中国地质学会岩矿测试技术专业委员会、国家地质实验测试中心主办

应用能谱-扫描电镜和X射线衍射技术研究原煤伴生矿物中稀土和放射性元素赋存形式

杨瑞林, 白燕. 应用能谱-扫描电镜和X射线衍射技术研究原煤伴生矿物中稀土和放射性元素赋存形式[J]. 岩矿测试, 2019, 38(4): 382-393. doi: 10.15898/j.cnki.11-2131/td.201811210125
引用本文: 杨瑞林, 白燕. 应用能谱-扫描电镜和X射线衍射技术研究原煤伴生矿物中稀土和放射性元素赋存形式[J]. 岩矿测试, 2019, 38(4): 382-393. doi: 10.15898/j.cnki.11-2131/td.201811210125
Rui-lin YANG, Yan BAI. The Occurrence of Rare Earth and Radioactive Elements in the Associated Minerals with Raw Coal by EDX-SEM and XRD[J]. Rock and Mineral Analysis, 2019, 38(4): 382-393. doi: 10.15898/j.cnki.11-2131/td.201811210125
Citation: Rui-lin YANG, Yan BAI. The Occurrence of Rare Earth and Radioactive Elements in the Associated Minerals with Raw Coal by EDX-SEM and XRD[J]. Rock and Mineral Analysis, 2019, 38(4): 382-393. doi: 10.15898/j.cnki.11-2131/td.201811210125

应用能谱-扫描电镜和X射线衍射技术研究原煤伴生矿物中稀土和放射性元素赋存形式

  • 基金项目:
    山西省国土资源厅资助项目"山西省霍西煤田煤炭中共伴生矿产资源调查与评价"(SXZDF20161029)
详细信息
    作者简介: 杨瑞林, 高级实验师, 主要从事电子显微技术的应用研究。E-mail:3500895295@qq.com
  • 中图分类号: TQ533.1;P575.2;P575.5

The Occurrence of Rare Earth and Radioactive Elements in the Associated Minerals with Raw Coal by EDX-SEM and XRD

  • 研究原煤中稀土及放射性元素的赋存形式,对原煤是集中还是分散利用、燃煤过程中粉煤灰的排放截留、从原煤或粉煤灰中提取稀土及放射性元素等方面都具有指导意义。由前人研究可知不同矿区原煤中稀土及放射性元素的赋存形式有差异。本文研究了山西省霍西煤田两个矿区175个煤样中稀土及放射性元素的赋存形式,应用背散射电子图像(BSEI)定位分析区域,应用BSEI、能谱-扫描电镜法(EDX-SEM)中的面分析(EDS-mapping)和粉晶X射线衍射法确定了主要伴生矿物,应用BSEI和EDX-SEM中的点分析(EDS-point)确定了微量伴生矿物。在煤样中发现了铈镧钕钇镝钪六种稀土元素及一种放射性元素钍,其中铈、镧和钕主要以磷酸盐形式伴生于高岭石类矿物中,部分伴生在含氧化铝或氧化硅较多的矿物中,少量存在于碳中;钇、镝以磷酸盐或氧化物形式独立存在于碳中;在部分锆石、独居石中分别发现了钪和钍。研究表明,该矿区煤样中稀土元素主要以细粒自生矿物的形式伴生在其他矿物中,少数以独立矿物的形式存在于碳中,放射性元素钍伴生在独居石中。
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  • 图 1  煤样不同区域的背散射电子图像和二次电子形貌图像s

    Figure 1. 

    图 2  煤样某一区域的背散射电子组成图像以及元素分布图

    Figure 2. 

    图 3  白色灰度等级区域的点分析结果(与图 2a中的W区对应)

    Figure 3. 

    图 4  某煤样的X射线衍射物相分析图谱

    Figure 4. 

    图 5  原煤样品批1某区域的背散射电子图像及标记微区的X射线能谱分析结果

    Figure 5. 

    图 6  原煤样品批2某区域的背散射电子图像及标记微区的X射线能谱分析结果

    Figure 6. 

    图 7  原煤样品批3某区域的背散射电子图像及标记微区的X射线能谱分析结果

    Figure 7. 

    表 1  代表性分析点所属煤样中的元素成分及伴生矿物

    Table 1.  Elemental composition and associated minerals in representative analysis points of coal samples

    原煤样品
    图像编号
    SEM-EDS检出的元素 XRD检出的伴生矿物
    图 5-a Al, Si, O; Ca, O; Ca, S, O; P, Ce, O; Fe, O; Ti, O; Si, O; Se, Pb 硅酸铝, 高岭石类矿物, 二氧化硅, 氧化钙, 氧化钛, 三氧化二铁, 磷酸铈, 硒化铅
    图 5-b Al, Si, O; Ca, S, O; Ca, C, O; Fe, O; Mg, O; Ca, S, Fe, Mg, O; P, Ce, O 高岭石类矿物, 硫酸钙, 方解石, 磷酸铈, 氧化铁, 氧化镁
    图 5-c Ca, C, O; Fe, S; Al, Si, O; O, P, Ce, La, Nd; Ti, O 高岭石类矿物, 碳酸钙, 氧化钛, 硫化铁
    图 5-d Al, Si, O; Mg, S, K, Fe; Ti, O; Zr, O; Fe, Mg, Ca, C, O; O, P, Ce, La, W; Fe, Cu, S 氧化铝, 勃姆石, 高岭石类矿物, 低辉铜矿, 硫化钾
    图 6-b Ca, C, O; Fe, S; Al, Si, O; Ti, O; Fe, S; O, P, Ce; O, P, Ce, La, Na, W 高岭石类矿物, 方解石, 硫化铁, 磷酸铈, 氧化钛
    图 6-ac Al, Si, O; O, P, Ce, Nd, La, Ca; Ti, O; Fe, S; Ca, C, O; O, P, W; Fe, Cu, S; Ag, Ce, Nd, La, P, O; Ag, Ce, Nd, La, Th, W, P, O 高岭石类矿物, 硫化铁, 氧化钛, 低辉铜矿, 磷酸镧
    图 6-d Al, Si, O; Ti, O; Ca, O; Mo, O; O, P, Ce, W; O, P, Y, Dy 高岭石类矿物, 二氧化钛, 氧化钼
    图 7-a Al, Si, O; Ti, O; Zr, O, Si; Y, Ir, Ta, Dy, O; O, S, Cu, Zn; O, P, Ce, La, Nd 高岭石类矿物, 硅铝石, 氧化钛, 硫酸锌, 二氧化硅, 锆石, 氧化钕
    图 7-b Al, Si, O; Zr, O; Ti, O, K, Fe; Ti, O; Fe, Cu, S; Al, Zr, Sc, Ir, O; O, P, Ce, Nd 高岭石类矿物, 氧化钛, 氧化铁, 硫化亚铜
    图 7-c Al, Si, O, K; Ti, O; Zn, S; O, P, Ce, Nd, La; Fe, S; Cu, Fe, S; Zr, Ag, Sc, O; Zr, Ag, Sc, Ir, O 高岭石类矿物, 氧化钛, 硫化铁, 磷酸镧
    下载: 导出CSV

    表 2  代表性分析点所属煤样中稀土及放射性元素的赋存形式

    Table 2.  Occurrence modes of rare earth elements and radioactive elements in representative analysis points of coal samples

    元素 元素的赋存形式 矿物的赋存形式 原煤样品图像示例
    铈,镧,钕 稀土磷酸盐
    稀土磷酸盐
    稀土磷酸盐
    独居石
    独居石
    嵌在高岭石类矿物中
    嵌在氧化硅为主矿物中
    嵌在氧化铝为主矿物中
    嵌在高岭石类矿物中
    独立生长在碳中
    图 5-a
    图 5-b, 图 7-c
    图 5-d
    图 3, 图 5-c, 图 6-a, 图 6-c
    图 6-b
    伴生在独居石中 嵌在高岭石类矿物中 图 6-a
    钇,镝 磷钇矿, 镝与钇伴

    氧化钇, 氧化镝, 镝与钇伴生
    独立生长在碳中独立生长在碳中 图 6-d
    图 7-a
    伴生在锆石中
    伴生在锆石中
    嵌在高岭石类矿物中
    嵌在氧化硅为主矿物中
    图 7-b
    图 7-c
    下载: 导出CSV
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收稿日期:  2018-11-12
修回日期:  2019-03-11
录用日期:  2019-04-09

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