology and Tethyan Geology, 2022, 42(1): 122-132. doi: 10.19826/j.cnki.1009-3850.2022.01006
张国伟, 郭安林, 董云鹏, 等. 关于秦岭造山带[J]. 地质力学学报, 2019, 25(5): 746-768 doi: 10.12090/j.issn.1006-6616.2019.25.05.064
ZHANG Guowei, GUO Anlin, DONG Yunpeng, et al. Rethinking of the Qinling Orogen[J]. Journal of Geomechanics, 2019, 25(5): 746-768. doi: 10.12090/j.issn.1006-6616.2019.25.05.064
张健, 李怀坤, 田辉. 华北克拉通南缘官道口群龙家园组凝灰岩SHRIMP锆石U-Pb年代学研究[J]. 华北地质, 2021, 44(04): 1-4
ZHANG Jian, LI Huaikun, TIAN Hui. SHRIMP Zircon U-Pb dating of tuff from the Longjiayuan Formation of the Guandaokou Group, southern margin of North China Craton [J]. North China Geology, 2021, 44(04): 1-4.
张元厚, 张世红, 韩以贵, 等. 华熊地块马超营断裂走滑特征及演化[J]. 吉林大学学报(地球科学版), 2006, 36(2): 169-176, 193.
ZHANG Yuanhong, ZHANG Shihong, HAN Yigui, et al. Strik-Slip Features of the Machaoying Fault Zone and Its Evolution in the Huaxiong Terrane, Southern North China Craton[J]. Journal of Jilin Unviersity: Earth Science Edition, 2006, 36(2): 169-176+193.
赵太平, 徐勇航, 翟明国. 华北陆块南部元古宙熊耳群火山岩的成因与构造环境: 事实与争议[J]. 高校地质学报, 2007, 2: 191-206 doi: 10.3969/j.issn.1006-7493.2007.02.005
ZHAO Taiping, XU Yonghang, ZHAI Mingguo. Petrogenesis and Tectonic Setting of the Paleoproterozoic Xiong’er Group in the Southern Part of the North China Craton: a Review[J]. Geological Journal of China Universities, 2007, 2: 191-206. doi: 10.3969/j.issn.1006-7493.2007.02.005
Ames L, Tilton G R, Zhou G. Timing of collision of the Sino-Korean and Yangtse cratons: uranium-lead zircon dating of coesite-bearing eclogites. [J]. Geology, 1993, 21(4): 339-342. doi: 10.1130/0091-7613(1993)021<0339:TOCOTS>2.3.CO;2
Brooker R A, Kjarsgaard B A. Silicate–Carbonate Liquid Immiscibility and Phase Relations in the System SiO2–Na2O–Al2O3–CaO–CO2 at 0·1–2·5 GPa with Applications to Carbonatite Genesis [J]. Journal of Petrology, 2011, 52(7/8): 1281-1305.
Chaussidon M and Lorand J P. Sulphur isotope composition of orogenic spinel lherzolite massifs from Ariege (North-Eastern Pyrenees, France): an ion microprobe study[J]. Geochimica et Cosmochimica Acta, 1990, 54(10): 2835-2846. doi: 10.1016/0016-7037(90)90018-G
Chavagnac V, Jahn B M. Coesite-bearing eclogites from the Bixiling Complex, Dabie Mountains, China: Sm-Nd ages, geochemical characteristics and tectonic implications[J]. Chemical Geology, 1996, 133(1): 29-51.
Chen Y J, Santosh M. Triassic tectonics and mineral systems in the Qinling Orogen, central China[J]. Geological Journal, 2014, 49: 338-358.
Dong Y P, Yang Z, Liu X M, et al. Mesozoic intracontinental orogeny in the Qinling Mountains, central China[J]. Gondwana Research, 2016, 30: 144-158.
Feng Jiaying, Tang Li, Yang Bochang, et al. Bastnäsite U-Th-Pb age, sulfur isotope and trace elements of the Huangshui’an deposit: Implications for carbonatite-hosted Mo-Pb-REE mineralization in the Qinling Orogenic Belt, China[J]. Ore Geology Reviews, 2022, 143: 104790. doi: 10.1016/j.oregeorev.2022.104790
Gao Shan, Luo Tingchuan, Zhang Benren, et al. Chemical composition of the continental crust as revealed by studies in East China[J]. Geochimica et Cosmochimica Acta, 1998, 62(11): 1959–1975. doi: 10.1016/S0016-7037(98)00121-5
Gittins J, Jago B C. Differentiation of natrocarbonatite magma at Oldoinyo Lengai volcano, Tanzania[J]. Mineralogical Magazine, 1998, 62(6): 759-768. doi: 10.1180/002646198548142
Hacker B R, Ratschbacher L, Webb L, et al. U/Pb zircon ages constrain the architecture of the ultrahigh-pressure Qinling-Dabie Orogen, China[J]. Earth and Planetary Science Letters, 1998, 161(1): 215-230.
Harlov D E, Wirth R, Hetherington C J. Fluid-mediated partial alteration in monazite: the role of coupled dissolution–reprecipitation in element redistribution and mass transfer[J]. Contributions to Mineralogy and Petrology, 2011, 162(2): 329-348. doi: 10.1007/s00410-010-0599-7
Hou Zengqian, Liu Yan, Tian Shihong, et al. Formation of carbonatite-related giant rare-earth-element deposits by the recycling of marine sediments[J]. Scientific reports, 2015, 5: 2045-2322.
Hou Zengqian, Tian Shihong, Yuan Zhongxin, et al. The Himalayan collision zone carbonatites in western Sichuan, SW China: Petrogenesis, mantle source and tectonic implication[J]. Earth and Planetary Science Letters, 2006, 244(1-2): 234-250. doi: 10.1016/j.jpgl.2006.01.052
Huang Dianhao, Wu Chengyu, Du Andao, et al. Re-Os Isotope Ages of Molybdenum Deposits in East Qinling and Their Significance[J]. Chinese Journal of Geochemistry, 1995, 4: 313-322.
Kathryn M. Goodenough, Eimear A. Deady, Charles D. Beard, et al. Carbonatites and Alkaline Igneous Rocks in Post-Collisional Settings: Storehouses of Rare Earth Elements[J]. Journal of Earth Science, 2021, 32(6): 1332-1358. doi: 10.1007/s12583-021-1500-5
Keller J, Hoefs J. Stable isotope characteristics of recent natrocarbonatites from Oldoinyo Lengai [J]. Carbonatites Volcanism, 1995, 4: 113—123.
Kynicky J, Smith M P, Xu Cheng. Diversity of Rare Earth Deposits: The Key Example of China[J]. Elements, 2012, 8(5): 361-367. doi: 10.2113/gselements.8.5.361
Le Maitre R W. Igneous rocks: a classification and glossary of terms[M]. Cambridge: Cambridge University Press, 2002.
Ling X X, Li Q L, Liu Y, et al. In situ SIMS Th-Pb dating of bastnaesite: constraint on the mineralization time of the Himalayan Mianning-Dechang rare earth element deposits[J]. Journal of Analytical Atomic Spectrometry, 2016, 31(8): 1680-1687. doi: 10.1039/C6JA00093B
Mao Jingwen, Zhang Zhaochong, Zhang Zuoheng, et al. Re-Os isotopic dating of molybdenites in the Xiaoliugou W (Mo) deposit in the northern Qilian mountains and its geological significance[J]. Geochimica et Cosmochimica Acta: Journal of the Geochemical Society and the Meteoritical Society, 1999, 63(11/12): 1815-1818.
Poitrasson F, Shepherd TJ, Chenery S. Electron microprobe and LA-ICP-MS study of monazite hydrothermal alteration: Implications for U-Th-Pb geochronology and nuclear ceramics [Review][J]. Geochimica et Cosmochimica Acta: Journal of the Geochemical Society and the Meteoritical Society, 2000, 64(19): 3283-3297. doi: 10.1016/S0016-7037(00)00433-6
Rasmussen B, Muhling J R. Monazite begets monazite: evidence for dissolution of detrital monazite and reprecipitation of syntectonic monazite during low-grade regional metamorphism[J]. Contributions to Mineralogy and Petrology, 2007, 154(6): 675-689. doi: 10.1007/s00410-007-0216-6
Sal’nikova E B, Yakovleva S Z, Nikiforov A V, et al. Bastnaesite: A Promising U-Pb Geochronological Tool[J]. Doklady earth sciences, 2010, 430(1): 134-136. doi: 10.1134/S1028334X10010290
Song Wenlei, Xu Cheng, Smith M P, et al. Origin of unusual HREE-Mo-rich carbonatites in the Qinling orogen, China[J]. Scientific reports, 2016, 6(1): 37377. doi: 10.1038/srep37377
Song Wenlei, Xu Cheng, Qi Liang, et al. Genesis of Si-rich carbonatites in Huanglongpu Mo deposit, Lesser Qinling orogen, China and significance for Mo mineralization[J]. Ore Geology Reviews, 2015, 64: 756-765. doi: 10.1016/j.oregeorev.2014.04.003
Stein H J, Markey R J, Morgan J W, et al. Highly precise and accurate Re-Os ages for molybdenite from the East Qinling molybdenum belt, Shaanxi Province, China[J]. Economic Geology, 1997, 92(7-8): 827-835. doi: 10.2113/gsecongeo.92.7-8.827
Tang Li, Wagner T, Fusswinke T, et al. Magmatic-hydrothermal evolution of an unusual Mo-rich carbonatite: a case study using LA-ICP-MS fluid inclusion microanalysis and He–Ar isotopes from the Huangshui’an deposit, Qinling, China[J]. Mineralium Deposita, 2021, 56(6) : 1-18.
Tang Li, Zhang Shouting, Yang Fan, et al. Triassic alkaline magmatism and mineralization in the Xiong'ershan area, East Qinling, China[J]. Geological Journal, 2019, 54(1): 143-156. doi: 10.1002/gj.3166
Taylor H P, Frechen J, Degens, E T. Oxygen and carbon isotope studies of carbonatites from the Laacher See District, West Germany and the Alnö District, Sweden[J]. Geochimica et Cosmochimica Acta, 1967, 31(3): 407-430. doi: 10.1016/0016-7037(67)90051-8
Wallace M E, Green D H. An experimental determination of primary carbonatite magma composition[J]. Nature, 1988, 335: 343. doi: 10.1038/335343a0
Wang, Zaicong, Becker H. Molybdenum partitioning behavior and content in the depleted mantle: Insights from Balmuccia and Baldissero mantle tectonites (Ivrea Zone, Italian Alps) [J]. Chemical Geology, 2018, 499: 138-150. doi: 10.1016/j.chemgeo.2018.09.023
Wedepohl K H. The composition of the continental crust[J]. The Geochimica et Cosmochimica Acta, 1995, 59, 1217-1232. doi: 10.1016/0016-7037(95)00038-2
Xu Cheng, Chakhmouradian A R, Taylor R N, et al. Origin of carbonatites in the South Qinling orogen: Implications for crustal recycling and timing of collision between the South and North China Blocks[J]. Geochimica et Cosmochimica Acta, 2014, 143: 189-206. doi: 10.1016/j.gca.2014.03.041
Xu Cheng, Wang Linjun, Song Wenlei, et al. Carbonatites in China: A review for genesis and mineralization[J]. Geoscience Frontiers, 2010, 1(1): 105-114. doi: 10.1016/j.gsf.2010.09.001
Yang Yueheng, Wu Fuyuan, Li Yang. In situ U-Pb dating of bastnaesite by LA-ICP-MS[J]. Journal of Analytical Atomic Spectrometry, 2014, 29(6): 1017-1023. doi: 10.1039/C4JA00001C
Ying Yuancan, Chen Wei, Lu Jue, et al. In situ U-Th-Pb ages of the Miaoya carbonatite complex in the South Qinling orogenic belt, central China[J]. Lithos, 2017, 290: 159-171
Zhang Wei, Chen Wei Terry, Gao Jianfeng, et al. Two episodes of REE mineralization in the Qinling Orogenic Belt, Central China: in-situ U-Th-Pb dating of bastnäsite and monazite[J]. Mineralium Deposita, 2019, 54(8): 1265-1280. doi: 10.1007/s00126-019-00875-7
Zheng Hui, Chen Huayong, Li Dengfeng, et al. 2020. Timing of carbonatite-hosted U-polymetallic mineralization in the supergiant Huayangchuan deposit, Qinling Orogen: constraints from titanite U–Pb and molybdenite Re–Os dating[J]. Geoscience Frontiers, 2020, 11: 1581-1592. doi: 10.1016/j.gsf.2020.03.001
Zheng Y F, Gao T S, Wu Y B, et al. Fluid flow during exhumation of deeply subducted continental crust: zircon U-Pb age and O-isotope studies of a quartz vein within ultrahigh-pressure eclogite[J]. Journal of Metamorphic Geology, 2007, 25(2): 267-283. doi: 10.1111/j.1525-1314.2007.00696.x
-
图(7)
表(4)
计量
- 文章访问数: 630
- PDF下载数: 14
- 施引文献: 0