Experimental Study and Industrial Application of Single Reverse Flotation of Wangji Collophanite(Ph1)
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摘要:
王集Ph1层胶磷矿原浮选工艺是正反浮选,在生产实践中存在最终尾矿品位偏高,产率和回收率偏低的问题。本文通过实验研究、工艺改造,将原正反浮选工艺改为单一反浮选工艺,生产工艺指标得到改善,回收率提高了9.78个百分点。
Abstract:The former flotation process of Wangji Collophanite(Ph1)is direct-reverse flotation processes. In the production practice, there are some problems such as high grade of final tailings, low yield and recovery rate. In this paper, through test research and technological transformation, the original direct-reverse flotation processes was changed into single reverse flotation process, and the production process index was improved ,the recovery was improved by 9.78 percentages.
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Key words:
- Collophanite /
- Reverse flotation /
- Industrialization
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表 1 矿物多元素分析结果 /%
Table 1. Analysis results of mineral multi-elements
P2O5 MgO Fe2O3 Al2O3 CaO A-I I-L F 22.74 4.48 1.27 1.52 42.11 9.74 15.47 2.03 表 2 实验室实验结果
Table 2. Results of laboratory test
产物名称 产率/% 品位/% 回收率/% P2O5 MgO 精矿 67.03 30.66 0.42 87.63 尾矿 32.97 8.79 8.35 11.37 中矿 17.84 25.59 1.04 19.47 表 3 产品多元素化学分析结果 /%
Table 3. Multi-element chemical analysis results of products
名称 P2O5 MgO Fe2O3 Al2O3 CaO A-I I-L F 原矿 22.74 4.48 1.27 1.52 42.11 9.74 15.47 2.03 精矿 29.57 1.12 1.36 1.63 44.73 11.44 5.83 2.64 尾矿 8.38 11.7 1.13 1.05 35.61 8.72 27.59 0.84 表 4 正反浮选工艺指标
Table 4. Process indexes of direct-reverse flotation
产品名称 产率/% 品位/% 回收率/% P2O5 MgO P2O5 精矿 59.45 29.88 1.08 79.51 尾矿1 35.16 11.28 5.3 17.75 尾矿2 5.39 11.47 12.75 2.74 原矿 100 22.34 3.18 100 表 5 单一反浮选工艺指标
Table 5. Process index of single reverse flotation
产品名称 产率/% 品位/% 回收率/% P2O5 MgO P2O5 精矿 69.68 29.13 1.15 89.30 尾矿 30.32 8.02 11.72 10.70 原矿 100 22.73 4.39 100 表 6 正反浮选和单一反浮选工艺药剂消耗对比
Table 6. Reagents consumption comparison between reverse flotation and single reverse flotation processes
药剂名称 单价/
(元·kg-1)正反浮选 单一反浮选 单耗/
(kg·t-1)成本/
元单耗/
(kg·t-1)成本/
元碳酸钠 1.33 9.28 12.34 -- -- 抑制剂 5 3.65 18.25 -- -- 正浮选捕收剂 4 0.94 3.76 -- -- 反浮选捕收剂 6.2 1.04 6.45 0.94 5.89 硫酸 0.48 39.00 18.72 68.02 26.53 合计 59.52 32.42 -
[1] 李成秀, 文书明. 我国磷矿选矿现状及其进展[J]. 矿产综合利用, 2010(2):22-25. doi: 10.3969/j.issn.1000-6532.2010.02.007
LI C X, WEN S M. Current status and development of phosphate ore processing in China[J]. Comprehensive Utilization of Mineral Resources, 2010(2):22-25. doi: 10.3969/j.issn.1000-6532.2010.02.007
[2] 王涛, 付磊, 李宁. 某硅钙质胶磷矿正反浮选试验研究[J]. 矿产综合利用, 2020(2):91-95. doi: 10.3969/j.issn.1000-6532.2020.02.016
WANG T, FU L, LI N. Study on direct-reverse flotation of a silica calcinate phosphate ore[J]. Multipurpose Utilization of Mineral Resources, 2020(2):91-95. doi: 10.3969/j.issn.1000-6532.2020.02.016
[3] 赵辉, 刘志红. 贵州某硅-钙质胶磷矿双反浮选试验研究[J]. 矿冶工程, 2017, 37(2):57-59. doi: 10.3969/j.issn.0253-6099.2017.02.014
ZHAO H, LIU Z H. Experimental study on double reverse flotation of a silica-calcareous collophanite in Guizhou[J]. Mining and Metallurgy Engineering, 2017, 37(2):57-59. doi: 10.3969/j.issn.0253-6099.2017.02.014
[4] 吴中贤, 姜效军, 陶东平. 新型胶磷矿反浮选脱硅阳离子捕收剂试验研究[J]. 矿产综合利用, 2020(5):115-119. doi: 10.3969/j.issn.1000-6532.2020.05.017
WU Z X, JIANG X J, TAO D P. Experimental study on a novel cationic collector for reverse flotation of collophane for silica removal[J]. Multipurpose Utilization of Mineral Resources, 2020(5):115-119. doi: 10.3969/j.issn.1000-6532.2020.05.017
[5] 陈彰瑞. 湖北省磷块岩矿床原矿石的工艺矿相特征[J]. 化工矿山技术, 1991, 20(2):20-23.
CHEN Z R. Characteristics of process mineral facies of the original ore of phosphorite block deposit in Hubei Province[J]. Chemical Mine Technology, 1991, 20(2):20-23.
[6] 何新建, 傅克文, 孙立田. 王集Ph1层胶磷矿正反浮选工艺优化的工业试验研究[J]. 有色金属(选矿部分), 2016(5):59-60.
HE X J, FU K W, SUN L T. Study on the flotation process optimization of Ph1 layer collophanite[J]. Nonferrous Metals (Mineral Processing Section), 2016(5):59-60.
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