Development and Application of the Current Situation and Development Trend of Platinum-Rhenium Reforming Catalyst
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摘要:
这是一篇陶瓷及复合材料领域的论文。我国铂铼催化剂行业随着原油加工技术需求不断提升发展，催化剂是石油冶炼的核心，其中浸渍法是重整催化剂主要制取方法。催化重整催化剂一般为铂-铼催化剂，未来研究趋势主要是提高催化剂的铼含量降低铂用量。铂铼催化剂的特点是稳定性好，选择性稍差，可以长周期稳定运转，再生周期可以达到3~5年，在半再生重整工艺大规模生产中得到了广泛应用。从20世纪后半叶以来，我国炼油催化剂市场现已形成了以中国石化和中国石油旗下催化剂公司为主，以民营催化剂公司为辅的市场格局，催化剂需求量稳定在10 t/a 以上。
Abstract:This is an essay in the field of ceramics and composites.With the increasing demand for crude oil processing technology, China′s platinum rhenium catalyst industry is also developing. Catalyst is the core material of petroleum smelting, and impregnation method is the most important preparation method of reforming catalyst. Catalytic reforming catalysts generally refer to trace rhenium catalysts. The main research direction in the future is to increase the rhenium content of the catalyst and reduce the amount of platinum in the catalyst. The characteristics of platinum-rhenium catalysts are good stability, slightly poor selectivity, long-term stable operation, and regeneration cycle that can reach 3~5 years, which have been widely used in large-scale production of semi-regenerative reforming processes. Since the late 20th century, China′s refining catalyst market has formed a′Sinopec and PetroChina′s catalyst companies, supplemented by private catalyst companies′ market structure, catalyst demand is stable at more than 10 tons per year.
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国家 公司 牌号 金属组分/% 载体 形状 应用年份 铂 铼 其他 美国 雪弗龙 A 0.60 Re / 改进载体 1967 B 0.30 0.44 / 1969 D Pt Re / 1972 E 0.30 0.30 / γ-Al2O3 圆柱 1975 F 0.30 0.60 / γ-Al2O3 条形 1978 恩格哈德（Englhard Co） E-601 0.35 0.35 / γ-Al2O3 条形 / E-611 0.275 0.275 / γ-Al2O3 条形 / E-802 0.26 0.50 / γ-Al2O3 条形 / E-803 0.22 0.42 / γ-Al2O3 条形 / E-804 0.22 0.22 / γ-Al2O3 条形 / 环球油品公司（UOP） R-16G 0.375 0.375 / γ-小球 1968 R-62 0.22 0.44 / γ-小球 1982 R-56 0.25 0.40 / γ-挤条 1992 R-72 0.30 / Ge γ-小球 1994 R-86 0.25 0.4 / γ-挤条 2001 埃克森美孚（ExxonMobil） KX-120 0.30 / Ir：0.30 圆柱条 1971 KX-130 0.30 / Ir：0.30 1971 KX-160 Pt Re / 1971 KX-170 Pt Re / 1971 法国 法国石油研究院(IFP) RG-451 0.30 / Ir：0.04Ti：0.24 η-挤条 1973 RG-482 0.30 0.30 / γ-挤条 1982 RG-492 0.30 0.60 / γ-挤条 / RG-582A 0.275 0.275 X γ-挤条 1994 RG-582 0.30 0.20 X γ-挤条 1994 RG-682A 0.275 0.40 X γ-挤条 / RG-682 0.30 0.40 X γ-挤条 / 荷兰 阿克苏国际化学公司(AKZO Chemicals intern BV) CK-433 0.3 0.3 / γ-Al2O3 条形 / 
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表 2 中国石油化工科学研究院铂-铼重整催化剂产品
Table 2. Chinese platinum-rhenium reforming catalyst products
产品编号 金属组分/% 载体 球形直径
(形状)d/mm应用
年份石科院 工业 铂 铼 其他元素 / 7341 0.5 0.45 / η- Al2O3 1.7-2.3 1974 / CB-5 0.5 0.35 / η- Al2O3 1.5-2.25 1982 / 3741-2 0.5 0.45 / η- Al2O3 1.7-2.3 1984 PR-A CB-6 0.5 0.27 / η- Al2O3 1.5-2.5 1985 PR-B CB-7 0.21 0.42 / η- Al2O3 1.5-2.2 1989 / CB-8 0.15 0.30 / η- Al2O3 1.5-2.2 1991 PR-C CB-60 0.25 0.26 无 SB 条 1995 PR-D CB-70 0.21 0.46 无 SB 条 1995 PR-D 3923 / / / / / / PRT-C PRT-C 0.25 0.26 含有 SB 条 2002 PRT-D PRT-D 0.21 0.46 含有 SB 条 2002 / R-最新 0.25 0.40 无 不详 / /
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专利授权号 专利名称 专利权人 CN105413714B 一种铂铼重整催化剂的制备方法和铂铼重整催化剂 中国石油化工股份有限公司；
中国石化催化剂有限公司CN105709784B 一种硫化型铂铼重整催化剂的制备方法 中国石油化工股份有限公司；
中国石油化工股份有限公司抚顺石油化工研究院CN102140366B 一种铂铼重整催化剂的初始反应方法 中国石油化工股份有限公司；
中国石油化工股份有限公司石油化工科学研究院CN1191121C 一种铂-铼重整催化剂及制备方法 中国石油化工股份有限公司；
中国石油化工股份有限公司石油化工科学研究院CN109954505A 一种还原态铂铼重整催化剂 中国石油化工股份有限公司；
中国石油化工股份有限公司大连石油化工研究院
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