Geochronology, geochemistry and geological sig-nificance of the Early Cretaceous alkali feldspar granites in the Yilehuli Mountain, Da Hinggan, Mountain
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摘要:
对大兴安岭伊勒呼里山早白垩世碱长花岗岩进行了岩相学、地球化学、LA-ICP-MS锆石U-Pb定年研究。伊勒呼里山地区碱长花岗岩主量元素具有富Si、富碱,贫Mg、Ca的特征;微量元素亏损Sr、P、Eu、Ti,富集K、Rb、Th等不相容元素,元素地球化学特征表明,岩体为铝质A型花岗岩(A/CNK=0.88~1.21,A/NK=0.94~1.49)。测年结果显示,粗中粒碱长花岗岩的锆石年龄为140.3±1.0Ma,细中粒碱长花岗岩锆石年龄为137.9±0.8Ma,均形成于早白垩世。结合区域研究资料,伊勒呼里山地区碱长花岗岩岩体的形成与蒙古-鄂霍茨克洋闭合后的岩石圈伸展密切相关,其岩浆源区可能为地壳物质的部分熔融。
Abstract:Petrographic and geochemical data and LA-ICP-MS zircon U-Pb ages were obtained for Early Cretaceous alkali feldspar granites of the Yilehuli Mountain. The major elements of Yilehuli alkali feldspar granites are high in Si, ALK, and low in Mg, Ca. Trace elements are enriched in incompatible elements such as K, Rb and Th, and depleted in Sr, P, Eu and Ti. Geochemical features indicate that alkali feldspar granites are aluminum A-type granites (A/CNK=0.88~1.21, A/NK=0.94~1.49). LA-ICP-MS zircon U-Pb age data of coarse-medium alkali feldspar granites and fine-medium alkali feldspar granites are 140.3 ±1.0Ma and 137.9 ±0.8Ma, respectively, indicating that intrusive rocks were formed in Early Cretaceous. Combined with regional geological investiga-tion, the authors hold that the formation of Yilehuli plutons was closely related to lithospheric extension caused by closure of the Mongol-Okhotsk Ocean, and that the primary magma was derived from partial melting of crustal materials.
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Key words:
- Early Cretaceous /
- geochemistry /
- zircon U-Pb age /
- A-type granite /
- Yilehuli Mountain
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图 1 伊勒呼里山地区中生代侵入岩分布地质简图(据参考文献[5]修改)
Figure 1.
表 1 伊勒呼里山早白垩世花岗岩LA-ICP-MS锆石U-Th-Pb定年结果(D0410)
Table 1. LA-ICP-MS zircon U-Th-Pb data for Early Cretaceous granites in Yilehuli Mountain
分析序号 含量/10-6 同位素比值 年龄/Ma Pb U 206Pb/238U 1σ err% 207Pb/235U 1σ err% 207Pb/206Pb 1σ err% 208Pb/232Th 1σ err% 232Th/238U 1σ err% 206Pb/238U 1σ 207Pb/235U 1σ 207Pb/206Pb 1σ 中粗粒碱长质花岗岩,D0410 1 9 342 0.0225 0.0001 0.54 0.1574 0.0041 2.60 0.0507 0.0013 2.59 0.0079 0.0001 0.73 0.8196 0.0061 0.75 143 1 148 4 227 60 2 3 133 0.0227 0.0002 0.88 0.1487 0.0080 5.36 0.0474 0.0025 5.32 0.0075 0.0001 1.58 0.6675 0.0034 0.51 145 1 141 8 68 127 3 4 174 0.0221 0.0002 0.72 0.1495 0.0057 3.80 0.0490 0.0018 3.76 0.0078 0.0001 0.90 0.6852 0.0024 0.36 141 1 141 5 147 88 4 7 268 0.0222 0.0001 0.57 0.1565 0.0041 2.61 0.0510 0.0013 2.57 0.0078 0.0001 0.60 0.9643 0.0052 0.53 142 1 148 4 240 59 5 15 623 0.0224 0.0001 0.49 0.1561 0.0019 1.22 0.0506 0.0006 1.20 0.0080 0.0001 0.46 0.4852 0.0017 0.36 143 1 147 2 222 28 6 5 206 0.0223 0.0001 0.62 0.1475 0.0052 3.55 0.0479 0.0017 3.45 0.0087 0.0001 0.92 0.6622 0.0026 0.40 142 1 140 5 94 82 7 5 175 0.0216 0.0002 0.79 0.1516 0.0064 4.20 0.0507 0.0021 4.09 0.0079 0.0001 0.94 0.8952 0.0060 0.67 138 1 143 6 226 95 8 3 131 0.0209 0.0002 0.93 0.1474 0.0073 4.94 0.0511 0.0024 4.79 0.0071 0.0002 2.22 0.6022 0.0084 1.40 133 1 140 7 246 110 9 6 244 0.0217 0.0001 0.62 0.1439 0.0047 3.25 0.0481 0.0015 3.20 0.0081 0.0001 0.88 0.6602 0.0027 0.40 138 1 136 4 104 76 10 5 207 0.0218 0.0002 0.80 0.1493 0.0059 3.95 0.0497 0.0020 3.93 0.0082 0.0001 1.59 0.6368 0.0024 0.38 139 1 141 6 180 92 11 9 352 0.0224 0.0001 0.60 0.1466 0.0025 1.70 0.0474 0.0008 1.63 0.0084 0.0001 0.43 0.7885 0.0039 0.50 143 1 139 2 68 39 12 7 255 0.0226 0.0001 0.60 0.1502 0.0039 2.57 0.0482 0.0012 2.53 0.0081 0.0001 0.70 0.7232 0.0029 0.40 144 1 142 4 109 60 13 8 319 0.0215 0.0001 0.53 0.1517 0.0035 2.31 0.0511 0.0012 2.26 0.0081 0.0001 0.67 0.8151 0.0077 0.95 137 1 143 3 243 52 14 5 211 0.0219 0.0001 0.61 0.1473 0.0049 3.35 0.0487 0.0016 3.26 0.0086 0.0001 0.95 0.6870 0.0089 1.29 140 1 140 5 135 77 15 24 770 0.0222 0.0002 1.01 0.1518 0.0017 1.14 0.0495 0.0005 1.00 0.0083 0.0001 0.65 1.4382 0.0062 0.43 142 1 143 2 171 23 16 5 201 0.0223 0.0001 0.65 0.1545 0.0045 2.93 0.0502 0.0014 2.85 0.0085 0.0001 1.07 0.6102 0.0084 1.38 142 1 146 4 204 66 17 3 111 0.0217 0.0003 1.16 0.1533 0.0091 5.93 0.0513 0.0029 5.60 0.0091 0.0001 1.22 0.9005 0.0047 0.52 138 2 145 9 252 129 18 11 447 0.0219 0.0001 0.53 0.1465 0.0019 1.30 0.0486 0.0006 1.26 0.0084 0.0001 0.64 0.7845 0.0037 0.47 140 1 139 2 126 30 19 8 329 0.0219 0.0001 0.50 0.1479 0.0031 2.08 0.0491 0.0010 1.99 0.0091 0.0001 0.58 0.7240 0.0024 0.33 139 1 140 3 152 47 20 9 325 0.0215 0.0001 0.53 0.1545 0.0035 2.24 0.0521 0.0011 2.20 0.0081 0.0001 0.67 1.2785 0.0208 1.62 137 1 146 3 290 50 21 2 86 0.0215 0.0003 1.17 0.1508 0.0122 8.11 0.0506 0.0041 8.09 0.0084 0.0002 2.37 0.6421 0.0030 0.46 137 2 143 12 224 187 22 5 198 0.0216 0.0001 0.63 0.1419 0.0049 3.47 0.0475 0.0016 3.43 0.0079 0.0001 0.95 0.6191 0.0056 0.91 138 1 135 5 74 81 23 6 231 0.0224 0.0002 0.83 0.1588 0.0043 2.71 0.0514 0.0013 2.57 0.0082 0.0001 0.63 1.0333 0.0105 1.01 143 1 150 4 258 59 24 6 254 0.0216 0.0002 0.77 0.1526 0.0037 2.40 0.0513 0.0012 2.26 0.0081 0.0001 0.62 0.8131 0.0051 0.63 138 1 144 3 252 52 25 5 217 0.0222 0.0001 0.64 0.1525 0.0045 2.94 0.0499 0.0015 2.91 0.0084 0.0001 0.80 0.6496 0.0028 0.43 141 1 144 4 189 68 中粗粒碱长质花岗岩,D0410 1 23 795 0.022 0.0002 0.94 0.1557 0.0035 2.23 0.0512 0.001 2.01 0.0072 0.0001 0.75 1.3066 0.0022 0.17 141 1 147 3 252 46 2 2 87 0.022 0.0004 1.75 0.1591 0.0105 6.58 0.0525 0.0037 7.14 0.0064 0.0002 3.86 1.1638 0.0134 1.15 140 2 150 10 306 163 3 5 186 0.0216 0.0003 1.25 0.1446 0.0085 5.9 0.0485 0.0028 5.79 0.0069 0.0001 2.09 0.8203 0.0012 0.15 138 2 137 8 124 136 4 4 148 0.022 0.0003 1.28 0.1553 0.0106 6.84 0.0513 0.0034 6.61 0.0069 0.0002 2.65 0.8119 0.0077 0.95 140 2 147 10 254 152 5 2 68 0.0211 0.0003 1.5 0.1607 0.0129 8.04 0.0551 0.0041 7.52 0.0067 0.0002 3.33 1.3812 0.0165 1.2 135 2 151 12 417 168 6 7 240 0.0218 0.0002 1.08 0.1553 0.0073 4.68 0.0518 0.0023 4.53 0.0065 0.0001 0.89 1.6087 0.0081 0.51 139 1 147 7 275 104 7 13 390 0.0219 0.0002 0.73 0.1519 0.0041 2.69 0.0504 0.0013 2.65 0.0069 0 0.45 2.436 0.0177 0.73 140 1 144 4 211 62 8 5 206 0.0212 0.0002 1.09 0.1595 0.0089 5.6 0.0545 0.003 5.47 0.0066 0.0002 2.58 0.6629 0.0007 0.11 135 1 150 8 393 123 9 5 183 0.0217 0.0005 2.12 0.1634 0.015 9.19 0.0545 0.005 9.13 0.0067 0.0002 2.74 0.9998 0.0068 0.68 139 3 154 14 393 205 10 2 76 0.0214 0.0003 1.46 0.1608 0.011 6.86 0.0544 0.004 7.41 0.0065 0.0003 4.03 1.0006 0.0061 0.61 137 2 151 10 388 166 11 2 61 0.0219 0.0004 1.71 0.1391 0.0131 9.44 0.046 0.005 10.78 0.0075 0.0004 5.56 0.8453 0.0017 0.2 140 2 132 12 0 260 12 12 478 0.0212 0.0002 0.84 0.1422 0.006 4.21 0.0487 0.002 4.09 0.0062 0.0001 0.96 1.1916 0.0014 0.12 135 1 135 6 131 96 13 2 90 0.0218 0.0006 2.78 0.1555 0.0112 7.2 0.0516 0.0039 7.59 0.0068 0.0003 4.62 0.9944 0.005 0.5 139 4 147 11 268 174 14 3 108 0.0211 0.0004 1.96 0.1579 0.0154 9.73 0.0542 0.0055 10.08 0.0063 0.0003 4.02 0.7825 0.0021 0.27 135 3 149 14 378 227 15 1 56 0.021 0.0008 3.65 0.1665 0.0194 11.67 0.0576 0.0063 10.88 0.0062 0.0004 6.64 0.852 0.0033 0.39 134 5 156 18 515 239 16 1 54 0.0218 0.0006 2.75 0.1573 0.0147 9.38 0.0524 0.0062 11.76 0.0039 0.0008 20.03 0.8927 0.0045 0.5 139 4 148 14 304 268 17 5 198 0.0216 0.0003 1.25 0.1435 0.0079 5.52 0.0482 0.0026 5.46 0.0059 0.0001 1.29 1.4964 0.0145 0.97 138 2 136 8 111 129 18 3 109 0.022 0.0004 1.97 0.1302 0.0113 8.67 0.0429 0.0053 12.41 0.0068 0.0002 2.96 1.0084 0.0054 0.54 140 3 124 11 -175 309 19 6 222 0.0214 0.0002 1.02 0.1467 0.0072 4.93 0.0498 0.0023 4.67 0.0068 0.0001 1.6 0.9028 0.0072 0.79 136 1 139 7 185 109 20 5 196 0.0214 0.0002 1.14 0.1722 0.0085 4.91 0.0583 0.0028 4.76 0.0061 0.0001 2.34 0.7509 0.0015 0.2 137 2 161 8 540 104 21 1 56 0.0216 0.0004 2.08 0.1423 0.0111 7.78 0.0479 0.0045 9.37 0.0085 0.0006 7.42 0.7843 0.0041 0.52 137 3 135 11 93 222 22 1 25 0.0216 0.0006 2.94 0.1642 0.0181 11.05 0.055 0.0055 9.94 0.0087 0.0016 18.59 0.9261 0.0024 0.26 138 4 154 17 413 222 23 5 217 0.0214 0.0003 1.25 0.1549 0.0091 5.87 0.0525 0.0031 5.98 0.0065 0.0001 2.18 0.8261 0.0024 0.3 137 2 146 9 307 136 24 3 114 0.0218 0.0004 1.8 0.1635 0.0138 8.42 0.0544 0.0052 9.62 0.0071 0.0006 7.88 0.8378 0.0034 0.41 139 3 154 13 386 216 25 10 375 0.022 0.0002 0.93 0.1482 0.0055 3.68 0.0489 0.0017 3.57 0.0069 0.0001 1.17 1.1747 0.0029 0.25 140 1 140 5 143 84 表 2 伊勒呼里山碱长花岗岩体主量、微量和稀土元素组成
Table 2. Major, trace element and REE data components for Yilehuli intrusion
岩性 粗中粒、细粒似斑状碱长花岗岩 样品号 D0410 D1396 D1397 P12TC29 P12TC39 P12TC94 P15TC34 P15TC38 P15TC96 P22LT58 P22TC20 P25TC360 SiO2 74.26 76.2 75.58 65.21 69.78 67.88 75.64 75.84 74.38 75.04 75.98 75.62 TiO2 0.19 0.17 0.16 0.12 0.22 0.21 0.21 0.24 0.37 0.23 0.19 0.54 Al2O3 12.59 12.2 12.13 15.51 15.13 15.14 11.27 11.61 12.08 11.77 12.66 11.97 Fe2O3 1.22 0.79 1.03 2.78 1.96 2.4 2.04 1.47 1.49 1.75 0.93 1.33 FeO 0.66 1.36 2.09 3.18 2.62 3.16 1.62 1.84 1.54 1.3 1.18 1.54 MnO 0.04 0.02 0.05 0.03 0.07 0.05 0.02 0.01 0.06 0.04 0.04 0.05 MgO 0.48 0.33 0.35 1.15 0.68 0.67 0.03 0.02 0.2 0.3 0.24 0.36 CaO 0.37 0.22 0.23 1.89 0.91 1.18 0.41 0.39 0.59 0.7 0.54 0.14 Na2O 4.62 3.93 3.94 3.7 3.87 4.47 4.36 3.92 4.29 4.21 3.79 4.28 K2O 4.5 4.62 4.63 4 4.17 4.26 4.49 4.78 4.32 4.69 4.63 3.78 P2O5 0.02 0.03 0.01 0.02 0.08 0.06 0.06 0.13 0.1 0.05 0.05 0.32 烧失量 0.36 0.11 0.02 2.28 0.02 0 0.04 0.02 0.22 0 0.08 0.12 总计 99.31 99.98 100.22 99.87 99.51 99.48 100.19 100.27 99.64 100.08 100.31 100.05 K2O/Na2O 0.97 1.18 1.18 1.08 1.08 0.95 1.03 1.22 1.01 1.22 1.11 0.88 K2O+Na2O 9.12 8.55 8.57 7.7 8.04 8.73 8.85 8.7 8.61 8.9 8.42 8.06 A/CNK 0.96 1.03 1.02 1.12 1.21 1.07 0.88 0.94 0.94 1.04 0.89 1.05 A/NK 1.01 1.06 1.05 1.49 1.39 1.26 0.94 1.00 1.03 0.98 1.12 1.07 Mg# 56.27 30.21 23.01 39.22 31.65 27.45 3.2 1.9 18.81 26.63 29.17 29.43 Ba 296 91.6 104 27.6 15.9 243 607 359 280 277 83 131 Rb 127 142 122 125 140 115 118 132 121 122 151 121 Sr 98.4 15.2 13.3 19.2 21.4 80.1 60.3 42.4 40.4 46.1 14.6 23.3 Zr 273 140 116 237 218 174 185 137 280 179 159 250 Cr 33 7.73 5.32 7.13 7.67 6.71 7.23 6.83 6.46 6.43 7.08 7.53 Sc 2.5 2.78 1.1 2.4 3.11 3.03 3.11 2.09 5.86 2.92 2.32 0.92 Nb 17.3 14.2 13.4 18.6 18.9 13.4 14.3 13.1 17.3 14.9 15.8 19.5 Hf 5.33 5.59 5.81 9.12 8.02 6.17 6.35 5.01 8.37 5.53 9.7 7.18 Ta 1.46 1 1.54 1.6 1.12 1.16 1.14 0.99 2.42 1.56 8.93 1.4 Th 1.76 9.16 5.9 17.5 19.7 15.4 11.9 8.97 16.5 11.6 16.7 9.94 Y 14.7 9.13 12.1 11.6 10.4 16.6 11.9 12.1 37.2 24.6 33.1 14.1 V 15.2 3.39 0.14 2.23 1.11 12.8 7.39 5.55 13.4 9.56 1.86 8.7 La 28.8 9.73 20.5 16.3 24.6 30.2 19.3 10.2 47.2 30.7 54.5 13.5 Ce 69.3 19.1 43.4 29.2 37.6 63.3 40 17.4 101 78.9 122 61.2 Pr 6.25 2.29 5.6 2.68 3.41 7.35 5.23 2.37 12.9 9.4 11.8 2.31 Nd 20.7 6.59 16.5 7.14 8.15 22 15.7 6.98 42.1 30 34.2 6.23 Sm 3.61 1.22 2.92 1.23 1.16 3.69 2.82 1.23 7.78 5.62 5.82 1.19 Eu 0.46 0.2 0.3 0.16 0.15 0.59 0.64 0.39 1.02 0.6 0.96 0.4 Gd 2.84 1.15 2.56 1.32 1.41 3.51 2.52 1.29 7.21 4.95 5.91 1.45 Tb 0.45 0.21 0.4 0.21 0.2 0.5 0.39 0.25 1.12 0.78 0.92 0.26 Dy 2.7 1.45 2.26 1.43 1.22 2.7 2.16 1.69 6.22 4.14 5.4 1.8 Ho 0.54 0.32 0.44 0.34 0.29 0.54 0.42 0.37 1.23 0.79 1.08 0.41 Er 1.58 1.2 1.52 1.33 1.16 1.76 1.38 1.31 3.99 2.42 3.62 1.47 Tm 0.28 0.22 0.26 0.26 0.23 0.28 0.24 0.23 0.63 0.36 0.63 0.26 Yb 1.86 1.55 1.71 1.93 1.71 1.81 1.6 1.58 3.92 2.18 4.47 1.79 Lu 0.28 0.29 0.32 0.36 0.35 0.33 0.29 0.29 0.7 0.37 0.84 0.33 ∑REE 154.35 54.65 110.79 75.49 92.04 155.16 104.59 57.68 274.22 195.81 285.25 106.7 LR/HR 12.26 6.12 9.42 7.9 11.43 11.12 9.3 5.5 8.47 9.71 10.03 10.92 (La/Yb)N 10.44 4.23 8.08 5.7 9.7 11.25 8.13 4.35 8.12 9.49 8.22 5.09 δEu 0.42 0.51 0.33 0.38 0.36 0.49 0.72 0.94 0.41 0.34 0.5 0.93 注:主量元素含量单位为%,微量和稀土元素含量为10-6 -
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